Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 15, Problem 28P
Vitamin C is ascorbic acid
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Chapter 15 Solutions
Principles of Modern Chemistry
Ch. 15 - Vitamin C is ascorbic acid (HC6H7O6), for which Ka...Ch. 15 - Suppose a 0.100 M solution of each of the...Ch. 15 - Sulfanilic acid (NH2C6H4SO3H) is used in...Ch. 15 - Phthalic acid ( H2C8H4O4, abbreviated H2Ph ) is a...Ch. 15 - Prob. 88APCh. 15 - Prob. 94APCh. 15 - Prob. 100APCh. 15 - Prob. 102AP
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- Lactic acid, C3H6O3, occurs in sour milk as a result of the metabolism of certain bacteria. Calculate the pH of a solution of 56. mg lactic acid in 250. mL water. Ka for D-lactic acid is 1.5 × 10−4.arrow_forwardBarbituric acid, HC4H3N2O3, is used to prepare barbiturates, a class of drugs used as sedatives. A 325-mL aqueous solution of barbituric acid has a pH of 2.34 and contains 9.00 g of the acid. What is Ka for barbituric acid?arrow_forwardA solution of acetic acid, HC2H3O2, on a laboratory shelf was of undetermined concentration. If the pH of the solution was found to be 2.57, what was the concentration of the acetic acid? The Ka of acetic acid is 1.7 105.arrow_forward
- The base ethylamine (CH3CH2NH2) has a Kb of. A closely related base, ethanolamine(HOCH2CH2NH2), has a Kb of 3.2105. (a) Which of the two bases is stronger? (b) Calculate the pH of a 0.10M solution of the strong base?arrow_forwardNicotinic acid, C6H5NO2, is found in minute amounts in all living cells, hut appreciable amounts occur in liver, yeast, milk, adrenal glands, white meat, and corn. Whole wheat (lour contains about 60. 0g per gram of flour. One gram (1.00 g) of the acid dissolves in water to give 60. mL of solution having a pH of 2.70. What is the approximate value of Ka for the acid? Nicotinic acidarrow_forwardConsider 0.10 M solutions of the following compound: AlCl3, NaCN, KOH, CsClO4, and NaF. Place these solutions in order of increasing pH.arrow_forward
- What is the pH of a solution obtained by mixing 235 mL of NaOH with a pH of 11.57 and 316 mL of Sr(OH)2 with a pH of 12.09? Assume that volumes are additive.arrow_forwardConsider pyridine, C5H5N, a pesticide and deer repellent. Its conjugate acid, C5H5NH+, has K a =6.7106. (a) Write a balanced net ionic equation for the reaction that shows the basicity of aqueous solutions of pyridine. (b) Calculate Kb for the reaction in (a). (c) Find the pH of a solution prepared by mixing 2.74 g of pyridine in enough water to make 685 mL of solution.arrow_forwardWrite the reaction and the corresponding Kb equilibrium expression for each of the following substances acting as bases in water. a. aniline, C6H5NH2 b. dimethylamine, (CH3)2NHarrow_forward
- C6H4NH2COOH, para-aminobenzoic acid (PABA), is used in some sunscreen agents. Calculate the concentrations of hydronium ion and para-aminobenzoate ion, C6H4NH2COO, in a 0.080 M solution of the acid. The value of Ka is 2.2 105.arrow_forwardA chemist wanted to determine the concentration of a solution of lactic acid, HC3H5O3. She found that the pH of the solution was 2.60. What was the concentration of the solution? The Kd of lactic acid is 1.4 104.arrow_forwardFor conjugate acidbase pairs, how are Ka and Kb related? Consider the reaction of acetic acid in water CH3CO2H(aq)+H2O(l)CH3CO2(aq)+H3O+(aq) where Ka = 1.8 105 a. Which two bases are competing for the proton? b. Which is the stronger base? c. In light of your answer to part b. why do we classify the acetate ion (CH3CO2) as a weak base? Use an appropriate reaction to justify your answer. In general, as base strength increases, conjugate acid strength decreases. Explain why the conjugate acid of the weak base NH3 is a weak acid. To summarize, the conjugate base of a weak acid is a weak base and the conjugate acid of a weak base is a weak acid (weak gives you weak). Assuming Ka for a monoprotic strong acid is 1 106, calculate Kb for the conjugate base of this strong acid. Why do conjugate bases of strong acids have no basic properties in water? List the conjugate bases of the six common strong acids. To tie it all together, some instructors have students think of Li+, K+, Rb+, Cs+, Ca2+, Sr2+, and Ba2+ as the conjugate acids of the strong bases LiOH, KOH. RbOH, CsOH, Ca(OH)2, Sr(OH)2, and Ba(OH)2. Although not technically correct, the conjugate acid strength of these cations is similar to the conjugate base strength of the strong acids. That is, these cations have no acidic properties in water; similarly, the conjugate bases of strong acids have no basic properties (strong gives you worthless). Fill in the blanks with the correct response. The conjugate base of a weak acid is a_____base. The conjugate acid of a weak base is a_____acid. The conjugate base of a strong acid is a_____base. The conjugate acid of a strong base is a_____ acid. (Hint: Weak gives you weak and strong gives you worthless.)arrow_forward
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