FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
16th Edition
ISBN: 9781323406038
Author: McMurry
Publisher: PEARSON C
expand_more
expand_more
format_list_bulleted
Videos
Textbook Question
Chapter 7, Problem 7.55AP
Use your answer from Problem 7.53 to calculate the following:
- (a) [N2O4] at equilibrium when [NO2] = 0.0250 mol/L
- (b) [NO2] at equilibrium when [N2O4] = 0.0750 mol/L
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solution
Students have asked these similar questions
Derive the Henderson – Hasselbach Equation.
[H*][A¯]
Ка— [НА]
Molecular Weight:
H = 1 g/mol
C= 12 g/mol N=14 g/mol O = 16 g/mol Cl= 35.45 g/mol
The following reaction plays a key role in the destruction of ozone in the atmosphere:
Cl(g)+ O3 (g)-> ClO(g)+O2 (g)
Given the standard molar entropies (S°) below, calculate the ΔS for this reaction.
S°C1O = 218.9 J/mol*K
S°O3 = 238.8 J/mol*K
S°Cl = 165.2 J/mol*K
S°O2= 205.0 J/mol*K
_______ J/K = ΔS
Given the equation below, determine which statement is incorrect.
4C(s) + 6H2(g) + O2(g) → 2C2H5OH(1) AH°=555.4 kJ
A) If the equation above is multiplied by two, AH° = - 1110.8 kJ
B) For every 0.5 mol of O2, AH° = -277.7 kJ
If the state of ethanol changes from the liquid state to the gas state, the
value for AH° no loner applies.
D) The value of 571.1 kJ applies to one mole of liquid ethanol.
E) If the equation above is reversed, AH° = + 555.4 kJ
Chapter 7 Solutions
FUND.OF GEN CHEM CHAP 1-13 W/ACCESS
Ch. 7.1 - Classify each of the following as having potential...Ch. 7.2 - Based on bond energies, which atmospheric gas in...Ch. 7.3 - Prob. 7.1CIAPCh. 7.3 - How many Calories (i.e., kilocalories) are in a...Ch. 7.3 - Prob. 7.3PCh. 7.3 - Prob. 7.4PCh. 7.3 - Prob. 7.5PCh. 7.3 - Prob. 7.6PCh. 7.4 - Prob. 7.7PCh. 7.4 - Prob. 7.8KCP
Ch. 7.5 - The reaction between iron and oxygen to form rust...Ch. 7.6 - Prob. 7.10PCh. 7.8 - Prob. 7.11PCh. 7.8 - Prob. 7.12PCh. 7.8 - Prob. 7.13PCh. 7.8 - The following diagrams represent two similar...Ch. 7.9 - Prob. 7.3CIAPCh. 7.9 - Prob. 7.4CIAPCh. 7.9 - Is the yield of SO3 at equilibrium favored by a...Ch. 7.9 - Prob. 7.16PCh. 7.9 - Prob. 7.17PCh. 7 - What are the signs of H, S, and G for the...Ch. 7 - Prob. 7.19UKCCh. 7 - Prob. 7.20UKCCh. 7 - Two curves are shown in the following energy...Ch. 7 - Prob. 7.22UKCCh. 7 - Prob. 7.23APCh. 7 - Prob. 7.24APCh. 7 - Prob. 7.25APCh. 7 - Prob. 7.26APCh. 7 - Acetylene (H C C H) is the fuel used in welding...Ch. 7 - Prob. 7.28APCh. 7 - Prob. 7.29APCh. 7 - Prob. 7.30APCh. 7 - Prob. 7.31APCh. 7 - Prob. 7.32APCh. 7 - Prob. 7.33APCh. 7 - Prob. 7.34APCh. 7 - Why are most spontaneous reactions exothermic?Ch. 7 - Prob. 7.36APCh. 7 - Prob. 7.37APCh. 7 - Prob. 7.38APCh. 7 - Prob. 7.39APCh. 7 - Prob. 7.40APCh. 7 - Prob. 7.41APCh. 7 - Prob. 7.42APCh. 7 - Prob. 7.43APCh. 7 - Prob. 7.44APCh. 7 - Prob. 7.45APCh. 7 - Prob. 7.46APCh. 7 - Prob. 7.47APCh. 7 - Prob. 7.48APCh. 7 - What is meant by the term chemical equilibrium?...Ch. 7 - Prob. 7.50APCh. 7 - Prob. 7.51APCh. 7 - Prob. 7.52APCh. 7 - Prob. 7.53APCh. 7 - Prob. 7.54APCh. 7 - Use your answer from Problem 7.53 to calculate the...Ch. 7 - Use your answer from Problem 7.54 to calculate the...Ch. 7 - Prob. 7.57APCh. 7 - Prob. 7.58APCh. 7 - Prob. 7.59APCh. 7 - Prob. 7.60APCh. 7 - Prob. 7.61APCh. 7 - Prob. 7.62APCh. 7 - Prob. 7.63APCh. 7 - Prob. 7.64APCh. 7 - Prob. 7.65APCh. 7 - Prob. 7.66APCh. 7 - For the unbalanced combustion reaction shown, 1...Ch. 7 - Prob. 7.68CPCh. 7 - Prob. 7.69CPCh. 7 - Prob. 7.70CPCh. 7 - Urea is a metabolic waste product that decomposes...Ch. 7 - Prob. 7.72CPCh. 7 - Prob. 7.73CPCh. 7 - Methanol, CH3OH, is used as race car fuel. (a)...Ch. 7 - Prob. 7.75CPCh. 7 - Prob. 7.76CPCh. 7 - Prob. 7.77CPCh. 7 - Prob. 7.78GPCh. 7 - Prob. 7.79GPCh. 7 - Prob. 7.80GP
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, biochemistry and related others by exploring similar questions and additional content below.Similar questions
- Balance the following (fictional) chemical equations by supplying the correct coefficient. Do not leave any space blank (in other words, write in 1 if you would be leaving it blank): R(OZ)2 - RY2+ Z20 a) ZY+ b) D2 (g) + L2 (g) – DL3 (e)arrow_forwardThe reaction CO2(g) + H2O(l) ⇔ H+(aq) + HCO3-(aq) has ΔH° = -12.65 kJ mol-1 and ΔS° = -192.5 J mol-1 K-1. Calculate the equilibrium constant when the temperature is 4.00 °C. (R = 8.3145 J mol-1 K-1) Multiply your answer by 109 before entering it. (Hint: remember that when calculating ΔG°, all values must be for standard state.)arrow_forwardStarting with the following equation, Ca (PO)2(s) + H2SOд(aq) → CaSO(s) + HРО(aq) - calculate the mass in grams of Ca (PO), that will be required to produce 875 grams of CaSO.arrow_forward
- The value of delta g for the conversion of 3-phosphoglycerate to 2-phosphoglycerate (2PG) is +4.40 kJ/mol. If the concentration of 3-phosphoglycerate at equilibrium is 2.05 mM, what is the concentration of 2 phosphoglycerate? Assume the temperature of 250 celsiusarrow_forwardBenzene, C6H6, is an aromatic hydrocarbon that exists as a liquid at 298 K and 1 bar. The solubility of benzene in water, defined as the concentration of the saturated solution, is 2.23×10¬3 M at 298 K and 1 bar, and its standard Gibbs free energy of formation is AfG° (C6H6, ) = 124.3 kJ/mol. a. Calculate the standard Gibbs free energy change for the process of dissolution of benzene in water a. Find the chemical potential of the benzene solute standard state AFG° (C6H6, aq).arrow_forwardConsider the following equilibrium at 298 K. R = 8.314 J/K-mol Citrate Isocitrate Using the equilibrium concentrations of [Citrate] = 2.15 M and [Isocitrate] = 0.00825 M, calculate K'g, then AG°. Which one of the following is the correct value for AG in units of kJ/mol? 5990 kJ/mol -2480 kJ/mol 2.48 kJ/mol 13.8 kJ/mol 5.99 kJ/mol -2.48 kJ/mol -5990 kJ/mol -9.99 kJ/mol -13800 kJ/mol 13800 kJ/mol -5.99 kJ/mol 9.99 kJ/mol 2480 kJ/mol 9990 kJ/mol -13.8 kJ/mol -9990 kJ/mol O O O O O O O O O O0000 O Oarrow_forward
- 6 x 10⁻⁵¹ = (0.15 M)² [S²⁻] [S²⁻] = (6 x 10⁻⁵¹) / (0.15 M)² Calculating, we find the minimum concentration of sulfide ion required: [S²⁻] ≈ 2.7 x 10⁻⁴⁹ M. check it calcution is writearrow_forwardThe ΔG°′ value for glucose-1-phosphate is -20.9 kJ/mol. If glucose and phosphate are both at 4.8 mM, what is the equilibrium concentration of glucose-1-phosphate?arrow_forwardAG°xn=-28.6 kJ Given the following equation, H2O(g) + CO(g) → H2(g) + CO2(g) Calculate AG°n for the following reaction. -> 8 H2O(g) + 8 CO(g) 8H2(g) + 8 CO2(g) a -71.5 kJ b -3.57 kJ C +3.57 kJ d +228.8 kJ e -228.8 kJ O O O O Oarrow_forward
- What is the free Cu2+ (ag) concentration in a solution made up by mixing 50.0 mL of 0.100M Cu(NO3)2 with 50.0 mL 1.00 M NH3 (aq)? Given: Cu2+ (ag) + 4 NH3 (aq) > < Cu(NH3)42+ (aq) K, = 1.1 x 10^13arrow_forwardA monoprotic weak acid, HA, dissociates in water according to the reaction HA(aq) = H+ (aq) + A¯(aq) The equilibrium concentrations of the reactants and products are [HA] = 0.220 M, [H+] = 3.00 × 10−4 M, and [A¯] = 3.00 × 10−4 M. Calculate the value of pKa for the acid HA. pKa =arrow_forwardThe value of AG®' for the conversion of 3-phosphoglycerate to 2-phosphoglycerate (2PG) is +4.40 kJ/mol. If the concentration of 3-phosphoglycerate at equilibrium is 1.95 mM, what is the concentration of 2-phosphoglycerate? Assume a temperature of 25.0 °C. [2PG] = mMarrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
BiochemistryBiochemistryISBN:9781319114671Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.Publisher:W. H. Freeman
Lehninger Principles of BiochemistryBiochemistryISBN:9781464126116Author:David L. Nelson, Michael M. CoxPublisher:W. H. Freeman
Fundamentals of Biochemistry: Life at the Molecul...BiochemistryISBN:9781118918401Author:Donald Voet, Judith G. Voet, Charlotte W. PrattPublisher:WILEY
BiochemistryBiochemistryISBN:9781305961135Author:Mary K. Campbell, Shawn O. Farrell, Owen M. McDougalPublisher:Cengage Learning
BiochemistryBiochemistryISBN:9781305577206Author:Reginald H. Garrett, Charles M. GrishamPublisher:Cengage Learning
Fundamentals of General, Organic, and Biological ...BiochemistryISBN:9780134015187Author:John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. PetersonPublisher:PEARSON
Biochemistry
Biochemistry
ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:W. H. Freeman
Lehninger Principles of Biochemistry
Biochemistry
ISBN:9781464126116
Author:David L. Nelson, Michael M. Cox
Publisher:W. H. Freeman
Fundamentals of Biochemistry: Life at the Molecul...
Biochemistry
ISBN:9781118918401
Author:Donald Voet, Judith G. Voet, Charlotte W. Pratt
Publisher:WILEY
Biochemistry
Biochemistry
ISBN:9781305961135
Author:Mary K. Campbell, Shawn O. Farrell, Owen M. McDougal
Publisher:Cengage Learning
Biochemistry
Biochemistry
ISBN:9781305577206
Author:Reginald H. Garrett, Charles M. Grisham
Publisher:Cengage Learning
Fundamentals of General, Organic, and Biological ...
Biochemistry
ISBN:9780134015187
Author:John E. McMurry, David S. Ballantine, Carl A. Hoeger, Virginia E. Peterson
Publisher:PEARSON
GCSE Chemistry - Acids and Bases #34; Author: Cognito;https://www.youtube.com/watch?v=vt8fB3MFzLk;License: Standard youtube license