Organic Chemistry
6th Edition
ISBN: 9781936221349
Author: Marc Loudon, Jim Parise
Publisher: W. H. Freeman
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 1, Problem 1.38AP
Interpretation Introduction
Interpretation:
Whether the given experimental fact provides a clue to the preferred dihedral angles in ethylene has to be predicted with an explanation.
Concept introduction:
The dipole moment is defined as the charge separation between two atoms in a covalent bond or between two ions in an ionic bond. It is used to determine the polarity of atoms or ions. If the value of dipole moment is zero, then the molecule is said to be non-polar, and if the value of dipole moment is not zero, then the molecule is said to be polar and possess permanent dipole moment.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
Vanillin, the molecular structure above, is an interesting organic molecule. From the structure, answer the following questions and post them in the indicated submission box.
What is the molecular formula of this compound?
How many functional groups does this molecule have?
Write the names of all the functional groups present in vanillin.
Write the line-bond structures of all the functional groups present in vanillin.
What orbitals are involved in forming the following bonds in vanillin?
C=O
O-CH3
C=C
O-H
) Bean hexene is an odor compound used in cosmetics and cleaners. It is also known as leguminal. Its formula is:
CH3CH2CHCHCH2CH2OCHCH2CH3
|
OCH3
Please draw a Lewis structure for this compound with CORRECT GEOMETRY (use dashes and wedges!)
Label all pi bonds in the molecule (if there are any)
Indicate the bond angles for the red highlighted section of the molecule. (hint: you may want to keep the main carbon chain in-plane with the page for clarity)
For this question, you don’t need to draw out the orbitals.
The molecular structure of hinokitiol is represented below (See attached image)
Draw a complete Lewis structure of the molecule and answer the following questions.
Complete the structure by adding ONLY hydrogen atoms to carbon atoms where needed. You must not create any other bonds. Atoms such as oxygen or nitrogen may have lone pairs to complete their octets.
Each of the non-hydrogen atoms of this skeletal structure has been randomly numbered.
Match the atom number with the orbital hybridization invoked for sigma bonding.
Match these to the below (A)) (Options: sp3, sp2, sp, s, p, d2sp3, dsp3)
A) 12, 9, 7, 2, 4
B) How many pairs of non-bonding electrons are there in the molecule?
C) How many CH3 (methyl) groups are there in the molecule?
D) How many CH2 (methylene) groups are there in the molecule? (i.e. # of C-atoms having exactly two bonded H-atoms)
E) How many CH (methyne) groups are there in the molecule? (i.e. # of C-atoms having exactly one bonded H-atom)
F) How many…
Chapter 1 Solutions
Organic Chemistry
Ch. 1 - Prob. 1.1PCh. 1 - Prob. 1.2PCh. 1 - Prob. 1.3PCh. 1 - Prob. 1.4PCh. 1 - Prob. 1.5PCh. 1 - Prob. 1.6PCh. 1 - Prob. 1.7PCh. 1 - Prob. 1.8PCh. 1 - Prob. 1.9PCh. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Prob. 1.14PCh. 1 - Prob. 1.15PCh. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Prob. 1.21APCh. 1 - Prob. 1.22APCh. 1 - Prob. 1.23APCh. 1 - Prob. 1.24APCh. 1 - Prob. 1.25APCh. 1 - Prob. 1.26APCh. 1 - Prob. 1.27APCh. 1 - Prob. 1.28APCh. 1 - Prob. 1.29APCh. 1 - Prob. 1.30APCh. 1 - Prob. 1.31APCh. 1 - Prob. 1.32APCh. 1 - Prob. 1.33APCh. 1 - Prob. 1.34APCh. 1 - Prob. 1.35APCh. 1 - Prob. 1.36APCh. 1 - Prob. 1.37APCh. 1 - Prob. 1.38APCh. 1 - Prob. 1.39APCh. 1 - Prob. 1.40APCh. 1 - Prob. 1.41APCh. 1 - Prob. 1.42APCh. 1 - Prob. 1.43APCh. 1 - Prob. 1.44APCh. 1 - Prob. 1.45APCh. 1 - Prob. 1.46APCh. 1 - Prob. 1.47APCh. 1 - Prob. 1.48APCh. 1 - Prob. 1.49AP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Methylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is (a) Give values for the three bond angles indicated. (b) Indicate the most polar bond in the molecule. (c) Circle the shortest carbon-oxygen bond. (d) Circle the shortest carbon-carbon bond.arrow_forwardName 5 common organic compounds that are found in your home. Draw their Lewis structures and give their molecular formula. Encircle and identify the functional group/s that is/ are present in each molecule. Write your answers in another sheet of paper. Ex. Acetic acid in vinegar Substance Molecular formula Lewis structure CH,COOH - more preferable H-C+C 0-H Acetic acid C2H4O2 in vinegar H Carboxylic acid エーO-エarrow_forwardHow many different structural isomers are there for octahedral molecules with the general formula AX2Y3 if A is the inner atom and there are no X-Y, X-X and Y-Y bonds?arrow_forward
- Use this condensed chemical structure to complete the table belowarrow_forwardFor each compound in the table below, decide whether there would be any hydrogen-bonding force between molecules of the compound, or between molecules of the compound and molecules of water. name dimethyl ether iodomethane acetic acid compound formula or Lewis structure H T H-C-Ö-C-H I H HILIA CH₂I | H H :O: | || H-C-C-O-H Between molecules of the compound? O yes O no O yes O no hydrogen-bonding force O yes O no Between molecules of the compound and molecules of water? O yes Ono O yes O no O yes O no X Sarrow_forwardDraw a line-bond structure for propane, CH3CH2CH3. Predict the value of each bond angle, and indicate the overall shape of the molecule.arrow_forward
- Please don't provide handwritten solution .....arrow_forwardDraw the Lewis structures for the following molecules. For each molecule, determine its (a) electronic geometry, (b) number of nonbonding domains on the central atom, and (c) polarity of the molecule. Remember, that molecules that have zero nonbonding domains on the central atom AND have all of the outer atoms the same are NONPOLAR. Generally, molecules with different outer atoms or with more than one nonbonding domain are POLAR. However, these may be NONPOLAR ONLY IF the dipoles cancel each other due to a symmetrical arrangement. CIF3 (a) electronic geometry: -Select-- (b) number of nonbonding domains on central atom: -Select-v (c) molecule polarity: -Select- SO2 .(a) electronic geometry: --Select- (b) number of nonbonding domains on central atom: -Select---V (c) molecule polarity: --Select--v SF5 (a) electronic geometry: [-Select- (b) number of nonbonding domains on central atom: --Select--- ♥ (c) molecule polarity: --Select-- v IFS (a) electronic geometry: -Select-- (b) number of…arrow_forwardExplain the following observations about two carbon-oxygen bonds in the methane (formate) anion, HCO2-. You may draw a Lewis electron-dot diagram (or diagrams) of methanoate ion as part of your explanations. i. The two carbon-oxygen bonds in the methanoate(formate) anion, HCO2-, have the same length. ii.the length of the carbon-oxygen bonds in the methanoate(formate) anion, HCO2-, is intermediate between the length of the carbon-oxygen bond in methanol and the length of the carbon-oxygen bond in methanal.arrow_forward
- How to draw the line bond formula or lewis structure of a methyl ketone with the chemical formula C6H5C3H5O?arrow_forwardMolecule #7 BrF4* Calculate the number of valence electrons Draw the three-dimensional structure of the molecule using the "wedge and dash" notation. Our logic for this choice is: The formal charge on F is Estimate F-Br-F bond angle Calculate the number of valence electrons Draw the three-dimensional structure of the molecule using the "wedge and dash" notation. Our logic for this choice is: Draw the Lewis Structure below The molecular geometry is: This molecule is polar nonpolar (Circle your choice.) The formal charge on Br is The hybridization of Br is Molecule #8 XeOF4 Draw the Lewis Structure below The molecular geometry is: This molecule is polar nonpolar (Circle your choice.) The formal charge on Xe is The hybridization of Xe is The formal charge on O is Estimate F-Xe-F bond anglearrow_forwardwhich of the following statement is not true? 1)Nitrogen s relative inertness is due to formation of strong and stable bond between 2 nitrogens atom. 2)the bond energy of N2 is relatively higher that makes it relatively inert. 3)the bond energy of an O-H bond is always the same in all compounds that contain an O-H bond 4)carbon-carbon single bond is the longest among all sorts of carbon-carbon bonds 5)a shorter bond in general ,is a stronger bond than a longer bondarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Chemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage LearningChemistry by OpenStax (2015-05-04)ChemistryISBN:9781938168390Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark BlaserPublisher:OpenStaxChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage Learning
- ChemistryChemistryISBN:9781305957404Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCostePublisher:Cengage LearningChemistry: An Atoms First ApproachChemistryISBN:9781305079243Author:Steven S. Zumdahl, Susan A. ZumdahlPublisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry by OpenStax (2015-05-04)
Chemistry
ISBN:9781938168390
Author:Klaus Theopold, Richard H Langley, Paul Flowers, William R. Robinson, Mark Blaser
Publisher:OpenStax
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry
Chemistry
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Cengage Learning
Chemistry: An Atoms First Approach
Chemistry
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Cengage Learning
Stoichiometry - Chemistry for Massive Creatures: Crash Course Chemistry #6; Author: Crash Course;https://www.youtube.com/watch?v=UL1jmJaUkaQ;License: Standard YouTube License, CC-BY
Bonding (Ionic, Covalent & Metallic) - GCSE Chemistry; Author: Science Shorts;https://www.youtube.com/watch?v=p9MA6Od-zBA;License: Standard YouTube License, CC-BY
General Chemistry 1A. Lecture 12. Two Theories of Bonding.; Author: UCI Open;https://www.youtube.com/watch?v=dLTlL9Z1bh0;License: CC-BY