Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Chapter 9.2, Problem 13E

(a)

Interpretation Introduction

Interpretation: Using a relative reactivity for 1° to 2° hydrogen atoms of 1:3.3 , the percentage of each chlorobutane expected from monochlorination of 1-chlorobutane is to be calculated.

Concept Introduction: A hydrogen that is bonded to the primary carbon is called a 1o hydrogen and the hydrogen that is bonded to the secondary carbon is called a 2o hydrogen.

(b)

Interpretation Introduction

Interpretation: Using a relative reactivity for 1° to 2° hydrogen atoms of 1:3.3 , the expected ratio of 1° to 2° dichlorobutanes is to be determined.

Concept Introduction: When a chemical compound reacts with other compounds, its relative activity is defined as relative reactivity.

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What is the experimental yield (grams and percentage) Experiment: Oxidation of -Chlorotoluene to o-Chlorobenzoic acid materials used dissolved 3.35 g of KMnO4 1.20 mL of 2-chlorotoluene was added to the mixture 3.0 mL of concentrated hydrochloric acid (pH~2) 10 mL of toluene -The crystals were isolated by vacuum filtration- Product Characterization 1.15 g of the crude product 0.93 g of the final product M.p. (final): 139-141 oC
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