Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Chapter 9.2, Problem 14E
(a)
Interpretation Introduction
Interpretation: Using the data, the ratio of 1° to 2° dichlorobutanes obtained from monochlorination of 1-chlorobutane needs to be calculated.
Concept Introduction: A hydrogen that is bonded to the primary carbon is called a 1o hydrogen and the hydrogen that is bonded to the secondary carbon is called a 2o hydrogen.
(b)
Interpretation Introduction
Interpretation: The reason for the ratio, derived from monochlorination of 1-chlorobutane not according to the previous problem needs to be explained.
Concept Introduction: When a chemical compound reacts with other compounds, its relative activity is defined as relative reactivity.
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Photochemical chlorination of 2,2,4-trimethylpentane gives you four isomeric monochlorides
A. Write the structural formular for these four isomers
B. The two chlorides make up 65% of the monochlorides fraction. Asumming that all the primary hyrogens in 2,2,4-trimethylpentane are reactive, estimate the percentage of each of the two primary chlorides in the product mixture
a. Write the structure of the possible alkenes that are produced from the dehydration of 3-methyl-3-pentanol.
b. Which of these alkenes is predominant?
Chapter 9 Solutions
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Ch. 9.2 - Prob. 1ECh. 9.2 - Prob. 2ECh. 9.2 - Prob. 3ECh. 9.2 - Prob. 4ECh. 9.2 - Prob. 5ECh. 9.2 - Prob. 6ECh. 9.2 - Prob. 7ECh. 9.2 - Prob. 8ECh. 9.2 - Prob. 9ECh. 9.2 - Prob. 10E
Ch. 9.2 - Prob. 11ECh. 9.2 - Prob. 12ECh. 9.2 - Prob. 13ECh. 9.2 - Prob. 14ECh. 9.2 - Prob. 15ECh. 9.2 - Prob. 16ECh. 9.2 - Prob. 17ECh. 9.2 - Prob. 18ECh. 9.2 - Prob. 19ECh. 9.2 - Prob. 20ECh. 9.2 - Prob. 21ECh. 9.2 - Prob. 22ECh. 9.2 - Prob. 23ECh. 9.2 - Prob. 24ECh. 9.3 - Prob. 1ECh. 9.3 - Prob. 2ECh. 9.3 - Prob. 3ECh. 9.3 - Prob. 4ECh. 9.3 - Prob. 5ECh. 9.3 - Prob. 6ECh. 9.3 - Prob. 7ECh. 9.3 - Prob. 8ECh. 9.3 - Prob. 9ECh. 9.3 - Prob. 10ECh. 9.3 - Prob. 11ECh. 9.3 - Prob. 12ECh. 9.3 - Prob. 13ECh. 9.3 - Prob. 14E
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