CHEMISTRY, AP EDITION-W/ACCESS (HS)9th EditionZUMDAHL Publisher: CENGAGE LISBN: 9781285732930
CHEMISTRY, AP EDITION-W/ACCESS (HS)
Solutions for CHEMISTRY,AP EDITION-W/ACCESS (HS)
Problem 1RQ:
Four types of electromagnetic radiation (EMR) are ultraviolet, microwaves, gamma rays, and visible....Problem 2RQ:
Characterize the Bohr model of the atom. In the Bohr model, what do we mean when we say something is...Problem 3RQ:
What experimental evidence supports the quantum theory of light? Explain the wave-particle duality...Problem 4RQ:
List the most important ideas of the quantum mechanical model of the atom. Include in your...Problem 5RQ:
What are quantum numbers? What information do we get from the quantum numbers n, l, and ml? We...Problem 6RQ:
How do 2p orbitals differ from each other? How do 2p and 3p orbitals differ from each other? What is...Problem 7RQ:
Four blocks of elements in a periodic table refer to various atomic orbitals being filled. What are...Problem 8RQ:
What is the difference between core electrons and valence electrons? Why do we emphasize the valence...Problem 10RQ:
The radius trend and the ionization energy trend are exact opposites. Does this make sense?Problem 2ALQ:
Defend and criticize Bohrs model. Why was it reasonable that such a model was proposed, and what...Problem 3ALQ:
The first four ionization energies for the elements X and Y are shown below. The units are not...Problem 4ALQ:
Compare the first ionization energy of helium to its second ionization energy, remembering that both...Problem 6ALQ:
Explain why a graph of ionization energy versus atomic number (across a row) is not linear. Where...Problem 7ALQ:
Without referring to your text, predict the trend of second ionization energies for the elements...Problem 8ALQ:
Account for the fact that the line that separates the metals from the nonmetals on the periodic...Problem 9ALQ:
Explain electron from a quantum mechanical perspective, including a discussion of atomic radii,...Problem 10ALQ:
Choose the best response for the following. The ionization energy for the chlorine atom is equal in...Problem 11ALQ:
Consider the following statement "The ionization energy for the potassium atom is negative, because...Problem 13ALQ:
How does probability fit into the description of the atom?Problem 14ALQ:
What is meant by an orbital?Problem 15ALQ:
Explain the difference between the probability density distribution for an orbital and its radial...Problem 16ALQ:
Is the following statement true or false? The hydrogen atom has a 3s orbital. Explain.Problem 17ALQ:
Which is higher in energy, the 2s or 2p orbital, in hydrogen? Is this also true for helium? Explain.Problem 18ALQ:
Prove mathematically that it is more energetically favorable for a fluorine atom to take an electron...Problem 19Q:
What type of relationship (direct or inverse) e xists between wavelength, frequency, and photon...Problem 20Q:
What do we mean by the frequency of electromagnetic radiation? Is the frequency the same as the...Problem 21Q:
Explain the photoelectric effectProblem 22Q:
Describe briefly why the study of electromagnetic radiation bas been important to our understanding...Problem 23Q:
How does the wavelength of a fast-pitched baseball compare to the wavelength of an electron...Problem 24Q:
The following is an energy-level diagram for electronic transitions in the Bohr hydrogen atom. a....Problem 25Q:
The Bohr model works for only one electron species. Why do we discuss it in this text (what's good...Problem 26Q:
We can represent both probability and radial probability versus distance from the nucleus for a...Problem 27Q:
Consider the representations of the p and d atomic orbitals in Figs. 2-15 and 2- 17. What do the +...Problem 28Q:
The periodic table consists of four blocks of elements that correspond to s, p, d, and f orbitals...Problem 29Q:
Many times the claim is made that subshells half-filled with electrons are particularly stable. Can...Problem 31Q:
Elements with very large ionization energies also tend to have highly negative (favorable) electron...Problem 32Q:
The changes in electron affinity as one goes down a group in the periodic table are not nearly as...Problem 33Q:
Why is it much harder to explain the line spectra of polyelectronic atoms and ions than it is to...Problem 34Q:
Scientists use emission spectra to confirm the presence of an element in materials of unknown...Problem 36Q:
In the hydtogen atom, what is the physical significance of the for which n = and E = 0?Problem 37Q:
The work function is the energy required to remove an electron from an atom on the surface of a...Problem 38Q:
Many more anhydrous lithium salts are hygroscopic (readily absorb water) than are those of the other...Problem 39E:
The laser in an audio CD player uses light with u wavelength of 7.80 102 nm. Calculate the...Problem 40E:
An FM radio station broadcasts at 99.5 MHz. Calculate the wavelength of the corresponding radio...Problem 41E:
Microwave radiation has a wavelength on the order of 1.0 cm. Calculate the frequency and the energy...Problem 42E:
A photon of ultraviolet (UV) light possesses enough energy to mutate a strand of human DNA. What is...Problem 43E:
Octyl methoxycinoamate and oxybenzone are common ingredients in sunscreen applications. These...Problem 44E:
Human color vision is " produced" by the nervous system based on how three different cone receptors...Problem 45E:
Consider the following waves representing electromagnetic radiation: Which wave has the longer...Problem 46E:
One type of electromagnetic radiation has a frequency of 107.1 MHz, another type has a wavelength of...Problem 47E:
Carbon absorbs energy at a wavelength of 150. nm. The total amount of energy emitted by a carbon...Problem 48E:
X rays have wavelengths on the order of 1 1010 m. Calculate the energy of 1.0 1010 m X rays in...Problem 49E:
The work function of an element is the energy required to remove an electron from the surface of the...Problem 50E:
It takes 208.4 kJ of energy to remove 1 mole of electrons from an atom on the surface of rubidium...Problem 51E:
It takes 7.21 1019 J of energy to remove an electron from an iron atom. What is the maximum...Problem 52E:
Ionization energy is the energy required to remove an electron from an atom in the gas phase. The...Problem 53E:
Calculate the de Broglie wavelength for each of the following. a. an electron with a velocity 10.%...Problem 54E:
Neutron diffraction is used in determining the structures of molecules. a. Calculate the de Broglie...Problem 55E:
A particle has a velocity that is 90.% of the speed of light. If the wavelength of the particle is...Problem 56E:
Calculate the velocities of electrons with de Broglie wavelengths of 1.0 102 nm and 1.0 nm,...Problem 57E:
Calculate the wavelength of light emiued when each of the following transitions occur in the...Problem 58E:
Calculate the wavelength of light emitted when each of the following transitions occur in the...Problem 59E:
Using vertical lines, indicate the transitions from Exercise 57 on an energy-level diagram for the...Problem 60E:
Using vertical lines, indicate the transitions from Exercise 58 on an energy-level diagram for the...Problem 61E:
Calculate the longest and shortest wavelengths of light emitted by electrons in the hydrogen atom...Problem 62E:
Assume that a hydrogen atoms electron has been excited to the n = 5 level. How many different...Problem 63E:
Does a photon of visible light ( 400 to 700 nm) have sufficient energy to excite an electron in a...Problem 64E:
An electron is excited from the n = 1 ground state to the n = 3 state in a hydrogen atom. Which of...Problem 65E:
Calculate the maximum wavelength of light capable of removing an electron for a hydrogen atom from...Problem 66E:
Consider an electron for a hydrogen atom in an excited state. The maximum wavelength of...Problem 67E:
An excited hydrogen atom with an electron in the n = 5 state emits light having a frequency of 6.90 ...Problem 68E:
An excited hydrogen atom emits light with a wavelength of 397.2 nm to reach the energy level for...Problem 69E:
Using the Heisenberg uncertainty principle, calculate x for each of the following. a. an electron...Problem 70E:
The Heisenberg uncertainty principle can be expressed in the form Eth4 where E represents energy and...Problem 72E:
Identify each of the following orbitals and determine the n and l quantum numbers. Explain your...Problem 73E:
Which of the following sets of quantum numbers are not allowed in the hydrogen atom? For the sets of...Problem 74E:
Which of the following sets of quantum numbers are not allowed? For each incorrect set, state why it...Problem 75E:
What is the physical significance of the value of 2 at a particular point in an atomic orbital?Problem 76E:
In defining the sizes of orbitals, why must we use an arbitrary value, such as 90% of the...Problem 77E:
Total radial probability distributions for the helium, neon, and argon atoms are shown in the...Problem 78E:
Tbe relative orbital levels for the hydrogen atom can be represented as Draw the relative orbital...Problem 81E:
Give the maximum number of electrons in an atom that can have these quantum numbers: a. n = 4 b. n =...Problem 82E:
Give the maximum number of electrons in an atom that can have these quantum numbers: a. n = 0, l =...Problem 83E:
Draw atomic orbital diagrams representing the ground-state electron configumtion for each of the...Problem 84E:
For elements l36, there are two exceptions to the filling order as predicted from the periodic...Problem 85E:
The elements Si, Ga, As, Ge, Al, Cd, S, and Se are all used in the manufacture of various...Problem 86E:
The elements Cu, O, La, Y, Ba, Tl, and Bi are all found in high-temperature ceramic superconductors....Problem 87E:
Write the expected electron configurations for each of the following atoms: Sc, Fe, P, Cs, Eu, Pt,...Problem 88E:
Write the expected electron configurations for each of the following atoms: Cl, Sb, Sr, W, Pb, Cf.Problem 89E:
Write the expected ground-state electron configuration for the following. a. the element with one...Problem 90E:
Using only the periodic table inside the front cover of the text, write the expected ground-state...Problem 91E:
Given the valence electron orbital level diagram and the description, identify the element or ion....Problem 92E:
Identify the following elements. a. An excited state of this element has the electron configuration...Problem 93E:
In the ground state of mercury, Hg, a. how many electrons occupy atomic orbitals with n = 3? b. how...Problem 94E:
In the ground state of element 115, Uup, a. how many electrons have n = 5 as one of their quantum...Problem 95E:
Give a possible set of values of the four quantum numbers for all the electrons in a boron atom and...Problem 96E:
Give a possible set of values of the four quantum numbers for the 4s and 3d electrons in titanium.Problem 97E:
Valence electrons are those electrons in the outermost principal quantum level (highest n level) of...Problem 98E:
How many valence electrons do each of the following elements have, and what are the specific valence...Problem 99E:
A certain oxygen atom has the electron configuration 1s22s22px22py2. How many unpaired electrons are...Problem 100E:
Which of the following electron configurations correspond to an excited state? Identify the atoms...Problem 103E:
One bit of evidence that the quantum mechanical model is correct lies in the magnetic properties of...Problem 104E:
Identify how many unpaired electrons are present in each of the followiog in the ground state: O,...Problem 106E:
Arrange the following groups of atoms in order of increasing size. a. Rb, Na, Be b. Sr, Se, Ne c....Problem 109E:
In each of the following sets, which atom or ion bas the smallest radius? a. H, He b. Cl, In, Se c....Problem 110E:
In each of the following sets, which atom or ion has the smallest ionization energy? a. Ca, Sr, Ba...Problem 111E:
Element 106 has been named seaborgium, Sg, in honor of Glenn Seaborg, discoverer of the first...Problem 113E:
The first ionization energies of As and Se are 0.947 and 0.941 MJ/mol, respectively. Rationalize...Problem 114E:
Rank the elements Be, B, C, N, and O in order of increasing first ionization energy. Explain your...Problem 116E:
The following graph plots the first, second, and third ionization energies for Mg, Al, and Si....Problem 117E:
For each of the following pairs of elements (C and N) (Ar and Br) pick the atom with a. more...Problem 118E:
For each of the following pairs of elements (Mg and K) (F and Cl) pick the atom with a. more...Problem 119E:
The electron affinities of the elements from aluminum to chlorine are 44, 120, 74, 200.4, and ...Problem 120E:
In the second row of the periodic table, Be, N, and Ne all have positive (unfavorable) electron...Problem 122E:
Order the atoms in each of the following sets from the least negative electron affinity to the most....Problem 123E:
The electron affinity for sulfur is more negative than that for oxygen. How do you account for this?Problem 124E:
Which has the more negative electron affinity, the oxygen, atom or the O ion? Explain your answer.Problem 125E:
Write equations corresponding to the following: a. the fourth ionization energy of Se b. the...Problem 126E:
Using data from the text, determine the following values (justify your answer): a. the electron...Problem 129E:
Cesium was discovered in natural mineral waters in 1860 by R. W. Bunsen and G. R. Kirchhoff, using...Problem 130E:
'The bright yellow light emitted by a sodium vapor lamp consists of two emission Lines at 589.0 and...Problem 131E:
Does the information on alkali metals in Table 2-8 of the text confirm the general periodic trends...Problem 132E:
Predict the atomic number of the next alkali metal after francium and give its ground-state electron...Problem 133E:
Complete and balance the equations for the following reactions. a.Li(s) + N2(g) b.Rb(s) + S(s)Problem 135AE:
"Lithium" is often prescribed as a mood-stabilizing drug. Do you think the lithium prescribed is in...Problem 136AE:
A carbon-oxygen double bond in a certain organic molecule absorbs radiation that has a frequency of...Problem 137AE:
Photogray lenses incorporate small amounts of silver chloride in the glass of the lens. When light...Problem 139AE:
Mars is roughly 60 million km from the earth. How long does it take for a radio signal originating...Problem 140AE:
Consider the following approximate visible light spectrum: Barium emits light in the visible region...Problem 141AE:
One of the visible lines in the hydrogen emission spectrum corresponds to the n = 6 to n = 2...Problem 142AE:
Using Fig. 2-30, list the elements (ignore the lanthanides and actinides) that have ground-state...Problem 143AE:
Are the following statements true for the hydrogen atom only, true for all atoms, or not true for...Problem 144AE:
Although no currently known elements contain electrons in g orbitals in the ground state, it is...Problem 145AE:
Which of the following orbital designations are incorrect: 1s, 1p, 7d, 9s, 3f, 4f, 2d?Problem 146AE:
The four most abundant elements by mass in the human body are oxygen, carbon, hydrogen, and...Problem 147AE:
Consider the eight most abundant elements in the human body, as outlined in Exercise 156. Excluding...Problem 148AE:
An ion having a 4+ charge and a mass of 49.9 u has 2 electrons with principal quantum number n = 1.8...Problem 149AE:
The successive ionization energies for an unknown element are I1 = 896 kJ/mol I2 = 1752 kJ/mol I3 =...Problem 150AE:
In the ground state of cadmium, Cd, a. how many electrons have l = 2 as one of their quantum...Problem 153CWP:
It takes 476 kJ to remove 1 mole of electrons from the atoms at the surface of a solid metal. How...Problem 154CWP:
Calculate, to four significant figures, the longest and shortest wavelengths of light emitted by...Problem 155CWP:
Assume that a hydrogen atoms electron bas been excited to the n = 6 level. How many different...Problem 156CWP:
Determine the maximum number of electrons that can have each of the following designations: 2f,...Problem 157CWP:
Consider the ground state of arsenic, As. How many electrons have l = 1 as one of their quantum...Problem 158CWP:
Which of the following statements is(are) true? a. The 2s orbital in the hydrogen atom is larger...Problem 159CWP:
Identify the following three elements. a. The ground-state electron configuration is [Kr]5s24d105p4....Problem 160CWP:
For each of the following pairs of elements, choose the one that correctly completes the following...Problem 161CWP:
Which of the following statements is(are) true? a. F has a larger first ionization energy than does...Problem 162CWP:
Three elements have the electron configurations 1s22s22P63s2, 1s22s22p63s23p4, and...Problem 163CP:
The figure below represents part of the emission spectrum for a one-electron ion in the gas phase....Problem 164CP:
One of the emission spectral lines for Be3+ has a wavelength of 253.4 nm for an electronic...Problem 165CP:
The figure below represents part of the emission spectrum for a one-electron ion in lhe gas phase....Problem 166CP:
When lhe excited electron in a hydrogen atom falls from n = 5 to n = 2, a photon of blue light is...Problem 169CP:
The wave function for the 2pz, orbital in the hydrogen atom is 2pl=142(za0)3/2e/2cos where a0 is the...Problem 170CP:
Answer the following questions, assuming that ms, could have three values rather than two and that...Problem 171CP:
Assume that we are in another universe with different physical laws. Electrons in this universe are...Problem 172CP:
Without looking at data in the text, sketch a qualitative graph of the third ionization energy...Problem 173CP:
The following numbers are the ratios of second ionization energy to first ionization energy: Na: 9.2...Problem 174CP:
We expect the atomic radius to increase going down a group in the periodic table. Can you suggest...Problem 175CP:
The ionization energy for a 1s electron in a silver atom is 2.462 106 kJ/mol. a. Determine an...Problem 177CP:
An atom of a particular element is traveling at 1.00% of the speed of light. The de Broglie...Browse All Chapters of This Textbook
Chapter 1 - Chemical FoundationsChapter 2 - Atoms, Molecules, And IonsChapter 3 - StoichiometryChapter 4 - Types Of Chemical Reactions And Solution StoichiometryChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - Atomic Structure And PeriodicityChapter 8 - Bonding: General ConceptsChapter 9 - Covalent Bonding: OrbitalsChapter 10 - Liquids And Solids
Chapter 11 - Properties Of SolutionsChapter 12 - Chemical KineticsChapter 13 - Chemical EquilibriumChapter 14 - Acids And BasesChapter 15 - Acid-base EquilibriaChapter 16 - Solubility And Complex Ion EquilibriaChapter 17 - Spontaneity, Entropy, And Free EnergyChapter 18 - ElectrochemistryChapter 19 - The Nucleus: A Chemist's ViewChapter 20 - The Representative ElementsChapter 21 - Transition Metals And Coordination ChemistryChapter 22 - Organic And Biological Molecules
Sample Solutions for this Textbook
We offer sample solutions for CHEMISTRY,AP EDITION-W/ACCESS (HS) homework problems. See examples below:
Chapter 1, Problem 1RQChapter 1, Problem 30EChapter 1, Problem 35EChapter 1, Problem 36EChapter 1, Problem 38EChapter 1, Problem 45EChapter 1, Problem 57EChapter 1, Problem 59EChapter 1, Problem 60E
Chapter 1, Problem 63EChapter 1, Problem 64EChapter 1, Problem 73EChapter 1, Problem 113CPChapter 2, Problem 1RQChapter 2, Problem 64EChapter 2, Problem 67EChapter 2, Problem 68EExplanation: Atomic number given is 13. From the periodic table we can identify that the element...Chapter 2, Problem 71EExplanation: To determine: The naming of CuI The name of CuI is copper(I) iodide. In naming of...Explanation: To determine: The naming of HC2H3O2 The naming of HC2H3O2 is acetic acid. Rules for...To determine: The formula of of sulfur difluoride The formula of sulfur difluoride is SF2 Sulfur...Explanation: To determine: The formula of sodium oxide. The formula of sodium oxide is Na2O The...Chapter 2, Problem 86EChapter 2, Problem 88EExplanation: To determine: The formula and the name of the binary compound formed from Ca and N. The...Explanation: To determine: The explanation for the term “counting by weighing”. The stated concept,...Chapter 3, Problem 59EChapter 3, Problem 60EChapter 3, Problem 61EExplanation: Given The mass of P4O6 is 1.00 g . The molar mass of P4O6 is 219.866 g/mol . Formula...Chapter 3, Problem 64EChapter 3, Problem 67EChapter 3, Problem 68EChapter 3, Problem 71EChapter 3, Problem 73EChapter 3, Problem 76EChapter 3, Problem 79EChapter 3, Problem 100EChapter 3, Problem 109EChapter 3, Problem 119EChapter 3, Problem 121EChapter 3, Problem 124EChapter 3, Problem 150AEChapter 3, Problem 152CWPChapter 3, Problem 180IPChapter 4, Problem 1RQChapter 4, Problem 7RQExplanation: NaBr(s)→Na(aq)++Braq- Figure 1 Let us consider the above molecular-level pictures of...Explanation: Record the given data Moles of Sodium phosphate= 0.200 moles Volume of the solution=...Chapter 4, Problem 66EChapter 4, Problem 79EChapter 4, Problem 82EChapter 4, Problem 93AEChapter 4, Problem 121CPChapter 4, Problem 122CPChapter 4, Problem 123CPExplanation Record the given data Mass of the sample mixture = 0.205 g Mass of the precipitate =...Explanation: Given: Record the given data Upstream at which the stream rate flows = 5.00×104 L/s...Chapter 4, Problem 144MPChapter 4, Problem 145MPA barometer consists of Mercury column that is tipped inverted and positioned in a dish containing...Chapter 5, Problem 41EExplanation: The relation between pressures measured in the manometers containing mercury and...Explanation According to ideal gas equation, PV=nRT By rearranging the above equation, PVnT=R Since...Chapter 5, Problem 88EExplanation: To find: the mole fractions of CH4 and O2 in the given mixture if the partial pressure...Explanation To find: the number of moles of dimethyl hydrazine from its given mass. The number of...Explanation To determine: The partial pressure of carbon monoxide Partial pressure of carbon...Explanation To determine: The mixing ratio of benzene Mixing ratio of benzene = 9.47 × 10-3ppmv For...Explanation: The mass percent from the given data is, 26.1% Carbon13.1% Hydrogen61.0% Nitrogen Mass...Chapter 5, Problem 135AEExplanation To find: the empirical formula of the compound Convert the mass percent to gram 58.51%...Chapter 5, Problem 139AEChapter 5, Problem 152CPChapter 5, Problem 153CPExplanation To determine: Mass of hot air when the average molar mass of air 29.0g/mol Mass of hot...Chapter 5, Problem 162IPChapter 6, Problem 1RQChapter 6, Problem 20QChapter 6, Problem 34EChapter 6, Problem 50EChapter 6, Problem 52EChapter 6, Problem 79EChapter 6, Problem 80EExplanation: The balanced equation is: a) N2(g)→N2(l) In (a) the volume of products is decreases...Chapter 6, Problem 108AEChapter 6, Problem 115AEChapter 6, Problem 130CPChapter 6, Problem 131CPChapter 6, Problem 134IPChapter 6, Problem 135IPChapter 6, Problem 137MPChapter 7, Problem 1RQChapter 7, Problem 24QChapter 7, Problem 43EChapter 7, Problem 57EChapter 7, Problem 58EChapter 7, Problem 61EChapter 7, Problem 62EChapter 7, Problem 63EChapter 7, Problem 74EChapter 7, Problem 79EChapter 7, Problem 81EChapter 7, Problem 82EChapter 7, Problem 86EChapter 7, Problem 87EChapter 7, Problem 94EChapter 7, Problem 95EChapter 7, Problem 97EChapter 7, Problem 142AEChapter 7, Problem 171CPChapter 8, Problem 1RQExplanation: Refer to figure 3-4. The electro negativity of carbon (C) , nitrogen (N) , and oxygen...Explanation: Refer to figure 3-4 The electro negativity of Sodium (Na) Potassium (K) and Rubidium...Chapter 8, Problem 46EChapter 8, Problem 47EChapter 8, Problem 49EExplanation: In a periodic table the size of ions depends on the nuclear attraction on the valence...Chapter 8, Problem 54EChapter 8, Problem 62EChapter 8, Problem 81EChapter 8, Problem 84EChapter 8, Problem 89EChapter 8, Problem 101EChapter 8, Problem 102EChapter 8, Problem 129AEChapter 8, Problem 154CPChapter 8, Problem 155CPChapter 9, Problem 1RQChapter 9, Problem 23EChapter 9, Problem 24EChapter 9, Problem 26EChapter 9, Problem 29EChapter 9, Problem 30EChapter 9, Problem 39EChapter 9, Problem 52EChapter 9, Problem 53EChapter 9, Problem 63AEChapter 9, Problem 89CPChapter 10, Problem 1RQChapter 10, Problem 41EExplanation: CCl4 , CBr4, CF4 Identify the compound which has highest boiling point and justify it....Chapter 10, Problem 53EChapter 10, Problem 55EChapter 10, Problem 56EChapter 10, Problem 57EChapter 10, Problem 58EChapter 10, Problem 59EChapter 10, Problem 60EChapter 10, Problem 62EChapter 10, Problem 80EChapter 10, Problem 88EChapter 10, Problem 131CPChapter 10, Problem 146CPChapter 10, Problem 148IPExplanation: To explain molarity Molarity can be defined as moles of solute to litres of solution....Chapter 11, Problem 16SRChapter 11, Problem 31EExplanation: Record the given data Gram equivalent of HCl = 0.25 Molarity of HCl = 0.25 M To...Explanation: KrF2 8+2(7)=22e- KrF2 is dissolves in CCl4 . KrF2 is non-polar molecule that makes it...Chapter 11, Problem 55EChapter 11, Problem 79EExplanation: Record the given data, Molality of MgCl2= 0.050 m Molality of FeCl3= 0.050 m To...Explanation: Record the given data, Molality of MgCl2= 0.050 m Molality of FeCl3= 0.050 m To...Explanation: To find the Acetone and water polarity CH3COCH3 and H2O The electrostatic possible...Explanation: Record the given data, Freezing point of an aqueous solution =- 2.79°C To calculate...Mass of Sodium = 285-315 mg Mass of Potassium = 14.1-17.3 mg Mass of Calcium = 4.9-6.0 mg Mass of...Chapter 11, Problem 109AEChapter 11, Problem 120CPChapter 11, Problem 132IPChapter 12, Problem 1RQChapter 12, Problem 30EChapter 12, Problem 33EChapter 12, Problem 35EChapter 12, Problem 36EChapter 12, Problem 58EChapter 12, Problem 84AEChapter 12, Problem 86AEChapter 12, Problem 87AEChapter 12, Problem 91AEChapter 12, Problem 93AEChapter 12, Problem 105CPChapter 12, Problem 112CPChapter 13, Problem 1RQChapter 13, Problem 5ALQChapter 13, Problem 23EChapter 13, Problem 39EChapter 13, Problem 42EChapter 13, Problem 54EChapter 13, Problem 56EChapter 13, Problem 57EChapter 13, Problem 72AEChapter 13, Problem 73AEChapter 13, Problem 78AEChapter 13, Problem 104CPChapter 13, Problem 106CPChapter 14, Problem 1RQChapter 14, Problem 49EChapter 14, Problem 50EChapter 14, Problem 51EChapter 14, Problem 52EChapter 14, Problem 63EChapter 14, Problem 64EChapter 14, Problem 68EChapter 14, Problem 73EChapter 14, Problem 74EExplanation: To determine: The pH, [H+] and [OH−] of (C2H5)3N . The equilibrium constant expression...Chapter 14, Problem 101EChapter 14, Problem 107EChapter 14, Problem 108EChapter 14, Problem 109EChapter 14, Problem 119EChapter 14, Problem 120EChapter 14, Problem 123EChapter 14, Problem 126EChapter 14, Problem 151AEChapter 15, Problem 1RQChapter 15, Problem 7RQChapter 15, Problem 43EChapter 15, Problem 57EChapter 15, Problem 58EChapter 15, Problem 59EChapter 15, Problem 60EChapter 15, Problem 61EChapter 15, Problem 62EChapter 15, Problem 63EChapter 15, Problem 64EChapter 15, Problem 65EExplanation The value of pH of solution when 0.0 mL NaOH has been added is. 1.0_ . Given: The...Chapter 15, Problem 107CWPChapter 16, Problem 1RQExplanation To determine: The solubility product of CaC2O4 . The concentration of Ca2+ is 4.8×10−5...Chapter 16, Problem 22EChapter 16, Problem 27EChapter 16, Problem 28EChapter 16, Problem 35EChapter 16, Problem 36EChapter 16, Problem 37EChapter 16, Problem 40EChapter 16, Problem 53EChapter 16, Problem 70EChapter 16, Problem 102CPChapter 17, Problem 1RQChapter 17, Problem 53EChapter 17, Problem 54EChapter 17, Problem 63EChapter 17, Problem 64EChapter 17, Problem 68EChapter 17, Problem 70EChapter 17, Problem 72EChapter 17, Problem 74EChapter 17, Problem 78EChapter 17, Problem 86AEChapter 17, Problem 90AEChapter 17, Problem 119MPChapter 18, Problem 1RQChapter 18, Problem 16RORRExplanation: Given: I- (aq) + ClO- (aq) →I3− (aq) + Cl-(aq) To write the equations for two...Explanation: Given: Cu (s) + NO3- (aq) →Cu2+ (aq) + NO(g) To write the equations for two...Chapter 18, Problem 47EChapter 18, Problem 75EChapter 18, Problem 76EChapter 18, Problem 85EChapter 18, Problem 86EChapter 18, Problem 95EChapter 18, Problem 115AEChapter 18, Problem 117AEExplanation: Given The given reaction is, Fe(s)+HCl(aq)→HFeCl4(aq)+H2(g) . In this equation, the...Chapter 18, Problem 144CPExplanation The half cell reactions are, Anode: Hg→Hg2++2e− Eanodeο=0.242 V Cathode: 2Ag++2e−→2Ag...Chapter 18, Problem 153CPChapter 18, Problem 159MPExplanation (a) To define: The term thermodynamic stability. The thermodynamic stability is related...Explanation: Alpha particle is emitted. The parent nuclide is 232Th and the nuclide after the...Explanation The most stable isotope is 81Kr and the hottest one is 73Kr The nuclides having longer...Explanation Given The atomic mass of 232Pu is 3.85285×10−22 g . The mass of a neutron is...Explanation The atomic mass of 11H=1.0078 amu The mass of a neutron is 1.0087 amu . Mass of...Explanation Given The value of half life of 87Rb is 4.5×109 years . The decay constant is calculated...Explanation The decay constant is calculated by the formula given below. λ=0.693t1/2 Where t1/2 is...Explanation: The zirconium metal is capable of reducing water to form hydrogen gas at standard...Explanation The number of α and β particles produced are 4_ and 2_ . The mass number of 92238U is...Explanation The nuclear reaction for the synthesis of cobalt- 60 is, 2658Fe+201n→ 2760Co+ −10e . The...Chapter 20, Problem 1RQExplanation The valence electron configuration for halogens is ns2np5 . The common halogen elements...Explanation The value of ΔH° for the given reaction is 180 kJ_ . The stated reaction is,...Explanation: The compound XeO4 and IO4− ion are isoelectronic. The molecule xenon tetroxide (XeO4)...Explanation: The Lewis structure, molecular structure, bond angle and hybridization of central atom...Explanation Given Dimension of room is 10.0 m×10.0 m×10.0 m . Temperature is 25 °C . Pressure is...Explanation: Hydrogen gas is produced by reacting graphite with water. C(s)+H2O(g)→CO(g)+H2(g) The...Explanation: The number of moles of hydrogen gas is 0.249 mol_. Given Mass of alkaline earth metal...Explanation: Mass of radon (Ra) is 25 g_ . Given Mass of pitch-blende is 1.75×108 g . The conversion...Explanation Given Temperature is 900 K . Pressure of In(CH3)3 is 2.00 atm . Volume of In(CH3)3 is...Chapter 20, Problem 108IPChapter 20, Problem 109IPChapter 21, Problem 1RQExplanation: (I) To determine: The geometry and associated bond angles when a metal ion has a...Explanation: Atomic number of Nickel is 28 . Accordingly the electronic configuration is –...Explanation: Atomic number of Nickel is 22 . Accordingly the electronic configuration is –...EXPLANATION (a) To write: The electron configuration of metal ion in (NH4)2[Fe(H2O)2Cl4] . The...Explanation The complex ion is [Ru(NH3)5Cl]2+. This ion contains positive charge. Oxidation state of...Explanation The complex compound is [Co(NH3)6]Cl2 . Oxidation state of Chlorine ion (Cl−) is −1 ....Explanation The complex compound is [Cr(H2O)5Br]Br2 . Oxidation state of Bromine ion (Br−) is −1 ....Explanation The value of ΔH° for the given reaction is −11 kJ_ . For the reaction,...Explanation The reaction that takes place is, 3Fe2O3(s)+CO(g)→2Fe3O4(s)+CO2(g) Refer to Appendix 4....Explanation The given equations are, Co+3+e−→Co+2 Eο=1.82 V (1) Co2++3en→Co(en)32+ K=1.5×1012 (2)...Chapter 21, Problem 99IPChapter 22, Problem 1RQChapter 22, Problem 5RQExplanation: The type of isomerism that could be exhibited by C6H12 and an example that illustrates...Chapter 22, Problem 16EChapter 22, Problem 45EExplanation To determine: The monomer of the given polymer. The monomer is vinyl fluoride. It is an...Explanation The correct name of the compound is 2,3,5,6−Tetramethyl−octane whose structure is shown...Explanation The structure of the given compound 2,3,7,8−tetrachloro−dibenzo−p−dioxin is shown in...Chapter 22, Problem 130AEChapter 22, Problem 136AEExplanation The equilibrium constant for the given reaction is 6.88×10−13_ . The equilibrium...Chapter 22, Problem 148CPExplanation The structure of C5H12 is shown in Figure 1. The structure of C5H12 is, Figure 1 The...Explanation The structure of the polymer of ABS plastic is shown in figure 1. The reaction of Abs...Explanation Given Electronic configuration of M+2 is [Ar]3d10. So, atomic number of M is 30. In...Explanation The empirical formula of the given helicene is C5H3 . Helicene is an aromatic compound...The correct responses are urea and Ammonium cyanate. The first organic compound that is synthesized...Explanation Aldohexose is a six carbon aldehyde sugar with an aldehyde group on one end.
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