(a) Interpretation: All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included. Concept introduction: Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Question

Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0

Answer 1

Question

Chapter 1, Problem 1.53P

Interpretation Introduction

(a)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(b)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(c)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(d)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(e)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

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Part V. Label ad match the carbons in compounds Jane and Diane w/ the corresponding peak no. in the Spectra (Note: use the given peak no. To label the carbons, other peak no are intentionally omitted) 7 4 2 -0.13 -0.12 -0.11 -0.10 -0.08 8 CI Jane 1 -0.09 5 210 200 190 180 170 160 150 140 130 120 110 100 -8 90 f1 (ppm) 11 8 172.4 172.0 f1 (ppr HO CI NH Diane 7 3 11 80 80 -80 -R 70 60 60 2 5 -8 50 40 8. 170 160 150 140 130 120 110 100 90 -0 80 70 20 f1 (ppm) 15 30 -20 20 -60 60 -0.07 -0.06 -0.05 -0.04 -0.03 -0.02 -0.01 -0.00 -0.01 10 -0.17 16 15 56 16 -0.16 -0.15 -0.14 -0.13 -0.12 -0.11 -0.10 -0.09 -0.08 -0.07 -0.06 -0.05 -0.04 17.8 17.6 17.4 17.2 17.0 f1 (ppm) -0.03 -0.02 550 106 40 30 20 20 -0.01 -0.00 F-0.01 10 0

Consider the reaction of 2-methylpropane with a halogen. With which halogen will the product be almost exclusively 2-halo-2-methylpropane? 1. F2 2. Cl2 3. Br2 4. I2

None

Answer 2

Question

Chapter 1, Problem 1.53P

Interpretation Introduction

(a)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(b)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(c)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(d)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(e)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

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Answer 3

Question

Chapter 1, Problem 1.53P

Interpretation Introduction

(a)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(b)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(c)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(d)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(e)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

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Answer 4

Question

Chapter 1, Problem 1.53P

Interpretation Introduction

(a)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(b)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(c)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(d)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(e)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

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Answer 5

Chapter 1, Problem 1.53P

Interpretation Introduction

(a)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(b)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(c)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(d)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Interpretation Introduction

(e)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 6

Chapter 1, Problem 1.53P

Interpretation Introduction

(a)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 7

Chapter 1, Problem 1.53P

Interpretation Introduction

(a)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 8

Interpretation Introduction

(b)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 9

Interpretation Introduction

(b)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 10

Interpretation Introduction

(c)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 11

Interpretation Introduction

(c)

Interpretation:

All resonance contributors for the given ion are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 12

Interpretation Introduction

(d)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 13

Interpretation Introduction

(d)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 14

Interpretation Introduction

(e)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 15

Interpretation Introduction

(e)

Interpretation:

All resonance contributors for the given molecule are to be drawn. The curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next are to be included.

Concept introduction:

Resonance exists in molecules or ions for which there are two or more valid Lewis structures. For such molecules or ions, each valid Lewis structure is called a resonance contributor. Resonance contributors differ only in the position of their valence electrons, not their atoms.

Answer 16

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Answer 27

Ch. 1 - Prob. 1.1P Ch. 1 - Prob. 1.2P Ch. 1 - Prob. 1.3P Ch. 1 - Prob. 1.4P Ch. 1 - Prob. 1.5P Ch. 1 - Prob. 1.6P Ch. 1 - Prob. 1.7P Ch. 1 - Prob. 1.8P Ch. 1 - Prob. 1.9P Ch. 1 - Prob. 1.10P

Solution Summary: The author explains that resonance exists in molecules or ions for which there are two or more valid Lewis structures.

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