Chemistry: Principles and Practice
3rd Edition
ISBN: 9780534420123
Author: Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher: Cengage Learning
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Chapter 10, Problem 10.78QE
(a)
Interpretation Introduction
Interpretation:
The hybridization of central atom in
(b)
Interpretation Introduction
Interpretation:
The hybridization of central atom in prop-1-yne has to be given.
(c)
Interpretation Introduction
Interpretation:
The hybridization of central atom in acetaldehyde has to be given.
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1.
Draw the Lewis structures for each of the following ions or molecules. For each, give (i) the
molecular shape, (ii) the electron pair geometry at the central atom, and (iii) the hybridization of the central
atom.
(a) POF3
(b) XeO₂F3+
(c) BrCl₂
(d) N3 (the central atom is N; two other N's are bonded to it)
(e) PF3
The Lewis structure of BH2Cl
(a) Is the molecule polar or nonpolar?
(b) What is the hybridization of the carbon atom?
(c) What is the geometric shape of the molecule?
Consider the reaction BF3 + NH3 -> F3B-NH3
(a) Describe the changes in hybridization of the B and N atoms as a result of this reaction.
(b) Describe the shapes of all the reactant molecules with their bond angles.
(c) Draw the overall shape of the product molecule and identify the bond angles around B and N atoms.
(d) What is the name of the bond between B and N.
(e)Describe the bonding orbitals that make the B and F, B and N & N and H bonds in the product molecule.
Chapter 10 Solutions
Chemistry: Principles and Practice
Ch. 10 - Prob. 10.1QECh. 10 - Prob. 10.2QECh. 10 - Prob. 10.3QECh. 10 - Prob. 10.4QECh. 10 - Prob. 10.5QECh. 10 - Prob. 10.6QECh. 10 - Prob. 10.7QECh. 10 - Prob. 10.8QECh. 10 - Prob. 10.9QECh. 10 - Prob. 10.10QE
Ch. 10 - Which atomic orbitals overlap to form the bonds in...Ch. 10 - Prob. 10.12QECh. 10 - Identify the hybrid orbitals used by boron in BCl3...Ch. 10 - Identify the hybrid orbitals used by antimony in...Ch. 10 - Prob. 10.15QECh. 10 - Prob. 10.16QECh. 10 - Prob. 10.17QECh. 10 - Prob. 10.18QECh. 10 - Prob. 10.19QECh. 10 - Prob. 10.20QECh. 10 - Compare and contrast the molecular orbital and...Ch. 10 - Describe the bonding in molecular orbital terms...Ch. 10 - Prob. 10.23QECh. 10 - Prob. 10.24QECh. 10 - Prob. 10.25QECh. 10 - Prob. 10.26QECh. 10 - Prob. 10.27QECh. 10 - Prob. 10.28QECh. 10 - Prob. 10.29QECh. 10 - Prob. 10.30QECh. 10 - Prob. 10.31QECh. 10 - Prob. 10.32QECh. 10 - Prob. 10.33QECh. 10 - Prob. 10.34QECh. 10 - Prob. 10.35QECh. 10 - Prob. 10.36QECh. 10 - Prob. 10.37QECh. 10 - Prob. 10.38QECh. 10 - Prob. 10.39QECh. 10 - Use the VSEPR model to predict the bond angles...Ch. 10 - Prob. 10.41QECh. 10 - Prob. 10.42QECh. 10 - For each of the following molecules, complete the...Ch. 10 - Prob. 10.44QECh. 10 - Prob. 10.45QECh. 10 - Prob. 10.46QECh. 10 - Indicate which molecules are polar and which are...Ch. 10 - Prob. 10.48QECh. 10 - Indicate which of the following molecules are...Ch. 10 - Prob. 10.50QECh. 10 - Prob. 10.51QECh. 10 - Prob. 10.52QECh. 10 - Prob. 10.53QECh. 10 - Prob. 10.54QECh. 10 - Prob. 10.55QECh. 10 - Prob. 10.56QECh. 10 - Prob. 10.57QECh. 10 - Prob. 10.58QECh. 10 - Prob. 10.59QECh. 10 - Prob. 10.60QECh. 10 - Prob. 10.61QECh. 10 - Prob. 10.62QECh. 10 - Prob. 10.63QECh. 10 - Prob. 10.64QECh. 10 - Prob. 10.65QECh. 10 - Prob. 10.66QECh. 10 - Prob. 10.67QECh. 10 - Prob. 10.68QECh. 10 - Prob. 10.69QECh. 10 - Prob. 10.70QECh. 10 - Prob. 10.71QECh. 10 - Prob. 10.72QECh. 10 - Identify the orbitals on each of the atoms that...Ch. 10 - Prob. 10.74QECh. 10 - Prob. 10.75QECh. 10 - How many sigma bonds and how many pi bonds are...Ch. 10 - Give the hybridization of each central atom in the...Ch. 10 - Prob. 10.78QECh. 10 - Prob. 10.79QECh. 10 - Prob. 10.80QECh. 10 - Prob. 10.81QECh. 10 - Predict the hybridization at each central atom in...Ch. 10 - Prob. 10.83QECh. 10 - Tetrafluoroethylene, C2F4, is used to produce...Ch. 10 - Prob. 10.85QECh. 10 - Prob. 10.86QECh. 10 - Prob. 10.87QECh. 10 - Prob. 10.88QECh. 10 - Prob. 10.89QECh. 10 - Prob. 10.90QECh. 10 - Prob. 10.91QECh. 10 - Prob. 10.92QECh. 10 - Prob. 10.93QECh. 10 - Prob. 10.94QECh. 10 - Prob. 10.95QECh. 10 - Prob. 10.96QECh. 10 - Prob. 10.97QECh. 10 - Prob. 10.98QECh. 10 - The molecular orbital diagram of NO shown in...Ch. 10 - The molecular orbital diagram of NO shown in...Ch. 10 - The molecular orbital diagram of NO shown in...Ch. 10 - Prob. 10.102QECh. 10 - Prob. 10.103QECh. 10 - Prob. 10.104QECh. 10 - Prob. 10.105QECh. 10 - Following are the structures of three isomers of...Ch. 10 - The ions ClF2 and ClF2+ have both been observed....Ch. 10 - Aspirin, or acetylsalicylic acid, has the formula...Ch. 10 - Aspartame is a compound that is 200 times sweeter...Ch. 10 - Prob. 10.110QECh. 10 - Prob. 10.111QECh. 10 - Calcium cyanamide, CaNCN, is used both to kill...Ch. 10 - Histidine is an essential amino acid that the body...Ch. 10 - Formamide, HC(O)NH2, is prepared at high pressures...Ch. 10 - Prob. 10.115QECh. 10 - Prob. 10.116QECh. 10 - Prob. 10.117QECh. 10 - Prob. 10.118QECh. 10 - Prob. 10.119QECh. 10 - Prob. 10.120QECh. 10 - Prob. 10.121QECh. 10 - Prob. 10.122QECh. 10 - Prob. 10.123QECh. 10 - Prob. 10.124QECh. 10 - Two compounds have the formula S2F2. Disulfur...Ch. 10 - Prob. 10.126QECh. 10 - Prob. 10.127QE
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- 7. Nitrogen is the central atom in each of the species given. (a) Draw the Lewis electron-dot structure for each of the species. + NO₂ NO₂ NO₂ (b) List the species in order of increasing bond angle. Justify your answer. (c) For NO₂ and NO₂, give the hybridization of the nitrogen atom in it. (d) Identify the only one of the species that dimerizes and explain what causes it to do so.arrow_forwardH2CO molecules (a) use orbital hybridization theory to determine the molecular shape of h2co. (b) what bonds are formed between the c and o atoms in formaldehyde molecules?arrow_forwardNitrogen trifluoride (NF3) is used in the electronics industry to clean surfaces. NF3 is also a potent greenhouse gas. (A) Draw the Lewis structure of NF3 and determine its molecular geometry. (B) BF3 and NF3 both have three covalently bonded fluorine atoms around a central atom. Do they have the same dipole moment? (C) Could BF3 also behave as a greenhouse gas? Explain why or why not.arrow_forward
- (a) Find the angle u between adjacent nearest-neighbor bonds in the silicon lattice. Recall that each silicon atom is bonded to four of its nearest neighbors.The four neighbors form a regular tetrahedron— a pyramid whose sides and base are equilateral triangles. (b) Find the bond length, given that the atoms at the corners of the tetrahedron are 388 pm apart.arrow_forwardDraw a Lewis electron dot diagram for each of the follow- ing molecules and ions. Formulate the hybridization for the central atom in each case and give the molecular geometry. (a) BF3 (b) BH4- (c) PH3 (d) CS2 (e) CH3+arrow_forward2(a) Provide the Lewis structures for both CH3OH and C2H3Cl. 2(b) What is the largest bond angle among all the bond angles in CH3OH and C2H3Cl? Listthe three atoms making this largest bond angle, and estimate the value of the angle.2(c) What intermolecular forces are present(i) between CH3OH molecules?(ii) between C2H3Cl molecules?arrow_forward
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- Propylene, C3H6, is a gas that is used to form the importantpolymer called polypropylene. Its Lewis structure is given. (a) What is the total number of valence electrons in the propylenemolecule? (b) How many valence electrons are usedto make σ bonds in the molecule? (c) How many valenceelectrons are used to make π bonds in the molecule? (d) Howmany valence electrons remain in nonbonding pairs in themolecule? (e) What is the hybridization at each carbon atomin the molecule?arrow_forwardFor each of the following molecule: (i) draw the correct Lewis structure; (ii) determine the molecular geometry and the type of hybridization on the central atom, and (iii) predict whether the molecule is polar or nonpolar. (a) BrCl5arrow_forwardA useful solvent that will dissolve salts as well as organic compounds is the compound acetonitrile, H3CCN. It is present in paint strippers.(a) Write the Lewis structure for acetonitrile, and indicate the direction of the dipole moment in the molecule.(b) Identify the hybrid orbitals used by the carbon atoms in the molecule to form σ bonds.(c) Describe the atomic orbitals that form the π bonds in the molecule. Note that it is not necessary to hybridize the nitrogen atom.arrow_forward
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