CHEMISTRY, AP EDITION-W/ACCESS (HS)9th EditionZUMDAHL Publisher: CENGAGE LISBN: 9781285732930
CHEMISTRY, AP EDITION-W/ACCESS (HS)
Solutions for CHEMISTRY,AP EDITION-W/ACCESS (HS)
Problem 1RQ:
Define the following terms: potential energy, kinetic energy, path-dependent function, state...Problem 2RQ:
Consider the following potential energy diagrams for two different reactions. Which plot represents...Problem 3RQ:
What is the first law of thermodynamics? How can a system change its internal energy, E? What are...Problem 4RQ:
When a gas expands, what is the sign of w? Why? When a gas contracts, what is the sign of w? Why?...Problem 5RQ:
What is the heat gained/released at constant pressure equal1o (qp = ?)? What is the heat...Problem 6RQ:
High-quality audio amplifiers generate large amounts of heat. To dissipate the heat and prevent...Problem 7RQ:
Explain how calorimetry works to calculate H or E for a reaction. Does the temperature of the...Problem 8RQ:
What is Hesss law? When a reaction is reversed, what happens to the sign and magnitude of H for that...Problem 9RQ:
Define the standard enthalpy of formation. What are standard states for elements and for compounds?...Problem 1ALQ:
Objects placed together eventually reach the same temperature. When you go into a room and touch a...Problem 2ALQ:
What is meant by the term lower in energy? Which is lower in energy, a mixture of hydrogen and...Problem 3ALQ:
A fire is started in a fireplace by striking a match and lighting crumpled paper under some logs....Problem 4ALQ:
Liquid water turns to ice. Is this process endothermic or exothermic? Explain what is occurring...Problem 5ALQ:
Consider the following statements: ''Heat is a form of energy, and energy is conserved. The heat...Problem 6ALQ:
Consider 5.5 L of a gas at a pressure of 3.0 atm in a cylinder with a movable piston. The external...Problem 7ALQ:
Consider 5.5 L of a gas at a pressure of 3.0 atm in a cylinder with a movable piston. The external...Problem 9ALQ:
Hesss law is really just another statement of the first law of thermodynamics. Explain.Problem 10ALQ:
In the equation w = P V, why is there a negative sign?Problem 11Q:
Consider an airplane trip from Chicago, Illinois, to Denver, Colorado. List some path-dependent...Problem 12Q:
How is average bond strength related to relative potential energies of the reactants and the...Problem 13Q:
Assuming gasoline is pure C8H18(l), predict the signs of q and w for the process of combusting...Problem 14Q:
What is the difference between H and E?Problem 15Q:
The enthalpy change for the reaction CH4(g)+2O2(g)CO2(g)+2H2O(l) is 891 kJ for the reaction as...Problem 16Q:
For the reaction HgO(s)Hg(l)+12O2(g),H=+90.7kJ: a.What quantity of heat is required to produce 1...Problem 17Q:
The enthalpy of combustion of CH4(g) when H2O(l) is formed is 891 kJ/mol and the enthalpy of...Problem 18Q:
The enthalpy change for a reaction is a state function and it is an extensive property. Explain.Problem 20Q:
The combustion of methane can be represented as follows: a. Use the information given above to...Problem 21Q:
Why is it a good idea to rinse your thermos bottle with hot water before filling it with hot coffee?Problem 26E:
Which has the greater kinetic energy, an object with a mass of 2.0 kg and a velocity of 1.0 m/s or...Problem 27E:
Consider the following diagram when answering the questions below. a. Compare balls A and B in terms...Problem 31E:
Calculate E for each of the following. a. q = 47 kJ, w = + 88 kJ b. q = +82 kJ, w = 47 kJ c. q = +...Problem 32E:
A system undergoes a process consisting of the following two steps: Step 1: The system absorbs 72 J...Problem 33E:
If the internal energy of a thermodynamic system is increased by 300. J while 75 J of expansion work...Problem 34E:
Calculate the internal energy change for each of the following. a. One hundred (100.) joules of work...Problem 35E:
A sample of an ideal gas at 15.0 atm and 10.0 L is allowed to expand against a constant external...Problem 36E:
A piston performs work of 210. L atm on the surroundings, while the cylinder in which it is placed...Problem 37E:
Consider a mixture of air and gasoline vapor in a cylinder with a piston. The original volume is 40....Problem 38E:
As a system increases in volume, it absorbs 52.5 J of energy in the form of heat from the...Problem 39E:
A balloon filled with 39.1 moles of helium has a volume of 876 L at 0.0C and 1.00 atm pressure. The...Problem 40E:
One mole of H2O(g) at 1.00 atm and 100.C occupies a volume of 30.6 L. When 1 mole of H2O(g) is...Problem 41E:
One of the components of polluted air is NO. It is formed in the high-temperature environment of...Problem 42E:
The reaction SO3(g)+H2O(l)H2SO4(aq) is the last step in the commercial production of sulfuric acid....Problem 43E:
Are the following processes exothermic or endothermic? a. When solid KBr is dissolved in water, the...Problem 44E:
Are the following processes exothermic or endothermic? a. the combustion of gasoline in a car engine...Problem 45E:
The overall reaction in a commercial heat pack can be represented as 4Fe(s)+3O2(g)2Fe2O3(s)H=1652KJ...Problem 46E:
Consider the following reaction: 2H2(g)+O2(g)2H2O(l)H=572KJ a. How much heat is evolved for the...Problem 47E:
Consider the combustion of propane: C3H8(g)+5O2(g)3CO2(g)+4H2O(l)H=2221KJ Assume that all the heat...Problem 48E:
Consider the following reaction: CH4(g)+2O2(g)CO2(g)+2H2O(l)H=891KJ Calculate the enthalpy change...Problem 49E:
For the process H2O(l) H2O(g) at 298 K and 1.0 atm. H is more positive than E by 2.5 kJ/mol. What...Problem 50E:
For the following reactions at constant pressure, predict if H E, H E, or H = E. a. 2HF(g) H2(g)...Problem 51E:
Consider the substances in Table 7-1. Which substance requires the largest amount of energy to raise...Problem 52E:
The specific heat capacity of silver is 0.24 J/Cg. a. Calculate the energy required to raise the...Problem 53E:
A 500-g sample of one of the substances listed in Table 7-1 was heated from 25.2C to 55.1C,...Problem 54E:
It takes 585 J of energy to raise the temperature of 125.6 g mercury from 20.0C to 53.5C. Calculate...Problem 55E:
A 30.0-g sample of water at 280. K is mixed with 50.0 g water at 330. K. Calculate the final...Problem 56E:
A biology experiment requires the preparation of a water bath at 37.0C (body temperature). The...Problem 57E:
A 5.00-g sample of aluminum pellets (specific heat capacity = 0.89 J/C g) and a 10.00-g sample of...Problem 58E:
Hydrogen gives off 120. J/g of energy when burned in oxygen, and methane gives off 50. J/g under the...Problem 59E:
A 150.0-g sample of a metal at75.0C is added to 150.0 g H2O at 15.0C. The temperature of the water...Problem 60E:
A 110.-g sample of copper (specific heat capacity = 0.20 J/C g) is heated to 82.4C and then placed...Problem 61E:
In a coffee-cup calorimeter, 50.0 mL of 0.100 M AgNO3 and 50.0 mL of 0.100 M HCl are mixed to yield...Problem 62E:
In a coffee-cup calorimeter, 100.0 mL of 1.0 M NaOH and 100.0 mL of 1.0 M HCI are mixed. Both...Problem 63E:
A coffee-cup calorimeter initially contains 125 g water at 24.2C. Potassium bromide (10.5 g), also...Problem 64E:
In a coffee-cup calorimeter, 1.60 g NH4NO3 is mixed with 75.0 g water at an initial temperature of...Problem 65E:
Consider the dissolution of CaCl2: CaCl2(s)Ca2+(aq)+2Cl(aq)H=81.5KJ An 11.0-g sample of CaCl2 is...Problem 66E:
Consider the reaction 2HCl(aq)+Ba(OH)2(aq)BaCl2(aq)+2H2O(l)H=118KJ Calculate the heat when 100.0 rnL...Problem 67E:
The heat capacity of a bomb calorimeter was determined by burning 6.79 g methane (energy of...Problem 68E:
The combustion of 0.1584 g benzoic acid increases the temperature of a bomb calorimeter by 2.54C....Problem 69E:
The enthalpy of combustion of solid carbon to form carbon dioxide is 393.7 KJ/mol carbon, and the...Problem 70E:
Combustion reactions involve reacting a substance with oxygen. When compounds containing carbon and...Problem 71E:
Given the following data calculate H for the reaction On the basis of the enthalpy change, is this a...Problem 73E:
Given the following data 2O3(g) 3O2(g)H = 427 kJ O2(g) 2O(g)H = 495 kJ NO(g) + O3(g) NO2(g) +...Problem 74E:
Calculate H for the reaction N2H4(l) + O2(g) N2(g) + 2H2O(l) given the following data:...Problem 75E:
Given the following data...Problem 76E:
Given the following data...Problem 77E:
Give the definition of the standard enthalpy of formation for a substance. Write separate reactions...Problem 78E:
Write reactions for which the enthalpy change will be a. Hf for solid aluminum oxide. b. the...Problem 80E:
Use the values of Hf in Appendix 4 to calculate H for the following reactions. (See Exercise 77 .)...Problem 81E:
The Ostwald process for the commercial production of nitric acid from ammonia and oxygen involves...Problem 83E:
The reusable booster rockets of the space shuttle use a mixture of aluminum and ammonium perchlorate...Problem 84E:
The space shuttle Orbiter utilizes the oxidation of methylhydrazine by dinitrogen tetroxide for...Problem 85E:
Consider the reaction 2ClF3(g)+2NH3(g)N2(g)+6HF(g)+Cl2(g)H=1196KJ Calculate H for CIF3(g).Problem 86E:
The standard enthalpy of combustion of ethene gas, C2H4(g), is 1411.1 kJ/mol at 298 K. Given the...Problem 87E:
Water gas is produced from the reaction of steam with coal: C(s)+H2O(g)H2(g)+CO(g) Assuming that...Problem 88E:
Syngas can be burned directly or converted to methanol. Calculate H for the reaction...Problem 89E:
Ethanol (C2H5OH) has been proposed as an alternative fuel. Calculate the standard enthalpy of...Problem 90E:
Methanol (CH3OH) has also been proposed as an alternative fuel. Calculate the standard enthalpy of...Problem 91E:
Some automobiles and buses have been equipped to bum propane (C3H8). Compare the amounts of energy...Problem 92E:
Acetylene (C2H2) and butane (C4H10) are gaseous fuels with enthalpies of combustion of 49.9 kJ/g and...Problem 94E:
The complete combustion of acetylene, C2H2(g), produces 1300. kJ of energy per mole of acetylene...Problem 95AE:
It has been determined that the body can generate 5500 kJ of energy during one hour of strenuous...Problem 96AE:
One way to lose weight is to exercise! Walking briskly at 4.0 miles per hour for an hour consumes...Problem 97AE:
Three gas-phase reactions were run in a constant-pressure piston apparatus as shown in the following...Problem 98AE:
Nitrogen gas reacts with hydrogen gas to form ammonia gas .Consider the reaction between nitrogen...Problem 99AE:
Combustion of table sugar produces CO2(g) and H2O( l). When 1.46 g table sugar is combusted in a...Problem 101AE:
Consider the following cyclic process carried out in two steps on a gas: Step 1: 45 J of heat is...Problem 102AE:
Calculate H for the reaction 2K(s)+2H2O(l)2KOH(aq)+H2(g) A 5.00-g chunk of potassium is dropped into...Problem 103AE:
The enthalpy of neutralization for the reaction of a strong acid with a strong base is 56 kJ/mol...Problem 105AE:
If a student performs an endothermic reaction in a calorimeter, how does the calculated value of H...Problem 106AE:
In a bomb calorimeter, the reaction vessel is surrounded by water that must be added for each...Problem 107AE:
The bomb calorimeter in Exercise 102 is filled with 987 g water. The initial temperature of the...Problem 108AE:
Consider the two space shuttle fuel reactions in Exercises 81 and 82. Which reaction produces more...Problem 109AE:
Consider the following equations: 3A+6B3DH=403KJ/molE+2FAH=105.2KJ/molCE+3DH=64.8KJ/mol Suppose the...Problem 110AE:
Given the following data...Problem 111AE:
At 298 K, the standard enthalpies of formation for C2H2(g) and C6H6(l) are 227 kJ/mol and 49 kJ/mol,...Problem 112AE:
Using the following data, calculate the standard heat of formation of ICl(g) in kJ/mol:...Problem 113AE:
A sample of nickel is heated to 99.8C and placed in a coffee-cup calorimeter containing 150.0 g...Problem 114AE:
Given: 2Cu2O(s) + O2(g) 4CuO(s)H = 288 kJ Cu2O(s) CuO(s) + CuO(s)H = 11kJ Calculate the standard...Problem 115AE:
Calculate H for each of the following reactions, which occur in the atmosphere. a. C2H4(g) + O3(g) ...Problem 116CWP:
Consider a balloon filled with helium at the following conditions. 313 g He 1.00 atm 1910. L Molar...Problem 117CWP:
In which of the following systems is(are) work done by the surroundings on the system? Assume...Problem 118CWP:
Which of the following processes are exothermic? a. N2(g)2N(g) b. H2O(l)H2O(s) c. Cl2(g)2Cl(g) d....Problem 119CWP:
Consider the reaction B2H6(g)+3O2(s)B2O3(s)+3H2O(g)H=2035KJ Calculate the amount of heat released...Problem 120CWP:
A swimming pool, 10.0 m by 4.0 m, is filled with water to a depth of 3.0 m at a temperature of...Problem 121CWP:
In a coffee-cup calorimeter, 150.0 mL of 0.50 M HCI is added to 50.0 mL of 1.00 M NaOH to make 200.0...Problem 122CWP:
Calculate H for the reaction N2H4(l)+O2(g)N2(g)+2H2O(l) given the following data: Equation H(KJ)...Problem 123CWP:
Which of the following substances have an enthalpy of formation equal to zero? a. Cl2(g) b. H2(g) c....Problem 124CP:
Consider 2.00 moles of an ideal gas that are taken from state A (PA = 2.00 atm, vA = 10.0 L) to...Problem 125CP:
For the process H2O(l)H2O(g) at 298 K and 1.0 atm, H is more positive than E by 2.5 kJ/mol. What...Problem 126CP:
The sun supplies energy at a rate of about 1.0 kilowatt per square meter of surface area (1 watt = 1...Problem 127CP:
The best solar panels currently available are about 15% efficient in converting sunlight to...Problem 128CP:
On Easter Sunday, April 3, 1983, nitric acid spilled from a tank car near downtown Denver, Colorado....Problem 129CP:
A piece of chocolate cake contains about 400 calories. A nutritional calorie is equal to 1000...Problem 130CP:
The standard enthalpies of formation for S(g), F(g), SF4(g), and SF6(g) are +278.8, +79.0, 775, and...Problem 131CP:
You have a l.00-mole sample of water at 30.C and you heat it until you have gaseous water at 140.C....Problem 132CP:
A 500.0-g sample of an element at 195C is dropped into an ice--water mixture; 109.5 g ice melts and...Problem 133IP:
The preparation of NO2(g) from N2(g) and O2(g) is an endothermic reaction: N2(g) + O2(g) NO2(g)...Problem 134IP:
Nitromethane, CH3NO2, can be used as a fuel. When the liquid is burned, the (unbalanced) reaction is...Browse All Chapters of This Textbook
Chapter 1 - Chemical FoundationsChapter 2 - Atoms, Molecules, And IonsChapter 3 - StoichiometryChapter 4 - Types Of Chemical Reactions And Solution StoichiometryChapter 5 - GasesChapter 6 - ThermochemistryChapter 7 - Atomic Structure And PeriodicityChapter 8 - Bonding: General ConceptsChapter 9 - Covalent Bonding: OrbitalsChapter 10 - Liquids And Solids
Chapter 11 - Properties Of SolutionsChapter 12 - Chemical KineticsChapter 13 - Chemical EquilibriumChapter 14 - Acids And BasesChapter 15 - Acid-base EquilibriaChapter 16 - Solubility And Complex Ion EquilibriaChapter 17 - Spontaneity, Entropy, And Free EnergyChapter 18 - ElectrochemistryChapter 19 - The Nucleus: A Chemist's ViewChapter 20 - The Representative ElementsChapter 21 - Transition Metals And Coordination ChemistryChapter 22 - Organic And Biological Molecules
Sample Solutions for this Textbook
We offer sample solutions for CHEMISTRY,AP EDITION-W/ACCESS (HS) homework problems. See examples below:
Chapter 1, Problem 1RQChapter 1, Problem 30EChapter 1, Problem 35EChapter 1, Problem 36EChapter 1, Problem 38EChapter 1, Problem 45EChapter 1, Problem 57EChapter 1, Problem 59EChapter 1, Problem 60E
Chapter 1, Problem 63EChapter 1, Problem 64EChapter 1, Problem 73EChapter 1, Problem 113CPChapter 2, Problem 1RQChapter 2, Problem 64EChapter 2, Problem 67EChapter 2, Problem 68EExplanation: Atomic number given is 13. From the periodic table we can identify that the element...Chapter 2, Problem 71EExplanation: To determine: The naming of CuI The name of CuI is copper(I) iodide. In naming of...Explanation: To determine: The naming of HC2H3O2 The naming of HC2H3O2 is acetic acid. Rules for...To determine: The formula of of sulfur difluoride The formula of sulfur difluoride is SF2 Sulfur...Explanation: To determine: The formula of sodium oxide. The formula of sodium oxide is Na2O The...Chapter 2, Problem 86EChapter 2, Problem 88EExplanation: To determine: The formula and the name of the binary compound formed from Ca and N. The...Explanation: To determine: The explanation for the term “counting by weighing”. The stated concept,...Chapter 3, Problem 59EChapter 3, Problem 60EChapter 3, Problem 61EExplanation: Given The mass of P4O6 is 1.00 g . The molar mass of P4O6 is 219.866 g/mol . Formula...Chapter 3, Problem 64EChapter 3, Problem 67EChapter 3, Problem 68EChapter 3, Problem 71EChapter 3, Problem 73EChapter 3, Problem 76EChapter 3, Problem 79EChapter 3, Problem 100EChapter 3, Problem 109EChapter 3, Problem 119EChapter 3, Problem 121EChapter 3, Problem 124EChapter 3, Problem 150AEChapter 3, Problem 152CWPChapter 3, Problem 180IPChapter 4, Problem 1RQChapter 4, Problem 7RQExplanation: NaBr(s)→Na(aq)++Braq- Figure 1 Let us consider the above molecular-level pictures of...Explanation: Record the given data Moles of Sodium phosphate= 0.200 moles Volume of the solution=...Chapter 4, Problem 66EChapter 4, Problem 79EChapter 4, Problem 82EChapter 4, Problem 93AEChapter 4, Problem 121CPChapter 4, Problem 122CPChapter 4, Problem 123CPExplanation Record the given data Mass of the sample mixture = 0.205 g Mass of the precipitate =...Explanation: Given: Record the given data Upstream at which the stream rate flows = 5.00×104 L/s...Chapter 4, Problem 144MPChapter 4, Problem 145MPA barometer consists of Mercury column that is tipped inverted and positioned in a dish containing...Chapter 5, Problem 41EExplanation: The relation between pressures measured in the manometers containing mercury and...Explanation According to ideal gas equation, PV=nRT By rearranging the above equation, PVnT=R Since...Chapter 5, Problem 88EExplanation: To find: the mole fractions of CH4 and O2 in the given mixture if the partial pressure...Explanation To find: the number of moles of dimethyl hydrazine from its given mass. The number of...Explanation To determine: The partial pressure of carbon monoxide Partial pressure of carbon...Explanation To determine: The mixing ratio of benzene Mixing ratio of benzene = 9.47 × 10-3ppmv For...Explanation: The mass percent from the given data is, 26.1% Carbon13.1% Hydrogen61.0% Nitrogen Mass...Chapter 5, Problem 135AEExplanation To find: the empirical formula of the compound Convert the mass percent to gram 58.51%...Chapter 5, Problem 139AEChapter 5, Problem 152CPChapter 5, Problem 153CPExplanation To determine: Mass of hot air when the average molar mass of air 29.0g/mol Mass of hot...Chapter 5, Problem 162IPChapter 6, Problem 1RQChapter 6, Problem 20QChapter 6, Problem 34EChapter 6, Problem 50EChapter 6, Problem 52EChapter 6, Problem 79EChapter 6, Problem 80EExplanation: The balanced equation is: a) N2(g)→N2(l) In (a) the volume of products is decreases...Chapter 6, Problem 108AEChapter 6, Problem 115AEChapter 6, Problem 130CPChapter 6, Problem 131CPChapter 6, Problem 134IPChapter 6, Problem 135IPChapter 6, Problem 137MPChapter 7, Problem 1RQChapter 7, Problem 24QChapter 7, Problem 43EChapter 7, Problem 57EChapter 7, Problem 58EChapter 7, Problem 61EChapter 7, Problem 62EChapter 7, Problem 63EChapter 7, Problem 74EChapter 7, Problem 79EChapter 7, Problem 81EChapter 7, Problem 82EChapter 7, Problem 86EChapter 7, Problem 87EChapter 7, Problem 94EChapter 7, Problem 95EChapter 7, Problem 97EChapter 7, Problem 142AEChapter 7, Problem 171CPChapter 8, Problem 1RQExplanation: Refer to figure 3-4. The electro negativity of carbon (C) , nitrogen (N) , and oxygen...Explanation: Refer to figure 3-4 The electro negativity of Sodium (Na) Potassium (K) and Rubidium...Chapter 8, Problem 46EChapter 8, Problem 47EChapter 8, Problem 49EExplanation: In a periodic table the size of ions depends on the nuclear attraction on the valence...Chapter 8, Problem 54EChapter 8, Problem 62EChapter 8, Problem 81EChapter 8, Problem 84EChapter 8, Problem 89EChapter 8, Problem 101EChapter 8, Problem 102EChapter 8, Problem 129AEChapter 8, Problem 154CPChapter 8, Problem 155CPChapter 9, Problem 1RQChapter 9, Problem 23EChapter 9, Problem 24EChapter 9, Problem 26EChapter 9, Problem 29EChapter 9, Problem 30EChapter 9, Problem 39EChapter 9, Problem 52EChapter 9, Problem 53EChapter 9, Problem 63AEChapter 9, Problem 89CPChapter 10, Problem 1RQChapter 10, Problem 41EExplanation: CCl4 , CBr4, CF4 Identify the compound which has highest boiling point and justify it....Chapter 10, Problem 53EChapter 10, Problem 55EChapter 10, Problem 56EChapter 10, Problem 57EChapter 10, Problem 58EChapter 10, Problem 59EChapter 10, Problem 60EChapter 10, Problem 62EChapter 10, Problem 80EChapter 10, Problem 88EChapter 10, Problem 131CPChapter 10, Problem 146CPChapter 10, Problem 148IPExplanation: To explain molarity Molarity can be defined as moles of solute to litres of solution....Chapter 11, Problem 16SRChapter 11, Problem 31EExplanation: Record the given data Gram equivalent of HCl = 0.25 Molarity of HCl = 0.25 M To...Explanation: KrF2 8+2(7)=22e- KrF2 is dissolves in CCl4 . KrF2 is non-polar molecule that makes it...Chapter 11, Problem 55EChapter 11, Problem 79EExplanation: Record the given data, Molality of MgCl2= 0.050 m Molality of FeCl3= 0.050 m To...Explanation: Record the given data, Molality of MgCl2= 0.050 m Molality of FeCl3= 0.050 m To...Explanation: To find the Acetone and water polarity CH3COCH3 and H2O The electrostatic possible...Explanation: Record the given data, Freezing point of an aqueous solution =- 2.79°C To calculate...Mass of Sodium = 285-315 mg Mass of Potassium = 14.1-17.3 mg Mass of Calcium = 4.9-6.0 mg Mass of...Chapter 11, Problem 109AEChapter 11, Problem 120CPChapter 11, Problem 132IPChapter 12, Problem 1RQChapter 12, Problem 30EChapter 12, Problem 33EChapter 12, Problem 35EChapter 12, Problem 36EChapter 12, Problem 58EChapter 12, Problem 84AEChapter 12, Problem 86AEChapter 12, Problem 87AEChapter 12, Problem 91AEChapter 12, Problem 93AEChapter 12, Problem 105CPChapter 12, Problem 112CPChapter 13, Problem 1RQChapter 13, Problem 5ALQChapter 13, Problem 23EChapter 13, Problem 39EChapter 13, Problem 42EChapter 13, Problem 54EChapter 13, Problem 56EChapter 13, Problem 57EChapter 13, Problem 72AEChapter 13, Problem 73AEChapter 13, Problem 78AEChapter 13, Problem 104CPChapter 13, Problem 106CPChapter 14, Problem 1RQChapter 14, Problem 49EChapter 14, Problem 50EChapter 14, Problem 51EChapter 14, Problem 52EChapter 14, Problem 63EChapter 14, Problem 64EChapter 14, Problem 68EChapter 14, Problem 73EChapter 14, Problem 74EExplanation: To determine: The pH, [H+] and [OH−] of (C2H5)3N . The equilibrium constant expression...Chapter 14, Problem 101EChapter 14, Problem 107EChapter 14, Problem 108EChapter 14, Problem 109EChapter 14, Problem 119EChapter 14, Problem 120EChapter 14, Problem 123EChapter 14, Problem 126EChapter 14, Problem 151AEChapter 15, Problem 1RQChapter 15, Problem 7RQChapter 15, Problem 43EChapter 15, Problem 57EChapter 15, Problem 58EChapter 15, Problem 59EChapter 15, Problem 60EChapter 15, Problem 61EChapter 15, Problem 62EChapter 15, Problem 63EChapter 15, Problem 64EChapter 15, Problem 65EExplanation The value of pH of solution when 0.0 mL NaOH has been added is. 1.0_ . Given: The...Chapter 15, Problem 107CWPChapter 16, Problem 1RQExplanation To determine: The solubility product of CaC2O4 . The concentration of Ca2+ is 4.8×10−5...Chapter 16, Problem 22EChapter 16, Problem 27EChapter 16, Problem 28EChapter 16, Problem 35EChapter 16, Problem 36EChapter 16, Problem 37EChapter 16, Problem 40EChapter 16, Problem 53EChapter 16, Problem 70EChapter 16, Problem 102CPChapter 17, Problem 1RQChapter 17, Problem 53EChapter 17, Problem 54EChapter 17, Problem 63EChapter 17, Problem 64EChapter 17, Problem 68EChapter 17, Problem 70EChapter 17, Problem 72EChapter 17, Problem 74EChapter 17, Problem 78EChapter 17, Problem 86AEChapter 17, Problem 90AEChapter 17, Problem 119MPChapter 18, Problem 1RQChapter 18, Problem 16RORRExplanation: Given: I- (aq) + ClO- (aq) →I3− (aq) + Cl-(aq) To write the equations for two...Explanation: Given: Cu (s) + NO3- (aq) →Cu2+ (aq) + NO(g) To write the equations for two...Chapter 18, Problem 47EChapter 18, Problem 75EChapter 18, Problem 76EChapter 18, Problem 85EChapter 18, Problem 86EChapter 18, Problem 95EChapter 18, Problem 115AEChapter 18, Problem 117AEExplanation: Given The given reaction is, Fe(s)+HCl(aq)→HFeCl4(aq)+H2(g) . In this equation, the...Chapter 18, Problem 144CPExplanation The half cell reactions are, Anode: Hg→Hg2++2e− Eanodeο=0.242 V Cathode: 2Ag++2e−→2Ag...Chapter 18, Problem 153CPChapter 18, Problem 159MPExplanation (a) To define: The term thermodynamic stability. The thermodynamic stability is related...Explanation: Alpha particle is emitted. The parent nuclide is 232Th and the nuclide after the...Explanation The most stable isotope is 81Kr and the hottest one is 73Kr The nuclides having longer...Explanation Given The atomic mass of 232Pu is 3.85285×10−22 g . The mass of a neutron is...Explanation The atomic mass of 11H=1.0078 amu The mass of a neutron is 1.0087 amu . Mass of...Explanation Given The value of half life of 87Rb is 4.5×109 years . The decay constant is calculated...Explanation The decay constant is calculated by the formula given below. λ=0.693t1/2 Where t1/2 is...Explanation: The zirconium metal is capable of reducing water to form hydrogen gas at standard...Explanation The number of α and β particles produced are 4_ and 2_ . The mass number of 92238U is...Explanation The nuclear reaction for the synthesis of cobalt- 60 is, 2658Fe+201n→ 2760Co+ −10e . The...Chapter 20, Problem 1RQExplanation The valence electron configuration for halogens is ns2np5 . The common halogen elements...Explanation The value of ΔH° for the given reaction is 180 kJ_ . The stated reaction is,...Explanation: The compound XeO4 and IO4− ion are isoelectronic. The molecule xenon tetroxide (XeO4)...Explanation: The Lewis structure, molecular structure, bond angle and hybridization of central atom...Explanation Given Dimension of room is 10.0 m×10.0 m×10.0 m . Temperature is 25 °C . Pressure is...Explanation: Hydrogen gas is produced by reacting graphite with water. C(s)+H2O(g)→CO(g)+H2(g) The...Explanation: The number of moles of hydrogen gas is 0.249 mol_. Given Mass of alkaline earth metal...Explanation: Mass of radon (Ra) is 25 g_ . Given Mass of pitch-blende is 1.75×108 g . The conversion...Explanation Given Temperature is 900 K . Pressure of In(CH3)3 is 2.00 atm . Volume of In(CH3)3 is...Chapter 20, Problem 108IPChapter 20, Problem 109IPChapter 21, Problem 1RQExplanation: (I) To determine: The geometry and associated bond angles when a metal ion has a...Explanation: Atomic number of Nickel is 28 . Accordingly the electronic configuration is –...Explanation: Atomic number of Nickel is 22 . Accordingly the electronic configuration is –...EXPLANATION (a) To write: The electron configuration of metal ion in (NH4)2[Fe(H2O)2Cl4] . The...Explanation The complex ion is [Ru(NH3)5Cl]2+. This ion contains positive charge. Oxidation state of...Explanation The complex compound is [Co(NH3)6]Cl2 . Oxidation state of Chlorine ion (Cl−) is −1 ....Explanation The complex compound is [Cr(H2O)5Br]Br2 . Oxidation state of Bromine ion (Br−) is −1 ....Explanation The value of ΔH° for the given reaction is −11 kJ_ . For the reaction,...Explanation The reaction that takes place is, 3Fe2O3(s)+CO(g)→2Fe3O4(s)+CO2(g) Refer to Appendix 4....Explanation The given equations are, Co+3+e−→Co+2 Eο=1.82 V (1) Co2++3en→Co(en)32+ K=1.5×1012 (2)...Chapter 21, Problem 99IPChapter 22, Problem 1RQChapter 22, Problem 5RQExplanation: The type of isomerism that could be exhibited by C6H12 and an example that illustrates...Chapter 22, Problem 16EChapter 22, Problem 45EExplanation To determine: The monomer of the given polymer. The monomer is vinyl fluoride. It is an...Explanation The correct name of the compound is 2,3,5,6−Tetramethyl−octane whose structure is shown...Explanation The structure of the given compound 2,3,7,8−tetrachloro−dibenzo−p−dioxin is shown in...Chapter 22, Problem 130AEChapter 22, Problem 136AEExplanation The equilibrium constant for the given reaction is 6.88×10−13_ . The equilibrium...Chapter 22, Problem 148CPExplanation The structure of C5H12 is shown in Figure 1. The structure of C5H12 is, Figure 1 The...Explanation The structure of the polymer of ABS plastic is shown in figure 1. The reaction of Abs...Explanation Given Electronic configuration of M+2 is [Ar]3d10. So, atomic number of M is 30. In...Explanation The empirical formula of the given helicene is C5H3 . Helicene is an aromatic compound...The correct responses are urea and Ammonium cyanate. The first organic compound that is synthesized...Explanation Aldohexose is a six carbon aldehyde sugar with an aldehyde group on one end.
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