Examine the following reaction mechanisms and classify the role of each labeled species in the table below. Check all boxes that apply. :Br a + :0: MgBr + H :0: C d Br. b Br Br Classify each species. Check all that apply. ? OH + MgBrOH O Species Electrophile Nucleophile Brønsted Acid Brønsted Base None a b C d O O Х olo Ar B'
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Examine the following mechanism and classify the role of each labeled species in the table below. Check all the boxes that apply
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- Describe the classic experiments of Steward, Gurdon, and Wilmut.Bruce Ames and his colleagues have pointed out that although detailed toxicological analysis has been conducted on synthetic chemicals, almost no information is available about the mutagenic or carcinogenic effects of the toxins produced by plants as a natural defense against fungi, insects, and animal predators. Tens of thousands of such compounds have been discovered, and he estimates that in the United States adults eat about 1.5 g of these compounds each daylevels that are approximately 10,000 times higher than those of the synthetic pesticides present in the diet. For example, cabbage contains 49 natural pesticides and metabolites, and only a few of these have been tested for their carcinogenic and mutagenic effects. a. With the introduction of new foods into the U.S. diet over the last 200 years (mangoes, kiwi fruit, tomatoes, and so forth), has there been enough time for humans to develop resistance to the mutagenic effects of the toxins present in those foods? b. The natural pesticides present in plants constitute more than 99% of the toxins we eat. Should diet planning, especially for vegetarians, take into account the doses of toxins present in the diet?The genus Ferroplasma consists of a few species of acid-loving archaea. One species, F. acidarmanus, was discovered to be the main component of slime streamers (a type of biofilm) deep inside an abandoned California copper mine (Figure 4.11A). F. acidarmanus cells use an ancient energy-harvesting pathway that combines oxygen with ironsulfur compounds in minerals such as pyrite. This reaction dissolves the minerals, so groundwater that seeps into the mine ends up with extremely high concentrations of metal ions such as copper, zinc, cadmium, and arsenic. The reaction also produces sulfuric acid, which lowers the pH of the water around the cells to zero. Despite living in an environment with a composition similar to hot battery acid, F. acidarmanus cells maintain their internal pH at a cozy 5.0. Thus, researchers investigating Ferroplasma metabolic enzymes were surprised to discover that most of the cells enzymes function best at very low pH (Figure 4.11B). A. Deep inside one of the most toxic sites in the United States: Iron Mountain Mine, in California. The water in this stream, which is about 1 meter (3 feet) wide in this photo, is hot (around 40C, or 104F), heavily laden with arsenic and other toxic metals, and has a pH of zero. Slime streamers growing in it are a biofilm dominated by a species of archaea, Ferroplasma acidarmanus. B. pH profiles of four enzymes isolated from F. acidarmus. Researchers had expected these enzymes to function best at the cells cytoplasmic pH (5.0). What does the dashed line signify?
- Which of the following pathways requires molecular oxygen (O2)? a. aerobic respiration b. lactate formation c. alcoholic fermentation d. photosynthesisIn what form is energy transferred in a redox reaction?Figure 27.3 illustrates the response of R (ATP-regenerating) and U (ATP-utilizing) enzymes to energy charge. a. Would hexokinase be an R enzyme or a U enzyme? Would glutamine: PRPP amidotransferase, the second enzyme in purine biosynthesis, be an R enzyme or a U enzyme? b. If energy charge = 0.5: Is the activity of hexokinase high or low? Is ribose-5-P pyrophosphokinase activity high or low? c. If energy charge = 0.95: Is the activity of hexokinase high or low? Is ribose-5-P pyrophosphokinase activity high or low?
- Which of the following comparisons or contrasts between endergonic and exergonic reactions is false? Endergonic reactions have a positive ?G and exergonic reactions have a negative ?G Endergonic reactions consume energy and exergonic reactions release energy Both endergonic and exergonic reactions require a small amount of energy to overcome an activation barrier Endergonic reactions take place slowly and exergonic reactions take place quickly.Ammonification is the process by which. ammonia is released during the decomposition of nitrogen-containing organic compounds ammonium is converted to nitrite and nitrate in soils nitrate from soil is transformed to gaseous nitrogen compounds such as NO, N2O, and N2 gaseous nitrogen is fixed to yield ammoniaWhich of these statements is true? An antibiotic is any substance produced by a organism that is antagonistic to the growth of prokaryotes An antibiotic is any substance produced by a prokaryote that is antagonistic to the growth of other viruses An antibiotic is any substance produced by a prokaryote that is antagonistic to the growth of eukaryotic cells An antibiotic is any substance produced by a prokaryote that prevents growth of the same prokaryote.
- Chemiosmosis involves a. the movement of electrons across the cell membrane. b. the movement of hydrogen atoms across a mitochondrial membrane. c. the movement of hydrogen ions across a mitochondrial membrane. d. the movement of glucose through the cell membrane.Both prokaryotic and eukaryotic organisms carry out some form of glycolysis. How does ha fact support or not support the assertion that glycolysis is one of the oldest metabolic pathways?