
Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Textbook Question
Chapter 1, Problem 1.77P
Label the polar bonds in each molecule. Indicate the direction of the net dipole (if there is one).
a.
e. f.
b.
c.
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B. Classify the following amino acid. Atoms other than carbon and hydrogen are labeled.
a. acidic
b. basic
C.
neutral
C.
Consider the following image.
Which level of protein structure is shown here?
a.
primary
b. secondary
c. tertiary
d. quaternary
D.
Consider the following image.
H
RH
H
HR
H R
HR
HR
RH
Which level of protein structure is shown in the box?
a. primary
b. secondary
R
c.
tertiary
d.
quaternary
コー
R
Briefly answer three from the followings:
a. What are the four structures of the protein?
b. Why is the side chain (R) attached to the alpha carbon in the amino acids is important for the
function?
c. What are the types of amino acids? And how is it depend on the (R) structure?
d. Write a reaction to prepare an amino acid.
prod
Answe Answer A and B please
Chapter 1 Solutions
Organic Chemistry
Ch. 1 - While the most common isotope of nitrogen has a...Ch. 1 - Label each bond in the following compounds as...Ch. 1 - How many covalent bonds are predicted for each...Ch. 1 - Draw a valid Lewis structure for each species. a....Ch. 1 - Draw an acceptable Lewis structure for each...Ch. 1 - Prob. 1.6PCh. 1 - Draw a Lewis structure for each ion. a. CH3Ob....Ch. 1 - Draw Lewis structures for each molecular formula....Ch. 1 - Prob. 1.9PCh. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Draw a second resonance structure for each...Ch. 1 - Prob. 1.14PCh. 1 - Draw a second resonance structure for nitrous...Ch. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Simplify each condensed structure by using...Ch. 1 - Prob. 1.22PCh. 1 - Prob. 1.23PCh. 1 - Convert each skeletal structure to a complete...Ch. 1 - Draw in all hydrogens and lone pairs on the...Ch. 1 - Prob. 1.26PCh. 1 - What orbitals are used to form each of the CC, and...Ch. 1 - What orbitals are used to form each bond in the...Ch. 1 - Determine the hybridization around the highlighted...Ch. 1 - Classify each bond in the following molecules as ...Ch. 1 - Prob. 1.31PCh. 1 - Rank the following atoms in order of increasing...Ch. 1 - Prob. 1.33PCh. 1 - Prob. 1.34PCh. 1 - Provide the following information about...Ch. 1 - Use the ball-and-stick model to answer each...Ch. 1 - Citric acid is responsible for the tartness of...Ch. 1 - Zingerone gives ginger its pungent taste. a.What...Ch. 1 - Two radioactive isotopes of iodine used for the...Ch. 1 - Prob. 1.40PCh. 1 - Assign formal charges to each carbon atom in the...Ch. 1 - Assign formal charges to each N and O atom in the...Ch. 1 - Draw one valid Lewis structure for each compound....Ch. 1 - Prob. 1.44PCh. 1 - Prob. 1.45PCh. 1 - Prob. 1.46PCh. 1 - Draw all possible isomers for each molecular...Ch. 1 - 1.45 Draw Lewis structures for the nine isomers...Ch. 1 - Prob. 1.49PCh. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Prob. 1.52PCh. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - Draw all reasonable resonance structures for each...Ch. 1 - Prob. 1.56PCh. 1 - Rank the resonance structures in each group in...Ch. 1 - 1.56 Consider the compounds and ions with curved...Ch. 1 - 1.57 Predict all bond angles in each...Ch. 1 - Predict the geometry around each indicated atom....Ch. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Draw in all the carbon and hydrogen atoms in each...Ch. 1 - Prob. 1.64PCh. 1 - Prob. 1.65PCh. 1 - Prob. 1.66PCh. 1 - Prob. 1.67PCh. 1 - Each of the following condensed or skeletal...Ch. 1 - Prob. 1.69PCh. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - Prob. 1.72PCh. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Two useful organic compounds that contain Cl atoms...Ch. 1 - Use the symbols + and to indicate the polarity of...Ch. 1 - Label the polar bonds in each molecule. Indicate...Ch. 1 - Answer the following questions about acetonitrile...Ch. 1 - Prob. 1.79PCh. 1 - The principles of this chapter can be applied to...Ch. 1 -
a. What is the hybridization of each N atom in...Ch. 1 - 1.77 Stalevo is the trade name for a medication...Ch. 1 - 1.78 and are two highly reactive carbon...Ch. 1 - 1.79 The N atom in (acetamide) is hybridized,...Ch. 1 - Prob. 1.85PCh. 1 - Prob. 1.86PCh. 1 - Prob. 1.87PCh. 1 - Prob. 1.88PCh. 1 - Prob. 1.89PCh. 1 - Prob. 1.90P
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- 3. Refer to the data below to answer the following questions: Isoelectric point Amino Acid Arginine 10.76 Glutamic Acid 3.22 Tryptophan 5.89 A. Define isoelectric point. B. The most basic amino acid is C. The most acidic amino acid is sidizo zoarrow_forward3. A gas mixture contains 50 mol% H2 and 50 mol% He. 1.00-L samples of this gas mixture are mixed with variable volumes of O2 (at 0 °C and 1 atm). A spark is introduced to allow the mixture to undergo complete combustion. The final volume is measured at 0 °C and 1 atm. Which graph best depicts the final volume as a function of the volume of added O2? (A) 2.00 1.75 Final Volume, L 1.50 1.25 1.00 0.75 0.50 0.25 0.00 0.00 0.25 0.50 2.00 (B) 1.75 1.50 Final Volume, L 1.25 1.00 0.75 0.50- 0.25 0.00 0.75 1.00 0.00 0.25 Volume O₂ added, L 2 0.50 0.75 1.00 Volume O₂ added, L 2 2.00 2.00 (C) (D) 1.75 1.75 1.50 1.50 Final Volume, L 1.25 1.00 0.75 0.50 Final Volume, L 1.25 1.00 0.75 0.50 0.25 0.25 0.00 0.00 0.00 0.25 0.50 0.75 1.00 0.00 0.25 Volume O₂ added, L 0.50 0.75 1.00 Volume O₂ added, L 2arrow_forwardLeucine is an essential amino acid with the systematic name 2-amino-3-methylpentanoic acid. It has pai 2.36 and pKa2 = 9.60. H2N-C(R)H-COOH and R is -CH2-CH(CH3)2 A. Draw the condensed structure for leucine, and label all chirality centers with an asterisk. B. How many possible stereoisomers of leucine are there? C. Draw a Fischer projection of L-leucine and label the chirality center(s) as R or S. D. What is the p/ of leucine? E. Draw the structure of the predominant form of leucine at 10.00. F. Draw the structure of the predominant form of leucine at pH = 1.50. G. Leucine is described as an essential amino acid. What does this mean? H. Show the alkyl halide you would use to prepare leucine by the amidomalonate method. =arrow_forward
- a) Write out 6 completely different reactions of acetophenone (reagent, product). b) Write out 3 preparations of 1-methylcyclohexanol, using a different starting material for each one. You may use preps where you just change the functional group, and/or preps where you construct the carbon chain. c) Write out 3 preparations of 2-ethoxybenzoic acid, a different starting material for each one. You may use preps where you just change the functional group, and/or preps where you construct the carbon chain.arrow_forward12. CH3 OH OH H&C CH3 H₂C N OH H₂C CH3 H&C CH3 H₂C' CH3 H.C CH3OH H.C CH2CH3OH CH3CEN Which one of these 17 compounds is represented by this IR and this 'H NMR spectrum? IR Spectrum 3000 4000 3000 NMR Spectrum 2000 £500 RAVENUMBER 2000 1500 9 8 6 5 10 HP-00-290 ppm m 1000 500 1000 4 °arrow_forwardDraw the structure of (E,6R) 6-methoxy-4-hepten-2-one. Give the IUPAC name of this compound, including stereochemistry. Draw the most stable chair conformation of (cis) 1,3-isobutylcyclohexane. H HC=CCH₂ CH2CH3 EN(CH3)2 -CN(CH3)2arrow_forward
- 10. Write out the mechanism (intermediate/transition state) for this reaction; indicate stereochemistry in product. H3C CH₂OH CH3 SN1 Harrow_forwardWrite "most" under the member of each trio which is most stable. Write "least under the member of each trio which is least stable. b) Draw a Fischer projection of a pair of enantiomers with three chiral carbons. Which of these two would you expect to be more soluble in water? Why? 1-butanol 1-heptanol Which of these two would you expect to have the higher boiling point? Why? hexyl methyl ether 1-heptanolarrow_forwardWrite "most" under the most acidic compound. Write "least" under the least acidic compound. OH NO₂ OCH3 Br 9. Compound X, C50H84F2, reacts with excess H2/Pd to give a C50H88F2 compound. How many rings are in X? How many double bonds are in X? Show your work.arrow_forward
- 4. State whether these two are: a) the same molecule b) c) d) different compounds that are not isomers constitutional isomers diastereomers e) enantiomers CH3 CH₁₂ H OH HO H H OH HO H CH, CH₂ 5. a) How many stereocenters does this compound have? b) How many stereoisomers are possible for this compound? CH₂ OH CHCHarrow_forwardCalculating the pH at equivalence of a titration A chemist titrates 210.0 mL of a 0.1003 M hydrobromic acid (HBr) solution with 0.7550M KOH solution at 25 °C. Calculate the pH at equivalence. Round your answer to 2 decimal places. Note for advanced students: you may assume the total volume of the solution equals the initial volume plus the volume of KOH solution added. pH = ] ☑ o0o 18 Ararrow_forwardDo you do chemistry assignmentsarrow_forward
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