Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Chapter 9.3, Problem 9E

(a)

Interpretation Introduction

Interpretation: The order of reactivity of seven different types of hydrocarbons given in the question needs to be deduced.

Concept Introduction Free radicals are uncharged molecules having an unpaired valence electron.

These are typically highly reactive and short-lived molecules.

(b)

Interpretation Introduction

Interpretation: The logic used in sequencing of part a is to be described.

Concept Introduction : Free radicals are uncharged molecules having an unpaired valence electron.

These are typically highly reactive and short-lived molecules.

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E 9   Answer with explanation please.....
When an NMR spectrum is taken of the molecule below, there is the expected 5H in the aromatic region, triplet (3H) and quartet (2H) upfield of the aromatic region. After adding a drop of acidic D2O, the spectrum changes to one that just has 5H aromatic protons and an upfield 3H singlet. What happens? Explain with mechanisms step by step and include charges and lone pairs of all compounds involved.
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