General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Question
Chapter 8, Problem 8.62P
Interpretation Introduction
(a)
Interpretation:
The representation for a NaCl solution in water after heating to
Concept Introduction:
The given NaCl-water solution is saturated, the solid NaCl is present at the bottom of the flask which stores the solution. A saturated solution is formed when no more solute can be dissolved in the given solvent at given temperature. The solubility of the solute in solvent depends on temperature. If temperature increases, the solubility also increases and if temperature is decreased, the solubility decreases.
Interpretation Introduction
(b)
Interpretation:
The representation for a NaCl solution in water after cooling to
Concept Introduction:
The given NaCl-water solution is saturated, the solid NaCl is present at the bottom of the flask which stores the solution. A saturated solution is formed when no more solute can be dissolved in the given solvent at given temperature. The solubility of the solute in solvent depends on temperature. If temperature increases, the solubility also increases and if temperature is decreased, the solubility decreases.
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Instructions: Complete the questions in the space provided. Show all your work
1. You are trying to determine the rate law expression for a reaction that you are completing at 25°C. You measure
the initial reaction rate and the starting concentrations of the reactions for 4 trials.
BrO³¯ (aq) + 5Br¯ (aq) + 6H* (aq) → 3Br₂ (l) + 3H2O (l)
Initial rate
Trial
[BrO3]
[H*]
[Br]
(mol/L)
(mol/L) | (mol/L)
(mol/L.s)
1
0.10
0.10
0.10
8.0
2
0.20
0.10
0.10
16
3
0.10
0.20
0.10
16
4
0.10
0.10
0.20
32
a.
Based on the above data what is the rate law expression?
b. Solve for the value of k (make sure to include proper units)
2. The proposed reaction mechanism is as follows:
i.
ii.
BrО¸¯ (aq) + H+ (aq) → HBrO3 (aq)
HBrO³ (aq) + H* (aq) → H₂BrO3* (aq)
iii.
H₂BrO³* (aq) + Br¯ (aq) → Br₂O₂ (aq) + H2O (l)
[Fast]
[Medium]
[Slow]
iv.
Br₂O₂ (aq) + 4H*(aq) + 4Br(aq) → 3Br₂ (l) + H2O (l)
[Fast]
Evaluate the validity of this proposed reaction. Justify your answer.
е.
Д
CH3
D*, D20
C.
NaOMe,
Br
Br
Chapter 8 Solutions
General, Organic, & Biological Chemistry
Ch. 8.1 - Classify each substance as a heterogeneous...Ch. 8.1 - Classify each product as a solution, colloid, or...Ch. 8.2 - Consider the following diagrams for an aqueous...Ch. 8.2 - Classify each solution as an electrolyte or...Ch. 8.2 - Using the given number of moles, determine how...Ch. 8.2 - Prob. 8.6PCh. 8.2 - A solution contains the following ions:...Ch. 8.2 - If a solution contains 125 mEq of Na+ per liter,...Ch. 8.3 - Which compounds are water soluble? a. NaNO3 b. CH4...Ch. 8.3 - Prob. 8.10P
Ch. 8.3 - Use the solubility rules to predict whether the...Ch. 8.3 - Use the solubility rules for ionic compounds to...Ch. 8.4 - Why does a soft drink become "flat" faster when it...Ch. 8.4 - Predict the effect each change has on the...Ch. 8.5 - A commercial mouthwash contains 4.3 g of ethanol...Ch. 8.5 - What is the weight/volume percent concentration of...Ch. 8.5 - Prob. 8.17PCh. 8.5 - Prob. 8.18PCh. 8.5 - Prob. 8.19PCh. 8.5 - Prob. 8.20PCh. 8.5 - What is the concentration in parts per million of...Ch. 8.6 - Prob. 8.22PCh. 8.6 - Prob. 8.23PCh. 8.6 - Prob. 8.24PCh. 8.6 - Prob. 8.25PCh. 8.6 - How many grams of NaCl are contained in each of...Ch. 8.6 - How many milliliters of a 0.25 M sucrose solution...Ch. 8.7 - What is the concentration of a solution formed by...Ch. 8.7 - Prob. 8.29PCh. 8.7 - Prob. 8.30PCh. 8.8 - Prob. 8.31PCh. 8.8 - Prob. 8.32PCh. 8.8 - Prob. 8.33PCh. 8.9 - Prob. 8.34PCh. 8.9 - Prob. 8.35PCh. 8.9 - Prob. 8.36PCh. 8 - Prob. 8.37PCh. 8 - Prob. 8.38PCh. 8 - Prob. 8.39PCh. 8 - Prob. 8.40PCh. 8 - Classify each of the following as a solution,...Ch. 8 - Classify each of the following as a solution,...Ch. 8 - Prob. 8.43PCh. 8 - Label each diagram as a strong electrolyte, weak...Ch. 8 - Prob. 8.45PCh. 8 - Prob. 8.46PCh. 8 - Prob. 8.47PCh. 8 - Prob. 8.48PCh. 8 - Consider a mixture of two substances shown in blue...Ch. 8 - Which diagram (C or D) best represents what occurs...Ch. 8 - If the solubilityofKClin 100 mL of H2O is 34 g at...Ch. 8 - If the solubilityofsucrosein 100 mL of H2O is 204...Ch. 8 - Prob. 8.53PCh. 8 - Prob. 8.54PCh. 8 - Using the ball-and-stick model for methanol...Ch. 8 - Prob. 8.56PCh. 8 - Prob. 8.57PCh. 8 - Prob. 8.58PCh. 8 - Prob. 8.59PCh. 8 - Prob. 8.60PCh. 8 - Prob. 8.61PCh. 8 - Prob. 8.62PCh. 8 - Prob. 8.63PCh. 8 - How is the solubility of helium gas in water...Ch. 8 - Use the solubility rules listed in Section 8.3B to...Ch. 8 - Use the solubility rules listed in Section 8.3B to...Ch. 8 - Prob. 8.67PCh. 8 - Prob. 8.68PCh. 8 - Prob. 8.69PCh. 8 - Prob. 8.70PCh. 8 - Prob. 8.71PCh. 8 - Prob. 8.72PCh. 8 - Prob. 8.73PCh. 8 - Prob. 8.74PCh. 8 - How would you use a 250-mL volumetric flask to...Ch. 8 - How would you use a 250-mLvolumetric flask to...Ch. 8 - Prob. 8.77PCh. 8 - Prob. 8.78PCh. 8 - Prob. 8.79PCh. 8 - Prob. 8.80PCh. 8 - Prob. 8.81PCh. 8 - What is the molarity of a 20.0% (v/v) aqueous...Ch. 8 - Prob. 8.83PCh. 8 - Prob. 8.84PCh. 8 - Prob. 8.85PCh. 8 - Prob. 8.86PCh. 8 - Prob. 8.87PCh. 8 - Prob. 8.88PCh. 8 - Prob. 8.89PCh. 8 - Prob. 8.90PCh. 8 - Prob. 8.91PCh. 8 - Prob. 8.92PCh. 8 - What is the boiling point of a solution that...Ch. 8 - Prob. 8.94PCh. 8 - If 150 g of ethylene glycol (C2H6O2) is added to...Ch. 8 - Prob. 8.96PCh. 8 - Prob. 8.97PCh. 8 - Prob. 8.98PCh. 8 - Which solution in each pair has the higher melting...Ch. 8 - Prob. 8.100PCh. 8 - A flask contains two compartments (A and B) with...Ch. 8 - A flask contains two compartments (A and B) with...Ch. 8 - Prob. 8.103PCh. 8 - Explain why more sugar dissolves in a cup of hot...Ch. 8 - If the concentration of glucose in the blood is...Ch. 8 - Prob. 8.106PCh. 8 - Mannitol, a carbohydrate, is supplied as a 25%...Ch. 8 - A patient receives 750 ml, of a 10.% (w/v) aqueous...Ch. 8 - Explain why a cucumber placed in a concentrated...Ch. 8 - Explain why a cucumber placed in a concentrated...Ch. 8 - Prob. 8.111PCh. 8 - Prob. 8.112PCh. 8 - Prob. 8.113PCh. 8 - Prob. 8.114PCh. 8 - Prob. 8.115PCh. 8 - Prob. 8.116PCh. 8 - The therapeutic concentration—the concentration...Ch. 8 - Prob. 8.118CP
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