Biochemistry: Concepts and Connections (2nd Edition)
2nd Edition
ISBN: 9780134641621
Author: Dean R. Appling, Spencer J. Anthony-Cahill, Christopher K. Mathews
Publisher: PEARSON
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Textbook Question
Chapter 9, Problem 3P
Provide an explanation for the fact that a- D-manose is more stable than
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Describe the chemical difference between mannose and heptyl alpha-D-mannose. Why does FimH have a higher affinity for heptyl a-D-mannose versus methyl a-D-mannose?
Draw both possible disaccharides of D-psicose and D-mannose that are joined by an α(1→4) glycosidic linkage. Are either of them now a reducing sugar?
Draw the (B1-->A1) linked dissacharide formed between the C3 epimer of B-D-glucose and the C2 epimer of a-D-galactose.
Explain in 1-2 sentences why (or why not) a precipiate would be observed when mixing this dissacharide in an alkaline solution of copper.
Chapter 9 Solutions
Biochemistry: Concepts and Connections (2nd Edition)
Ch. 9 - Prob. 1PCh. 9 - -D-Galactopyranose rotates the plane of polarized...Ch. 9 - Provide an explanation for the fact that a-...Ch. 9 - Why is a type O individual considered a universal...Ch. 9 - The disaccharide , -trehalose differs from the ,...Ch. 9 - A reducing sugar will undergo the Fehling...Ch. 9 - Prob. 7PCh. 9 - Prob. 8PCh. 9 - Indicate whether the structures shown are R and S...Ch. 9 - Prob. 10P
Ch. 9 - Draw (using Haworth projections) the fragments of...Ch. 9 - One or more of the compounds shown below will...Ch. 9 - Why do you suppose that the influenza virus...Ch. 9 - Prob. 14PCh. 9 - Are mannose and galactose epimers? Allose and...Ch. 9 - Prob. 16PCh. 9 - Explain in about one sentence why it is important...Ch. 9 - Prob. 18PCh. 9 - Prob. 19PCh. 9 - Prob. 20PCh. 9 - Prob. 21PCh. 9 - Prob. 22PCh. 9 - Prob. 23P
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- It is important to note that galactose is an important component of glyco- proteins. What is the effect on glycoprotein synthesis in case of galactosemic patients who are not given galactose in their diet? Explain this observation.arrow_forwardGive the correct name for the tripeptide Glu-Asp-Ala. Give the IUPAC name for the tripeptide R-G-Parrow_forwardWhy is B-D-Glucopyranose in a chair conformation form is the most stable form of glucose present in our body?arrow_forward
- Draw the complete structure of the tetrapeptide Val-Cys-Glu-Ser.arrow_forwardConsidering the formation of glycosidic linkages between monosaccharides, how many possible trisaccharides can be produced by combining glucose, mannose and galactose? How does this differ from the number of possibilities for a tripeptide composed of three different amino acids?arrow_forwardReduction of D-fructose with a reducing agent yields a mixture of d-sorbitol along with a second, isomeric product. What is the structure of the second product?arrow_forward
- Name which, if any, of the following are epimers of d-glucose: Dmannose, D-galactose, D-ribose.arrow_forwardWhich of an alpha-D-2,3-di-O-methylglucopyranose or alpha-D-2,3, 6-tri-O-methylglucopyranose represents a glucose unit in glycogen which was originally carrying an (alpha 1-->6) glycosidic bond?arrow_forwardDraw the pyranose form of D-Glucose as a Haworth projection. Identify your projection as either the alpha or beta anomer. Which anomer of D-Glucose is more stable? Why?arrow_forward
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