Organic Chemistry
4th Edition
ISBN: 9780073402772
Author: Janice G. Smith
Publisher: MCG
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Chapter 1, Problem 1.19P
Interpretation Introduction
Interpretation: The geometry around highlighted atom in enanthotoxin is to be predicted.
Concept introduction: The geometry and hybridisation of an atom is determined by the number of groups around it. If the number of groups attached to an atom is
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Please answer part one and two, thank you!
Using the principles of VSEPR theory, you can predict the geometry or electron arrangement around any atom in any molecule, no matter how complex. Predict
the electron arrangement geometry around the indicated atoms in the structure shown.
a
H-C-0-H
Part 1 of 2
H
Part 2 of 2
b
H
Atom a: (Choose one)
linear
trigonal planar
tetrahedral
Atom b: (Choose one)
X
Group X elements can conduct electricity and heat. As a chemistry student, Explain the characteristics of Group X elements. Explain the chemical properties of Group X elements . Discuss the trends of Group X elements when going down the group
Using the knowledge of Lewis Diagram, show the formation of bond from any ONE of the element from Group X and any ONE non-metal element.
State the electronic configuration of the cation and anion from the bond formed above.
Draw the orbital diagram of the carbon and anion from thw bond formed above.
Show the formation of positive ion and negative ion from the bond formed above and justify the differences in their number of electrons.
Rubric: Part A; Choose your rubric based on the Bloom's.
Part B; Assess originality.
Chapter 1 Solutions
Organic Chemistry
Ch. 1 - While the most common isotope of nitrogen has a...Ch. 1 - Label each bond in the following compounds as...Ch. 1 - How many covalent bonds are predicted for each...Ch. 1 - Draw a valid Lewis structure for each species. a....Ch. 1 - Draw an acceptable Lewis structure for each...Ch. 1 - Prob. 1.6PCh. 1 - Draw a Lewis structure for each ion. a. CH3Ob....Ch. 1 - Draw Lewis structures for each molecular formula....Ch. 1 - Prob. 1.9PCh. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Draw a second resonance structure for each...Ch. 1 - Prob. 1.14PCh. 1 - Draw a second resonance structure for nitrous...Ch. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Simplify each condensed structure by using...Ch. 1 - Prob. 1.22PCh. 1 - Prob. 1.23PCh. 1 - Convert each skeletal structure to a complete...Ch. 1 - Draw in all hydrogens and lone pairs on the...Ch. 1 - Prob. 1.26PCh. 1 - What orbitals are used to form each of the CC, and...Ch. 1 - What orbitals are used to form each bond in the...Ch. 1 - Determine the hybridization around the highlighted...Ch. 1 - Classify each bond in the following molecules as ...Ch. 1 - Prob. 1.31PCh. 1 - Rank the following atoms in order of increasing...Ch. 1 - Prob. 1.33PCh. 1 - Prob. 1.34PCh. 1 - Provide the following information about...Ch. 1 - Use the ball-and-stick model to answer each...Ch. 1 - Citric acid is responsible for the tartness of...Ch. 1 - Zingerone gives ginger its pungent taste. a.What...Ch. 1 - Two radioactive isotopes of iodine used for the...Ch. 1 - Prob. 1.40PCh. 1 - Assign formal charges to each carbon atom in the...Ch. 1 - Assign formal charges to each N and O atom in the...Ch. 1 - Draw one valid Lewis structure for each compound....Ch. 1 - Prob. 1.44PCh. 1 - Prob. 1.45PCh. 1 - Prob. 1.46PCh. 1 - Draw all possible isomers for each molecular...Ch. 1 - 1.45 Draw Lewis structures for the nine isomers...Ch. 1 - Prob. 1.49PCh. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Prob. 1.52PCh. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - Draw all reasonable resonance structures for each...Ch. 1 - Prob. 1.56PCh. 1 - Rank the resonance structures in each group in...Ch. 1 - 1.56 Consider the compounds and ions with curved...Ch. 1 - 1.57 Predict all bond angles in each...Ch. 1 - Predict the geometry around each indicated atom....Ch. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Draw in all the carbon and hydrogen atoms in each...Ch. 1 - Prob. 1.64PCh. 1 - Prob. 1.65PCh. 1 - Prob. 1.66PCh. 1 - Prob. 1.67PCh. 1 - Each of the following condensed or skeletal...Ch. 1 - Prob. 1.69PCh. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - Prob. 1.72PCh. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Two useful organic compounds that contain Cl atoms...Ch. 1 - Use the symbols + and to indicate the polarity of...Ch. 1 - Label the polar bonds in each molecule. Indicate...Ch. 1 - Answer the following questions about acetonitrile...Ch. 1 - Prob. 1.79PCh. 1 - The principles of this chapter can be applied to...Ch. 1 -
a. What is the hybridization of each N atom in...Ch. 1 - 1.77 Stalevo is the trade name for a medication...Ch. 1 - 1.78 and are two highly reactive carbon...Ch. 1 - 1.79 The N atom in (acetamide) is hybridized,...Ch. 1 - Prob. 1.85PCh. 1 - Prob. 1.86PCh. 1 - Prob. 1.87PCh. 1 - Prob. 1.88PCh. 1 - Prob. 1.89PCh. 1 - Prob. 1.90P
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- Methylcyanoacrylate is the active ingredient in super glues. Its Lewis structure is (a) Give values for the three bond angles indicated. (b) Indicate the most polar bond in the molecule. (c) Circle the shortest carbon-oxygen bond. (d) Circle the shortest carbon-carbon bond.arrow_forwardUse the VSEPR model to predict the bond angles around each central atom in the following Lewis structures (benzene rings are frequently pictured as hexagons, without the letter for the carbon atom at each vertex). Note that the drawings do not necessarily depict the bond angles correctly.arrow_forwardPredicting the arrangement of electron groups around the central atom of a molecule.arrow_forward
- Which of the following explains the VSEPR geometry of an ammonia molecule? It is trigonal pyramidal because there are four bonded pairs around nitrogen. It is tetrahedral because there are four bonded pairs around nitrogen. It is trigonal pyramidal because there are three bonded pairs and one lone pair around nitrogen. It is tetrahedral because there are three bonded pairs and one lone pair around nitrogen.arrow_forwardUsing the principles of VSEPR theory, you can predict the geometry around any atom in any molecule, no matter how complex. Cicutoxin is a poisonous compound isolated from water hemlock, a highly toxic plant that grows in temperate regions in North America. Predict the geometry around the highlighted atoms in cicutoxin.arrow_forwardHow does adding an atom affect the position and angles of existing atoms or lone pairs? How does adding a lone pair affect the position and angles of existing atoms and lone pairs? Is the effect of adding bonded atoms and lone pairs to the central similar? Explain your answer. Describe what is meant by the "Steric #". Explain the difference between the terms "Electron Geometry" and "Molecule Geometry". How does changing a bond to a double or triple bond affect the shape of the molecules? List the molecules in Part III where the real bond angles differ from the theoretical model values. Why do you think the values differ?arrow_forward
- Name Section Table 1: Complete this table with your partner. You may ask the instructor to check your work. Formula Lewis structure Molecular geometry and bond angle(s) around central atoms(s) Polar or nonpolar, draw dipole arrow Hybridization of each atom Orbitals involved in each bond CO2 2 x C=O: sp- sp o o=c=o° C: sp O: sp Linear, 180° Non-polar 2 x C=O: p-p TC COF2 CH2CH2 SCI2 SF4 atoms. atomarrow_forwardPredicting the arrangement of electron groups around the central atom of a molecule.arrow_forwardPlease answer the following questions about the below molecule: This molecule has ___ sigma bonds. This molecule has ___ pi bonds. This molecule has ___ hydrogen atoms. This molecule has ___ carbon atoms. This molecule has ___ lone pairs The nitrogen atom is ___ hybridized. The ___ orbital is involved in all hydrogen sigma bonding. The bond angle of C-N-O is ___ °.arrow_forward
- Mark the correct statements related to the bonding, shape and polarity of molecules. A - Only valence electrons are used when Lewis structures are drawn. B - Valence electrons occupying pi bonding orbitals are not considered when determining the molecular shape with the VSEPR theory C- The lone pairs on the central atom does not influence the molecular shape of a molecule. D- Molecules with polar bonds are polar. E - Molecules with a tetrahedral electron pair geometry are non-polar.arrow_forwardIn addition to the items required for part A, divide the naming of the geometry into a name for the arrangement about each atom that can be considered central to two or more it is bound to. Make only one overall ball-and-stick sketch and judge overall polarity. Fill in the blanks here!arrow_forwardThe molecular structure of hinokitiol is represented below (See attached image) Draw a complete Lewis structure of the molecule and answer the following questions. Complete the structure by adding ONLY hydrogen atoms to carbon atoms where needed. You must not create any other bonds. Atoms such as oxygen or nitrogen may have lone pairs to complete their octets. Each of the non-hydrogen atoms of this skeletal structure has been randomly numbered. Match the atom number with the orbital hybridization invoked for sigma bonding. Match these to the below (A)) (Options: sp3, sp2, sp, s, p, d2sp3, dsp3) A) 12, 9, 7, 2, 4 B) How many pairs of non-bonding electrons are there in the molecule? C) How many CH3 (methyl) groups are there in the molecule? D) How many CH2 (methylene) groups are there in the molecule? (i.e. # of C-atoms having exactly two bonded H-atoms) E) How many CH (methyne) groups are there in the molecule? (i.e. # of C-atoms having exactly one bonded H-atom) F) How many…arrow_forward
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