Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 1, Problem 1.41AP
Interpretation Introduction

Interpretation:

The reason corresponding to the fact that, even though the CCl bond dipole is large, the dipole moment of carbon tetrachloride, CCl4, is zero has to be explained.

Concept introduction:

The quantity that is used to measure the uneven distribution of electrons around the atoms of a compound that possess the covalent bonds is known as dipole moment. It is denoted by μ. The dipole moment is the calculated by the multiplication of the magnitude of separated charges, q, with the vector, r, from positive to negative charge regions. The expression for dipole moment is given as,

μ=qr

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Part VII. Below are the 'HNMR, 13 C-NMR, COSY 2D- NMR, and HSQC 2D-NMR (similar with HETCOR but axes are reversed) spectra of an organic compound with molecular formula C6H1003 - Assign chemical shift values to the H and c atoms of the compound. Find the structure. Show complete solutions. Predicted 1H NMR Spectrum 4.7 4.6 4.5 4.4 4.3 4.2 4.1 4.0 3.9 3.8 3.7 3.6 3.5 3.4 3.3 3.2 3.1 3.0 2.9 2.8 2.7 2.6 2.5 2.4 2.3 2.2 2.1 2.0 1.9 1.8 1.7 1.6 1.5 1.4 1.3 1.2 1.1 f1 (ppm) Predicted 13C NMR Spectrum 100 f1 (ppm) 30 220 210 200 190 180 170 160 150 140 130 120 110 90 80 70 -26 60 50 40 46 30 20 115 10 1.0 0.9 0.8 0 -10
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