Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 1, Problem 1.14P
Interpretation Introduction

Interpretation:

The plot of the wavefunction ψ=sinnx for the domain 0xπ for n=1,2, and 3 is to be drawn and thier relationship between “n” the quantum number and the number of nodes in the wavefunction is to be stated.

Concept introduction:

The wavefunction Ψ contains all the information about the state of the system. The wavefunction is the function of the coordinates of particles and time. The principal quantum number describes the orbital size, azimuthal quantum number describes the shape of the orbital and magnetic quantum number describes the direction of an orbital.

The point at which the probability of finding an electron is zero is known as the node. The two types of nodes are radial nodes and angular nodes.

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10
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