Concept explainers
(a)
Interpretation:
The structure and polar nature of
Concept Introduction:
Polarity results from the uneven partial charge distribution between various atoms in a compound. Atoms, such as nitrogen, oxygen, and halogens that are more electronegative have a tendency to have partial negative charges. Atoms, such as carbon and hydrogen, have a tendency to be more neutral or have partial positive charges.
Polar nature of the molecules can be measured by the dipole moment. If a molecule has zero dipole moment then it is a non polar molecule. If a molecule has a net dipole moment then it is a polar molecule.
(b)
Interpretation:
The structure and polar nature of
Concept Introduction:
Refer to part (a).
(c)
Interpretation:
The structure and polar nature of
Concept Introduction:
Refer to part (a).
(d)
Interpretation:
The polar nature of
Concept Introduction:
Refer to part (a).
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Chemistry: Principles and Practice
- Consider the following molecules: SiH4, PH3, H2S. In each case, a central atom is surrounded by four electron pairs. In which of these molecules would you expect the bond angle to be less than 109.5? Explain your reasoning.arrow_forward(a) How does a polar molecule differ from a nonpolar one? (b) Atoms X and Y have different electronegativities. Will the diatomic molecule X—Y necessarily be polar? Explain. (c) What factors affect the size of the dipole moment of a diatomic molecule?arrow_forward2. Consider the following molecules or ions: CIOF5, NOBr, NH2F, and XeO2F3+. Answer the following questions based on the Lewis structures and VSEPR theory prediction of their molecular shapes. (a) Which one has only bond angles of 109.5°? (b) Which one has only bond angles of 120°? (c) Which one has bond angles of 90 and 180°? (d) Which one has bond angles of 90, 120, and 180°?arrow_forward
- Which of the following is a polar molecule? (A) All of them are (B) SO2 (C) PCl3 (D) CH3Cl (E) O3arrow_forwardConsider the reaction BF3 + NH3 -> F3B-NH3 (a) Describe the changes in hybridization of the B and N atoms as a result of this reaction. (b) Describe the shapes of all the reactant molecules with their bond angles. (c) Draw the overall shape of the product molecule and identify the bond angles around B and N atoms. (d) What is the name of the bond between B and N. (e)Describe the bonding orbitals that make the B and F, B and N & N and H bonds in the product molecule.arrow_forwardDetermine the electron and molecular geometries of each molecule. For molecules with two central atoms, indicate the geometry about each central atom.(a) N2(b) N2H2 (skeletal structure HNNH)(c) N2H4 (skeletal structure H2NNH2)arrow_forward
- Determine whether each molecule is polar or nonpolar: (a) H 2O; (b) CO 2.arrow_forwardNitrogen trifluoride (NF3) is used in the electronics industry to clean surfaces. NF3 is also a potent greenhouse gas. (A) Draw the Lewis structure of NF3 and determine its molecular geometry. (B) BF3 and NF3 both have three covalently bonded fluorine atoms around a central atom. Do they have the same dipole moment? (C) Could BF3 also behave as a greenhouse gas? Explain why or why not.arrow_forward10. Each ball-and-stick model below shows the electron-pair and molecular geometry of a generic molecule. Explain what is wrong with each molecular geometry and provide the correct molecular geometry based on the number of lone and bonding pairs around the central atom. (a) (b) (c) 11. Draw the Lewis structure for acetamide (CH3CONH2) and determine the geometry about each interior atom. Experiments show that the geometry about the N atom in acetamide is nearly planar. Draw a resonance structure that can account for the planar geometry about the N atom.arrow_forward
- Which one of the following molecules does not have a dipole moment? Justify your answer. (a) BrCI(b) CIF(c) BrF(d) O2(e) ICIarrow_forwardTwo important industrial chemicals, ethene, C2H4, and propene, C3H6, are produced by the steam (or thermal) cracking process: 2C3H8(g) = C2H4(g) + C3H6(g) + CH4(g) + H2(g) For each of the four carbon compounds, do the following: (a) Draw a Lewis Structure (b) Predict the geometry about the carbon atom (c) Determine the hybridization of each type of carbon atomarrow_forwardFor each of the following molecules or molecular ions, givethe steric number and sketch and name the approximatemolecular geometry. In each case, the central atom is listedfirst and the other atoms are all bonded directly to it.(a) PF3 (b) SO2Cl2(c) PF6- (d) ClO2-(e) GeH4arrow_forward
- Chemistry: Principles and ReactionsChemistryISBN:9781305079373Author:William L. Masterton, Cecile N. HurleyPublisher:Cengage Learning