Solutions for Principles of Modern Chemistry
Problem 1P:
A newly synthesized compound has the molecular Formula ClF2O2PtF6. Compute, to four significant...Problem 2P:
Acetaminophen is the generic name of the pain reliever in Tylenol and some other headache remedies....Problem 3P:
Arrange the following compounds from left to right in order of increasing percentage by mass of...Problem 4P:
Arrange the following compounds from left to right in order of increasing percentage by mass of...Problem 5P:
“Q-gas” is a mixture of 98.70% helium and 1.30% butane (C4H10) by mass. It is used as a filling for...Problem 6P:
A pharmacist prepares an antiulcer medicine by mixing 286gNa2CO3 with water, adding 150 g glycine...Problem 7P:
Zinc phosphate is used as a dental cement. A 50.00-mg sample is broken down into its constituent...Problem 8P:
Bromoform is 94.85% bromine, 0.40% hydrogen, and 4.75% carbon by mass. Determine its empirical...Problem 9P:
Fulgurites are the products of the melting that occurs when lightning strikes the earth. Microscopic...Problem 10P:
A sample of a “suboxide” of cesium gives up 1.6907% of its mass as gaseous oxygen when gently...Problem 11P:
Barium and nitrogen form two binary compounds containing 90.745% and 93.634% barium, respectively....Problem 15P:
The empirical formula of a gaseous fluorocarbon is CF2 . At a certain temperature and pressure, a...Problem 16P:
At its boiling point (280°C) and at atmospheric pressure, phosphorus has a gas density of 2.7gL1 ....Problem 17P:
A gaseous binary compound has a vapor density that is 1.94 times that of oxygen at the same...Problem 18P:
A gaseous binary compound has a vapor density that is 2.53 times that of nitrogen at 100°C and...Problem 21P:
For each of the following chemical reactions, calculate the mass of the underlined reactant that is...Problem 23P:
An 18.6-g sample of K2CO3 was treated in such a way thatall of its carbon was captured in the...Problem 25P:
Disilane (Si2H6) is a gas that reacts with oxygen to givesilica (SiO2) and water. Calculate the mass...Problem 26P:
Tetrasilane (Si4H10) is a liquid with a density of 0.825 gcm23. It reacts with oxygen to give silica...Problem 27P:
Cryolite (Na3AlF6) is used in the production of aluminumfrom its ores. It is made by the reaction...Problem 28P:
Carbon disulfide (CS2) is a liquid that is used in the productionof rayon and cellophane. It is...Problem 29P:
Potassium nitrate (KNO3) is used as a fertilizer for certaincrops. It is produced through the...Problem 30P:
Elemental phosphorus can be prepared from calciumphosphate via the overall reaction 2Ca3(...Problem 31P:
An element X has a dibromide with the empirical formula XBr2 and a dichloride with the empirical...Problem 32P:
An element A has a triiodide with the formula AI3 and atrichloride with the formula ACl3 . The...Problem 33P:
A mixture consisting of only sodium chloride (NaCl) andpotassium chloride (KCl) weighs 1.0000 g....Problem 34P:
A mixture of aluminum and iron weighing 9.62 g reactswith hydrogen chloride in aqueous solution...Problem 35P:
When ammonia is mixed with hydrogen chloride (HCl),the white solid ammonium chloride (NH4Cl) is...Problem 36P:
The poisonous gas hydrogen cyanide (HCN) is producedby the high-temperature reaction of ammonia with...Problem 37P:
The iron oxide Fe2O3 reacts with carbon monoxide (CO)to give iron and carbon dioxide:...Problem 39AP:
Human parathormone has the impressive molecularFormula C691H898N125O164S11 . Compute the mass...Problem 40AP:
A white oxide of tungsten is 79.2976% tungsten by mass.A blue tungsten oxide also contains...Problem 41AP:
A dark brown binary compound contains oxygen and ametal. It is 13.38% oxygen by mass. Heating it...Problem 42AP:
A binary compound of nickel and oxygen contains78.06% nickel by mass. Is this a stoichiometric or a...Problem 43AP:
Two binary oxides of the element manganese contain,respectively, 30.40% and 36.81% oxygen by mass....Problem 44AP:
A possible practical way to eliminate oxides of nitrogen(such as NO2 ) from automobile exhaust gases...Problem 45AP:
Aspartame (molecularformula C14H18N2O5 ) is a sugar substitutein soft drinks. Under certain...Problem 48AP:
Citric acid (C6H8O7) is made by fermentation of sugarssuch as sucrose (C12H22O11) in air. Oxygen is...Problem 50AP:
A sample of a substance with the empirical formula XBr2 weighs 0.5000 g. When it is dissolved in...Problem 51AP:
A newspaper article about the danger of global warmingfrom the accumulation of greenhouse gases such...Problem 52AP:
In the Solvay process for producing sodium carbonate (Na2CO3) , the following reactions occur in...Browse All Chapters of This Textbook
Chapter 1 - The Atom In Modern ChemistryChapter 2 - Chemical Formulas, Equations, And Reaction YieldsChapter 3 - Atomic Shells And Classical Models Of Chemical BondingChapter 4 - Introduction To Quantum MechanicsChapter 5 - Quantum Mechanics And Atomic StructureChapter 6 - Quantum Mechanics And Molecular StructureChapter 7 - Bonding In Organic MoleculesChapter 8 - Bonding In Transition Metal Compounds And Coordination ComplexesChapter 9 - The Gaseous StateChapter 10 - Solids, Liquids, And Phase Transitions
Chapter 11 - SolutionsChapter 12 - Thermodynamic Processes And ThermochemistryChapter 13 - Spontaneous Processes And Thermodynamic EquilibriumChapter 14 - Chemical EquilibriumChapter 15 - Acid–base EquilibriaChapter 16 - Solubility And Precipitation EquilibriaChapter 17 - ElectrochemistryChapter 18 - Chemical KineticsChapter 19 - Nuclear ChemistryChapter 20 - Molecular Spectroscopy And PhotochemistryChapter 21 - Structure And Bonding In SolidsChapter 22 - Inorganic MaterialsChapter 23 - Polymeric Materials And Soft Condensed MatterChapter A - Scientific Notation And Experimental Error
Book Details
Long considered the standard for covering chemistry at a high level, PRINCIPLES OF MODERN CHEMISTRY continues to set the standard as the most modern, rigorous, and chemically and mathematically accurate book on the market. This authoritative text features an "atoms first" approach and thoroughly revised chapters on Quantum Mechanics and Molecular Structure (Chapter 6), Electrochemistry (Chapter 17), and Molecular Spectroscopy and Photochemistry (Chapter 20). In addition, the text utilizes mathematically accurate and artistic atomic and molecular orbital art, and is student friendly without compromising its rigor. End-of-chapter learning aids now focus on only the most important key objectives, equations and concepts, making it easier for readers to locate chapter content, while new applications to a wide range of disciplines, such as biology, chemical engineering, biochemistry, and medicine deepen readers' understanding of the relevance of chemistry in today's world.
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Principles of Modern Chemistry
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