(a) Interpretation: The approximate geometry of [ BF 4 − ] is to be predicted. Concept introduction: The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

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Answer 1

Question

Chapter 1, Problem 1.9P

Interpretation Introduction

(a)

Interpretation:

The approximate geometry of [BF4−] is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(b)

Interpretation:

The approximate geometry of water is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(c)

Interpretation:

The approximate geometry of H2C=O• •• • is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(d)

Interpretation:

The approximate geometry of H3C−C≡N: is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.

Answer 2

Question

Chapter 1, Problem 1.9P

Interpretation Introduction

(a)

Interpretation:

The approximate geometry of [BF4−] is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(b)

Interpretation:

The approximate geometry of water is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(c)

Interpretation:

The approximate geometry of H2C=O• •• • is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(d)

Interpretation:

The approximate geometry of H3C−C≡N: is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Expert Solution & Answer

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Answer 3

Question

Chapter 1, Problem 1.9P

Interpretation Introduction

(a)

Interpretation:

The approximate geometry of [BF4−] is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(b)

Interpretation:

The approximate geometry of water is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(c)

Interpretation:

The approximate geometry of H2C=O• •• • is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(d)

Interpretation:

The approximate geometry of H3C−C≡N: is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Expert Solution & Answer

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Answer 4

Question

Chapter 1, Problem 1.9P

Interpretation Introduction

(a)

Interpretation:

The approximate geometry of [BF4−] is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(b)

Interpretation:

The approximate geometry of water is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(c)

Interpretation:

The approximate geometry of H2C=O• •• • is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(d)

Interpretation:

The approximate geometry of H3C−C≡N: is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Expert Solution & Answer

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Answer 5

Chapter 1, Problem 1.9P

Interpretation Introduction

(a)

Interpretation:

The approximate geometry of [BF4−] is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(b)

Interpretation:

The approximate geometry of water is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(c)

Interpretation:

The approximate geometry of H2C=O• •• • is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Interpretation Introduction

(d)

Interpretation:

The approximate geometry of H3C−C≡N: is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Answer 6

Chapter 1, Problem 1.9P

Interpretation Introduction

(a)

Interpretation:

The approximate geometry of [BF4−] is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Answer 7

Chapter 1, Problem 1.9P

Interpretation Introduction

(a)

Interpretation:

The approximate geometry of [BF4−] is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Answer 8

Interpretation Introduction

(b)

Interpretation:

The approximate geometry of water is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Answer 9

Interpretation Introduction

(b)

Interpretation:

The approximate geometry of water is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Answer 10

Interpretation Introduction

(c)

Interpretation:

The approximate geometry of H2C=O• •• • is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Answer 11

Interpretation Introduction

(c)

Interpretation:

The approximate geometry of H2C=O• •• • is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Answer 12

Interpretation Introduction

(d)

Interpretation:

The approximate geometry of H3C−C≡N: is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Answer 13

Interpretation Introduction

(d)

Interpretation:

The approximate geometry of H3C−C≡N: is to be predicted.

Concept introduction:

The three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry. The molecular geometry of any molecule is identified by using the central metal atom, pair of electrons and atoms surrounding the central atom with the help of VSEPR theory.

Answer 14

Expert Solution & Answer

Answer 15

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Answer 16

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Answer 17

Ch. 1 - Prob. 1.1P Ch. 1 - Prob. 1.2P Ch. 1 - Prob. 1.3P Ch. 1 - Prob. 1.4P Ch. 1 - Prob. 1.5P Ch. 1 - Prob. 1.6P Ch. 1 - Prob. 1.7P Ch. 1 - Prob. 1.8P Ch. 1 - Prob. 1.9P Ch. 1 - Prob. 1.10P

Solution Summary: The author explains that the three dimensional arrangement of atoms possesses by the molecule in space is known as the molecular geometry.

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Chapter 1 Solutions