Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Chapter 1, Problem 1.112QP
Interpretation Introduction
Interpretation: From the given data, volume of carbon dioxide gas evolved should be determined
Concept introduction:
Volume, mass and density are related as follows:
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3. Consider the compounds below and determine if they are aromatic, antiaromatic, or
non-aromatic. In case of aromatic or anti-aromatic, please indicate number of I
electrons in the respective systems. (Hint: 1. Not all lone pair electrons were explicitly
drawn and you should be able to tell that the bonding electrons and lone pair electrons
should reside in which hybridized atomic orbital 2. You should consider ring strain-
flexibility and steric repulsion that facilitates adoption of aromaticity or avoidance of anti-
aromaticity)
H H
N
N:
NH2
N
Aromaticity
(Circle)
Aromatic Aromatic Aromatic Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic TT
electrons
Me
H
Me
Aromaticity
(Circle)
Aromatic Aromatic Aromatic
Aromatic Aromatic
Antiaromatic Antiaromatic Antiaromatic Antiaromatic Antiaromatic
nonaromatic nonaromatic nonaromatic nonaromatic nonaromatic
aromatic πT
electrons
H
HH…
A chemistry graduate student is studying the rate of this reaction:
2 HI (g) →H2(g) +12(g)
She fills a reaction vessel with HI and measures its concentration as the reaction proceeds:
time
(minutes)
[IH]
0
0.800M
1.0
0.301 M
2.0
0.185 M
3.0
0.134M
4.0
0.105 M
Use this data to answer the following questions.
Write the rate law for this reaction.
rate
= 0
Calculate the value of the rate constant k.
k =
Round your answer to 2 significant digits. Also be
sure your answer has the correct unit symbol.
Chapter 1 Solutions
Chemistry: Atoms First
Ch. 1.4 - illustrates conversions between these two...Ch. 1.4 - Prob. 1PPACh. 1.4 - According to the website of the National...Ch. 1.4 - If a single degree on the Celsius scale is...Ch. 1.4 - A body temperature above 39C constitutes a high...Ch. 1.4 - The average temperature at the summit of Mt....Ch. 1.4 - Prob. 2PPBCh. 1.4 - If a single degree on the Fahrenheit scale is...Ch. 1.4 - Prob. 1.3WECh. 1.4 - Given that 20.0 mL of mercury has a mass of 272 g....
Ch. 1.4 - Prob. 3PPBCh. 1.4 - Using the picture of the graduated cylinder and...Ch. 1.4 - Prob. 1.4.1SRCh. 1.4 - Prob. 1.4.2SRCh. 1.4 - Prob. 1.4.3SRCh. 1.4 - Prob. 1.4.4SRCh. 1.5 - Determine the number of significant figures in the...Ch. 1.5 - Determine the number of significant figures in the...Ch. 1.5 - Using scientific notation, express the number one...Ch. 1.5 - Prob. 4PPCCh. 1.5 - Perform the following arithmetic operations and...Ch. 1.5 - Perform the following arithmetic operations, and...Ch. 1.5 - Prob. 5PPBCh. 1.5 - Prob. 5PPCCh. 1.5 - Prob. 1.6WECh. 1.5 - Prob. 6PPACh. 1.5 - Prob. 6PPBCh. 1.5 - Several pieces of aluminum metal with a total mass...Ch. 1.5 - Prob. 1.5.1SRCh. 1.5 - Prob. 1.5.2SRCh. 1.5 - Prob. 1.5.3SRCh. 1.5 - Prob. 1.5.4SRCh. 1.5 - Prob. 1.5.5SRCh. 1.5 - Prob. 1.5.6SRCh. 1.6 - The Food and Drug Administration (FDA) recommends...Ch. 1.6 - The American Heart Association recommends that...Ch. 1.6 - A gold nugget has a mass of 0.9347 oz. What is its...Ch. 1.6 - The diagram contains several objects that are...Ch. 1.6 - Prob. 1.8WECh. 1.6 - Prob. 8PPACh. 1.6 - The density of mercury is 13.6 g/cm3. What is its...Ch. 1.6 - Each diagram [(i) or (ii)] shows the objects...Ch. 1.6 - Prob. 1.6.1SRCh. 1.6 - Prob. 1.6.2SRCh. 1.6 - Prob. 1.6.3SRCh. 1.6 - Prob. 1.6.4SRCh. 1 - Prob. 1.1QPCh. 1 - Explain what is meant by the scientific method.Ch. 1 - What is the difference between a hypothesis and a...Ch. 1 - Classily each of the following statements as a...Ch. 1 - Classify each of the following statements as a...Ch. 1 - Prob. 1.6QPCh. 1 - Prob. 1.7QPCh. 1 - Prob. 1.8QPCh. 1 - Classify each of the following as a pure...Ch. 1 - What is the difference between a qualitative...Ch. 1 - Prob. 1.11QPCh. 1 - Prob. 1.12QPCh. 1 - Determine which of the following properties are...Ch. 1 - Determine whether the following statements...Ch. 1 - Prob. 1.15QPCh. 1 - Determine whether each of the following describes...Ch. 1 - Determine whether each of the following describes...Ch. 1 - Name the SI base units that are important in...Ch. 1 - Write the numbers represented by the following...Ch. 1 - What units do chemists normally use for the...Ch. 1 - What is the difference between mass and weight? If...Ch. 1 - Prob. 1.22QPCh. 1 - Prob. 1.23QPCh. 1 - Prob. 1.24QPCh. 1 - Prob. 1.25QPCh. 1 - Prob. 1.26QPCh. 1 - The density of water at 40C is 0.992 g/mL. What is...Ch. 1 - Prob. 1.28QPCh. 1 - Prob. 1.29QPCh. 1 - Prob. 1.30QPCh. 1 - Prob. 1.31QPCh. 1 - Prob. 1.32QPCh. 1 - Indicate which of the following numbers is an...Ch. 1 - Prob. 1.34QPCh. 1 - Distinguish between the terms accuracy and...Ch. 1 - Express the following numbers in scientific...Ch. 1 - Prob. 1.37QPCh. 1 - Prob. 1.38QPCh. 1 - Express the answers to the following calculations...Ch. 1 - Determine the number of significant figures in...Ch. 1 - Prob. 1.41QPCh. 1 - Carry out the following operations as if they were...Ch. 1 - Prob. 1.43QPCh. 1 - Three students (A, B, and C) are asked to...Ch. 1 - Prob. 1.45QPCh. 1 - Prob. 1.46QPCh. 1 - Prob. 1.47QPCh. 1 - The density of the metal bar shown is 8.16 g/cm3....Ch. 1 - The following shows an experiment used to...Ch. 1 - Prob. 1.50QPCh. 1 - Prob. 1.51QPCh. 1 - Prob. 1.52QPCh. 1 - Carry out the following conversions: (a) 1.1 1022...Ch. 1 - The average speed of helium at 25C is 1255 m/s....Ch. 1 - Prob. 1.55QPCh. 1 - Prob. 1.56QPCh. 1 - Prob. 1.57QPCh. 1 - Prob. 1.58QPCh. 1 - Prob. 1.59QPCh. 1 - Prob. 1.60QPCh. 1 - Prob. 1.61QPCh. 1 - Prob. 1.62QPCh. 1 - Prob. 1.63QPCh. 1 - Prob. 1.64QPCh. 1 - The density of ammonia gas under certain...Ch. 1 - Prob. 1.66QPCh. 1 - ADDITIONAL PROBLEMS 1.67 Using the appropriate...Ch. 1 - Prob. 1.68QPCh. 1 - Winch of the following statements describe...Ch. 1 - Prob. 1.70QPCh. 1 - Prob. 1.71QPCh. 1 - In determining the density of a rectangular metal...Ch. 1 - Prob. 1.73QPCh. 1 - Prob. 1.74QPCh. 1 - Prob. 1.75QPCh. 1 - Prob. 1.76QPCh. 1 - Prob. 1.77QPCh. 1 - The experiment described in Problem 1.77 is a...Ch. 1 - Prob. 1.79QPCh. 1 - Lithium has a very low density (density = 0.53...Ch. 1 - Prob. 1.81QPCh. 1 - Vanillin (used to flavor vanilla ice cream and...Ch. 1 - Prob. 1.83QPCh. 1 - Prob. 1.84QPCh. 1 - Prob. 1.85QPCh. 1 - Prob. 1.86QPCh. 1 - Prob. 1.87QPCh. 1 - Magnesium is used in alloys, in batteries, and in...Ch. 1 - Prob. 1.89QPCh. 1 - The surface area and average depth of the Pacific...Ch. 1 - Calculate the percent error for the following...Ch. 1 - Prob. 1.92QPCh. 1 - Chalcopyrite contains 34.63 percent copper by...Ch. 1 - Prob. 1.94QPCh. 1 - One gallon of gasoline in an automobile's engine...Ch. 1 - Prob. 1.96QPCh. 1 - The worlds total petroleum reserve is estimated at...Ch. 1 - Prob. 1.98QPCh. 1 - Prob. 1.99QPCh. 1 - Chlorine is used to disinfect swimming pools. The...Ch. 1 - Prob. 1.101QPCh. 1 - Prob. 1.102QPCh. 1 - Prob. 1.103QPCh. 1 - Prob. 1.104QPCh. 1 - Prob. 1.105QPCh. 1 - Prob. 1.106QPCh. 1 - Prob. 1.107QPCh. 1 - Prob. 1.108QPCh. 1 - Prob. 1.109QPCh. 1 - Prob. 1.110QPCh. 1 - In January 2009, the National Aeronautics and...Ch. 1 - Prob. 1.112QPCh. 1 - Prob. 1.113QPCh. 1 - Prob. 1.114QPCh. 1 - Prob. 1.115QPCh. 1 - The composition of pennies has changed over the...
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