Principles of Modern Chemistry
Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 14, Problem 110CP

At 1200 K in the presence of solid carbon, an equilibriummixture of CO and CO 2 (called “producer gas”) contains98.3 mol percent CO and 1.69 mol percent of CO 2 whenthe total pressure is 1 atm. The reaction is
CO 2 ( g ) + C ( g r a p h i t e ) 2 CO ( g )

  1. Calculate P CO and P CO 2 .
  2. Calculate the equilibrium constant.
  3. Calculate Δ G ° for this reaction.

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In a system with an anodic overpotential, the variation of ŋ as a function of the current density: 1. at low fields is linear 2. at higher fields, it follows Tafel's law Find the range of current densities for which the overpotential has the same value as when calculated for cases 1 and 2 (maximum relative difference of 5% with respect to the behavior for higher fields). To which overpotential range does this correspond? Data: 10 = 1.5 mA cm², T = 300°C, ẞ = 0.64, R = 8.314 J K 1 mol‍¹ and F = 96485 C mol-1.
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