Carbon monoxide is produced by incomplete combustion of fossil fuels. (a) Give the electron configuration for the valence molecular orbitals of CO. The orbitals have the same energy order as those of the N 2 molecule. (b) Do you expect CO to be paramagnetic or diamagnetic? (c) What is the bond order of CO? Does this match the bond order predicted by the electron-dot structure? (d) CO can react with OH − to form the formate ion, HCO 2 − Draw an electron-dot structure for the formate ion, and give any resonance structures if appropriate.
Carbon monoxide is produced by incomplete combustion of fossil fuels. (a) Give the electron configuration for the valence molecular orbitals of CO. The orbitals have the same energy order as those of the N 2 molecule. (b) Do you expect CO to be paramagnetic or diamagnetic? (c) What is the bond order of CO? Does this match the bond order predicted by the electron-dot structure? (d) CO can react with OH − to form the formate ion, HCO 2 − Draw an electron-dot structure for the formate ion, and give any resonance structures if appropriate.
Solution Summary: The author explains that the electronic configuration for the valence molecular orbitals of CO needs to be determined.
Carbon monoxide is produced by incomplete combustion of fossil fuels. (a) Give the electron configuration for the valence molecular orbitals of CO. The orbitals have the same energy order as those of the
N
2
molecule. (b) Do you expect CO to be paramagnetic or diamagnetic? (c) What is the bond order of CO? Does this match the bond order predicted by the electron-dot structure? (d) CO can react with
OH
−
to form the formate ion,
HCO
2
−
Draw an electron-dot structure for the formate ion, and give any resonance structures if appropriate.
Q6: Predict the effect of the changes given on the rate of the reaction below.
CH3OH
CH3Cl + NaOCH3
→ CH3OCH3 + NaCl
a) Change the substrate from CH3CI to CH31:
b) Change the nucleophile from NaOCH 3 to NaSCH3:
c) Change the substrate from CH3CI to (CH3)2CHCI:
d) Change the solvent from CH3OH to DMSO.
Q3: Arrange each group of compounds from fastest SN2 reaction rate to slowest SN2
reaction rate.
a)
CI
Cl
فيكم
H3C-Cl
A
B
C
D
Br
Br
b)
A
B
C
Br
H3C-Br
D
Q2: Group these solvents into either protic solvents or aprotic solvents.
Acetonitrile (CH3CN), H₂O, Acetic acid (CH3COOH), Acetone (CH3COCH3),
CH3CH2OH, DMSO (CH3SOCH3), DMF (HCON(CH3)2), CH3OH
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