Principles of Modern Chemistry
8th Edition
ISBN: 9781305079113
Author: David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher: Cengage Learning
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Chapter 2, Problem 43AP
Two binary oxides of the element manganese contain,respectively, 30.40% and 36.81% oxygen by mass. Calculatethe empirical formulas of the two oxides.
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Rank the following compounds most to least acidic:
a)
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OH
.OH
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F
F
F
F
OH
F
b)
Ha
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CI
Ha
F
F CI
Ha
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b)
Provide arrows to show the mechanisms and then predict the products of the following acid
base reaction. Use pKas to determine which way the reaction will favor (Hint: the lower pka
acid will want to dissociate)
Дон
OH
Ha
OH
NH2
c)
H
H-O-H
MATERIALS. Differentiate between interstitial position and reticular position.
Chapter 2 Solutions
Principles of Modern Chemistry
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Ch. 2 - Barium and nitrogen form two binary compounds...Ch. 2 - Prob. 12PCh. 2 - Prob. 13PCh. 2 - Prob. 14PCh. 2 - The empirical formula of a gaseous fluorocarbon is...Ch. 2 - At its boiling point (280°C) and at atmospheric...Ch. 2 - A gaseous binary compound has a vapor density that...Ch. 2 - A gaseous binary compound has a vapor density that...Ch. 2 - Prob. 19PCh. 2 - Prob. 20PCh. 2 - For each of the following chemical reactions,...Ch. 2 - Prob. 22PCh. 2 - An 18.6-g sample of K2CO3 was treated in such a...Ch. 2 - Prob. 24PCh. 2 - Disilane (Si2H6) is a gas that reacts with oxygen...Ch. 2 - Tetrasilane (Si4H10) is a liquid with a density of...Ch. 2 - Cryolite (Na3AlF6) is used in the production of...Ch. 2 - Carbon disulfide (CS2) is a liquid that is used in...Ch. 2 - Potassium nitrate (KNO3) is used as a fertilizer...Ch. 2 - Elemental phosphorus can be prepared from...Ch. 2 - An element X has a dibromide with the empirical...Ch. 2 - An element A has a triiodide with the formula AI3...Ch. 2 - A mixture consisting of only sodium chloride...Ch. 2 - A mixture of aluminum and iron weighing 9.62 g...Ch. 2 - When ammonia is mixed with hydrogen chloride...Ch. 2 - The poisonous gas hydrogen cyanide (HCN) is...Ch. 2 - The iron oxide Fe2O3 reacts with carbon monoxide...Ch. 2 - Titanium dioxide, TiO2 , reacts with carbon and...Ch. 2 - Human parathormone has the impressive...Ch. 2 - A white oxide of tungsten is 79.2976% tungsten by...Ch. 2 - A dark brown binary compound contains oxygen and...Ch. 2 - A binary compound of nickel and oxygen...Ch. 2 - Two binary oxides of the element manganese...Ch. 2 - A possible practical way to eliminate oxides of...Ch. 2 - Aspartame (molecularformula C14H18N2O5 ) is a...Ch. 2 - Prob. 46APCh. 2 - Prob. 47APCh. 2 - Citric acid (C6H8O7) is made by fermentation of...Ch. 2 - Prob. 49APCh. 2 - A sample of a substance with the empirical formula...Ch. 2 - A newspaper article about the danger of global...Ch. 2 - In the Solvay process for producing sodium...Ch. 2 - A yield of 3.00gKClO4 is obtained from the...Ch. 2 - Prob. 54APCh. 2 - Silicon nitride (Si3N4) , a valuable ceramic, is...
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- For each of the following, indicate whether the arrow pushes are valid. Do we break any rules via the arrows? If not, indicate what is incorrect. Hint: Draw the product of the arrow and see if you still have a valid structure. a. b. N OH C. H N + H d. e. f. مه N COHarrow_forwardDecide which is the most acidic proton (H) in the following compounds. Which one can be removed most easily? a) Ha Нь b) Ha Нь c) CI CI Cl Ha Ньarrow_forwardProvide all of the possible resonanse structures for the following compounds. Indicate which is the major contributor when applicable. Show your arrow pushing. a) H+ O: b) c) : N :O : : 0 d) e) Оarrow_forward
- Draw e arrows between the following resonance structures: a) b) : 0: :0: c) :0: N t : 0: بار Narrow_forwardDraw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. Cl Substitution will not occur at a significant rate. Explanation Check :☐ O-CH + Х Click and drag to start drawing a structure.arrow_forwardDraw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. Cl C O Substitution will not occur at a significant rate. Explanation Check + O-CH3 Х Click and drag to start drawing a structure.arrow_forward
- ✓ aw the major substitution products you would expect for the reaction shown below. If substitution would not occur at a significant rate under these conditions, check the box underneath the drawing area instead. Be sure you use wedge and dash bonds where necessary, for example to distinguish between major products. Note for advanced students: you can assume that the reaction mixture is heated mildly, somewhat above room temperature, but strong heat or reflux is not used. C Cl HO–CH O Substitution will not occur at a significant rate. Explanation Check -3 ☐ : + D Click and drag to start drawing a structure. © 2025 McGraw Hill LLC. All Rights Reserved. Terms of Use Privacy Cearrow_forwardPlease correct answer and don't used hand raitingarrow_forwardDon't used hand raiting and don't used Ai solutionarrow_forward
- Determine whether the following reaction is an example of a nucleophilic substitution reaction: Br OH HO 2 -- Molecule A Molecule B + Br 义 ollo 18 Is this a nucleophilic substitution reaction? If this is a nucleophilic substitution reaction, answer the remaining questions in this table. Which of the reactants is referred to as the nucleophile in this reaction? Which of the reactants is referred to as the organic substrate in this reaction? Use a ŏ + symbol to label the electrophilic carbon that is attacked during the substitution. Highlight the leaving group on the appropriate reactant. ◇ Yes O No O Molecule A Molecule B Molecule A Molecule B टेarrow_forwardPlease correct answer and don't used hand raitingarrow_forwardPlease correct answer and don't used hand raitingarrow_forward
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