Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Chapter 9.2, Problem 24E
Interpretation Introduction

Interpretation:

The 1H NMR spectrum of the mixture of 1, x -dichlorobutanes and that of 1-chlorobutane needs to be compared.

The features are consistent with the incorporation of a second chlorine atom in this experiment needs to be explained and with the proposal that a mixture of dichlorobutanes, rather than a single isomer is formed is to be explained.

Concept introduction:

Nuclear Magnetic Resonance (NMR) spectroscopy is a logical chemistry method used in quality control.

It studies for defining the material and purity of a sample and their molecular structure.

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and An acidic liquid has a broad band at 3300 cm a sharp band at 1710 cm in the infrared spectrum. One mole of this unknown reacts with one mole of NaOH. The ¹H NMR spectrum shows three peaks in the ratio 2 : 2 : 1. Microanalysis gave C, 33.2 %; H, 4.6%; C1, 32.7%. Deduce the structure of the unknown. Spell out the full name of the compound.
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