Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Chapter 9.2, Problem 8E
Interpretation Introduction
Interpretation: The reason for the usage of less amount of sulfuryl chloride, than the theoretically required amount to convert all the starting material to mono-substituted products, needs to be given.
Concept introduction: When a single chlorine atom is involved in chlorination reaction, that reaction is called a mono-chlorination reaction.
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X
Upon ozonolysis, Compound X produces two compounds: Compound Y and
Compound Z. Compound Y can also be prepared from the following synthetic
route:
PCC
1. R₂BH, THF
1. Mg. Et₂O
PCC
Compound Y
2.
CH₂Cl₂
2. NaOH, HO
CH₂Cl₂
3. H₂O*
From this information, draw the structures of Compounds X, Y, and Z. For
Compounds X and Z, different substituents are possible. For grading purposes,
just use hydrogens as the substituents.
Br
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What three alkenes (excluding stereoisomers) can be used to prepare 3chloro-3-methylhexane by addition of HCl?
Why is benzene less reactive toward electrophiles than an alkene, even though it has more p electrons than an alkene (six versus two)?
Chapter 9 Solutions
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Ch. 9.2 - Prob. 1ECh. 9.2 - Prob. 2ECh. 9.2 - Prob. 3ECh. 9.2 - Prob. 4ECh. 9.2 - Prob. 5ECh. 9.2 - Prob. 6ECh. 9.2 - Prob. 7ECh. 9.2 - Prob. 8ECh. 9.2 - Prob. 9ECh. 9.2 - Prob. 10E
Ch. 9.2 - Prob. 11ECh. 9.2 - Prob. 12ECh. 9.2 - Prob. 13ECh. 9.2 - Prob. 14ECh. 9.2 - Prob. 15ECh. 9.2 - Prob. 16ECh. 9.2 - Prob. 17ECh. 9.2 - Prob. 18ECh. 9.2 - Prob. 19ECh. 9.2 - Prob. 20ECh. 9.2 - Prob. 21ECh. 9.2 - Prob. 22ECh. 9.2 - Prob. 23ECh. 9.2 - Prob. 24ECh. 9.3 - Prob. 1ECh. 9.3 - Prob. 2ECh. 9.3 - Prob. 3ECh. 9.3 - Prob. 4ECh. 9.3 - Prob. 5ECh. 9.3 - Prob. 6ECh. 9.3 - Prob. 7ECh. 9.3 - Prob. 8ECh. 9.3 - Prob. 9ECh. 9.3 - Prob. 10ECh. 9.3 - Prob. 11ECh. 9.3 - Prob. 12ECh. 9.3 - Prob. 13ECh. 9.3 - Prob. 14E
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