Organic Chemistry: Principles and Mechanisms (Second Edition)
2nd Edition
ISBN: 9780393663556
Author: Joel Karty
Publisher: W. W. Norton & Company
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 1, Problem 1.21P
Interpretation Introduction
(a)
Interpretation:
A resonance structure of the given species is to be drawn.
Concept introduction:
Resonance structures differ in the position of electrons. The position of atoms remains the same. Curved arrows are used to show the movement of a pair of valence electrons. The formal charge on the atoms changes when the lone pair on an atom is converted to a bonding pair or a bonding pair is converted to a lone pair.
Interpretation Introduction
(b)
Interpretation:
A resonance structure of the given species is to be drawn.
Concept introduction:
Resonance structures differ in the position of electrons; the position of atoms remains the same. Curved arrows are used to show the movement of a pair of valence electrons. The formal charge on the atoms changes when the lone pair on an atom is converted to a bonding pair or a bonding pair is converted to a lone pair.
Interpretation Introduction
(c)
Interpretation:
A resonance structure of the given species is to be drawn.
Concept introduction:
Resonance structures differ in the position of electrons only; the position of atoms remains the same. Curved arrows are used to show the movement of a pair of valence electrons. The formal charge on the atoms changes when the lone pair on an atom is converted to a bonding pair or a bonding pair is converted to a lone pair.
Expert Solution & Answer
Trending nowThis is a popular solution!
Students have asked these similar questions
Problem What amount (mol) of each ion is in each solution?(a) 5.0 mol of ammonium sulfate dissolved in water(b) 78.5 g of cesium bromide dissolved in water(c) 7.42×1022 formula units of copper(II) nitrate dissolved in water(d) 35 mL of 0.84 M zinc chloridePlan We write an equation that shows 1 mol of compound dissociating into ions. (a) We multiply the number of moles of ions by 5.0. (b) We first convert grams to moles. (c) We first convert formula units to moles. (d) We first convert molarity and volume to moles.
Draw the curved arrows to show the resonance structure for the following molecules.
( there are 3 molecules )
Draw all resonance contributors for each of the following molecules or ions. Be sure to
include the curved arrows that indicate which pairs of electrons are shifted in going
from one resonance structure to the next.
(a) CH3NO2
(b) CH, CO,
(c) CH CHCHCH2 (the ion has two C-C single bonds)
(d) C5H5N (a ring is formed by the C and N atoms, and each H is bonded to a C atom)
(e) C4H5N (a ring is formed by the C and N atoms, and the N is bonded to one H atom,
and each C atom is bonded to one H atom)
Chapter 1 Solutions
Organic Chemistry: Principles and Mechanisms (Second Edition)
Ch. 1 - Prob. 1.1PCh. 1 - Prob. 1.2PCh. 1 - Prob. 1.3PCh. 1 - Prob. 1.4PCh. 1 - Prob. 1.5PCh. 1 - Prob. 1.6PCh. 1 - Prob. 1.7PCh. 1 - Prob. 1.8PCh. 1 - Prob. 1.9PCh. 1 - Prob. 1.10P
Ch. 1 - Prob. 1.11PCh. 1 - Prob. 1.12PCh. 1 - Prob. 1.13PCh. 1 - Prob. 1.14PCh. 1 - Prob. 1.15PCh. 1 - Prob. 1.16PCh. 1 - Prob. 1.17PCh. 1 - Prob. 1.18PCh. 1 - Prob. 1.19PCh. 1 - Prob. 1.20PCh. 1 - Prob. 1.21PCh. 1 - Prob. 1.22PCh. 1 - Prob. 1.23PCh. 1 - Prob. 1.24PCh. 1 - Prob. 1.25PCh. 1 - Prob. 1.26PCh. 1 - Prob. 1.27PCh. 1 - Prob. 1.28PCh. 1 - Prob. 1.29PCh. 1 - Prob. 1.30PCh. 1 - Prob. 1.31PCh. 1 - Prob. 1.32PCh. 1 - Prob. 1.33PCh. 1 - Prob. 1.34PCh. 1 - Prob. 1.35PCh. 1 - Prob. 1.36PCh. 1 - Prob. 1.37PCh. 1 - Prob. 1.38PCh. 1 - Prob. 1.39PCh. 1 - Prob. 1.40PCh. 1 - Prob. 1.41PCh. 1 - Prob. 1.42PCh. 1 - Prob. 1.43PCh. 1 - Prob. 1.44PCh. 1 - Prob. 1.45PCh. 1 - Prob. 1.46PCh. 1 - Prob. 1.47PCh. 1 - Prob. 1.48PCh. 1 - Prob. 1.49PCh. 1 - Prob. 1.50PCh. 1 - Prob. 1.51PCh. 1 - Prob. 1.52PCh. 1 - Prob. 1.53PCh. 1 - Prob. 1.54PCh. 1 - Prob. 1.55PCh. 1 - Prob. 1.56PCh. 1 - Prob. 1.57PCh. 1 - Prob. 1.58PCh. 1 - Prob. 1.59PCh. 1 - Prob. 1.60PCh. 1 - Prob. 1.61PCh. 1 - Prob. 1.62PCh. 1 - Prob. 1.63PCh. 1 - Prob. 1.64PCh. 1 - Prob. 1.65PCh. 1 - Prob. 1.66PCh. 1 - Prob. 1.67PCh. 1 - Prob. 1.68PCh. 1 - Prob. 1.69PCh. 1 - Prob. 1.70PCh. 1 - Prob. 1.71PCh. 1 - Prob. 1.72PCh. 1 - Prob. 1.73PCh. 1 - Prob. 1.74PCh. 1 - Prob. 1.75PCh. 1 - Prob. 1.76PCh. 1 - Prob. 1.77PCh. 1 - Prob. 1.78PCh. 1 - Prob. 1.79PCh. 1 - Prob. 1.80PCh. 1 - Prob. 1.81PCh. 1 - Prob. 1.82PCh. 1 - Prob. 1.1YTCh. 1 - Prob. 1.2YTCh. 1 - Prob. 1.3YTCh. 1 - Prob. 1.4YTCh. 1 - Prob. 1.5YTCh. 1 - Prob. 1.6YTCh. 1 - Prob. 1.7YTCh. 1 - Prob. 1.8YTCh. 1 - Prob. 1.9YTCh. 1 - Prob. 1.10YTCh. 1 - Prob. 1.11YTCh. 1 - Prob. 1.12YTCh. 1 - Prob. 1.13YTCh. 1 - Prob. 1.14YTCh. 1 - Prob. 1.15YTCh. 1 - Prob. 1.16YTCh. 1 - Prob. 1.17YT
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- Consider compounds A–D, which contain both a heteroatom and a double bond. (a) For which compounds are no additional Lewis structures possible? (b) When two or more Lewis structures can be drawn, draw all additional resonance structures.arrow_forwardProblem: (a) Draw six (6) constitutional isomers of C6H1202. (b) Which of the compounds you drew would be the most soluble in water? Explain your choice. (c) Which of the compounds you drew would be the most soluble in hexane? Explain your choice.arrow_forward(a) Draw all resonance contributors of the following ion. In drawing each additional resonance structure, use curved arrows to indicate which pairs of electrons are being shifted. (b) Draw the resonance hybrid. (c) Which c–C bond is the longest?arrow_forward
- Hello, can you draw and name two different molecules (with the explicit formula) with a total of 12 carbons, together with the side groups, according to the options given? a)Write and name two cyclic amide molecule. b)Write and name two aromatic amine molecule.arrow_forwardProblem Which of the following substances exhibits H bonding? For any that do, show the H bonds between two of its molecules. (a) C̟H, (b) CH;OH (c) CH3C–NH,arrow_forward3) Draw two more resonance structures of the following compound. Order the structures by increasing stability.arrow_forward
- 3) Draw all resonance structures of the following compound. Order the structures by increasing stability.arrow_forwardDetermine the weakest C-H bond in each of the following compounds. (a) (b) (c) ОНarrow_forwardProblem Draw a Lewis structure and identify the octet-rule exception for (a) H3PO4 (draw two resonance forms and select the more important); (b) BFCl2.Plan We draw each Lewis structure and examine it for exceptions to the octet rule.(a) The central atom is in Period 3, so it can have more than an octet.(b) The central atom is B, which can have fewer than an octet of electrons.arrow_forward
- Problem Draw Lewis structures for the following:(a) Ethylene (C2H4), the most important reactant in the manufacture of polymers(b) Nitrogen (N2), the most abundant atmospheric gasPlan We show the structure resulting from steps 1 to 4: placing the atoms, counting the total valence electrons, making single bonds, and distributing the remaining valence electrons in pairs to attain octets. Then we continue with step 5, if needed.arrow_forwardDraw all of the resonance structures for each of the following species. Be sure to include the curved arrows that indicate which pairs of electrons are shifted in going from one resonance structure to the next. Draw the resonance hybrid of each species. (a) ОН (b) (c) H3Carrow_forwardDraw complete Lewis structures for the following condensed structural formulas.(a) CH3(CH2)3CH(CH3)2 (b) (CH3)2CHCH2Cl(c) CH3CH2COCN (d) CH2CHCHO(e) (CH3)3CCOCHCH2 (f) CH3COCOOHarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
Organic Chemistry: A Guided InquiryChemistryISBN:9780618974122Author:Andrei StraumanisPublisher:Cengage Learning
Organic Chemistry: A Guided Inquiry
Chemistry
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Cengage Learning