Organic Chemistry
Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
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Chapter 1, Problem 1.41AP
Interpretation Introduction

Interpretation:

The reason corresponding to the fact that, even though the CCl bond dipole is large, the dipole moment of carbon tetrachloride, CCl4, is zero has to be explained.

Concept introduction:

The quantity that is used to measure the uneven distribution of electrons around the atoms of a compound that possess the covalent bonds is known as dipole moment. It is denoted by μ. The dipole moment is the calculated by the multiplication of the magnitude of separated charges, q, with the vector, r, from positive to negative charge regions. The expression for dipole moment is given as,

μ=qr

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a. The change in the Gibbs energy of a certain constant pressure process is found to fit the expression: AG-85.1 J mol −1 +36.5 J mol ¹K-1 × T A. Calculate the value of AS for the process. B. Next, use the Gibbs-Helmholtz equation: (a(AG/T)) ΔΗ - T2 to calculate the value of AH for the process.
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