Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 14, Problem 76AP

Methanol can be synthesized by means of the equilibriumreaction
CO ( g ) + 2 H 2 ( g ) CH 3 OH ( g )
for which the equilibrium constant at 225°C is 6.08 × 10 3 . Assume that the ratio of the pressures of CO(g) and H 2 ( g ) is 1:2. What values should they have if the partial pressureof methanol is to be 0.500 atm?

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3. An unknown element, X, combines with chlorine to give a substance with the formula XC14. A chlorine analysis of the substance indicates that it contains 83.47% chlorine by mass. What element is X and what is the formula of this compound? (Hint: to identify an element or compound, identify its molar mass. Remember that Molar Mass = (grams A)/(moles A). Solve for each individually and then divide them to find molar mass.)
1. When hydrogen sulfide (H2S, MM = 34.08 g/mol) gas is bubbled into a solution of sodium hydroxide (NaOH, 40.00 g/mol), sodium sulfide (Na2S, 78.04 g/mol) and water (18.02 g/mol) are produced according to the balanced chemical equation shown below? H2S 2 NaOH --> Na2S 2 H₂O (a) Assuming the reaction goes to completion, how many grams of sodium sulfide are formed if 2.50g of hydrogen sulfide is bubbled into a solution containing 1.85g of NaOH? (20 pts) (b) Which reactant and how much of it remains after the reaction has been completed? (15 pts) (c) If only 0.400g of sodium sulfide was recovered, what is the percent yield of this reaction (5 pts)
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