Chemistry: Atoms First
2nd Edition
ISBN: 9780073511184
Author: Julia Burdge, Jason Overby Professor
Publisher: McGraw-Hill Education
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Question
Chapter 1.5, Problem 1.6WE
Interpretation Introduction
Interpretation:
The density of the gas should be calculated with giving the appropriate significant figure.
Concept Introduction:
Density: The density of the substance is calculated using the formula:
For the given set of calculations the significant figures and their correct measurement has to be given.
Significant figures: The digits having a meaning in a given number are called as significant figures.
Significant figures –calculation rules
- Significant figure is a non-zero number (4443.2 has five significant figures)
- Zeros placement in between non-zero number are significant figures (40005 has five significant figures).
- Zeros before the non-zero number are not significant number (0.00040005 has five significant figures).
- Zeros after the non-zero number are significant in case of that number contains decimal point (4.5000 has five significant figures).
- Zeros after the non-zero number may or may not be a significant figure in case of that number does not have a decimal point (500 may have 1, 2 or 3 significant figures). In this cases use scientific notation to avoid ambiguity.
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Use the systematic treatment of equilibrium to determine the pH and the concentrations of all species in a saturated aqueous solution of SrF2. Do not include activity coefficients. The solubility of SrF2 is governed by
Ksp for the salt, hydrolysis of F- and of Sr2+, and by ion pairing between Sr2 + and F-.
PK(SrF2) = 8.58, PK(HF) = 3.17, pkw = 14.00, pk for the formation of (SrOH+) = 13.18,
pk for the formation of (SrF+) = 0.14
Show all your work and upload your answers here.
1 - Write the pertinent reactions.
2 - Write mass balance and charge balance equations.
3 - Write the equilibrium constant expressions.
4 - Count the equations and unknowns.
5- If the problem is solvable make suitable approximations and find the concentrations and the pH.
Chapter 1 Solutions
Chemistry: Atoms First
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