Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
2nd Edition
ISBN: 9780393655551
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter 7, Problem 7.3YT
Interpretation Introduction
Interpretation:
The complete Lewis structure for the negatively charged nucleophiles listed in the paragraph and the uncharged nucleophiles is to be drawn.
Concept introduction:
The term nucleophile means nucleus loving. The nucleus of an atom carries a positive charge. The nucleophile tends to be attracted by and forms a bond to a nonhydrogen atom that bears the partial or full positive charge. The nucleophile has an atom that bears a full negative charge. The nucleophile has one or two lone pairs of electrons that bear a partial negative charge.
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Make a list of electrophiles and nucleophiles that we have used this semester IN CLASS. I won't count it if we didn't use it. This
is not something that you find using an online search. This is information you have in your notes. Use the general form rather than
specific molecules (for example: you would put down H* as one entry, which is HCI, HBr, H₂SO4, H₂O, ROH, NH3, RCO₂H or
any other source of H¹). The halogens (F, Cl, Br, I-) are one type of nucleophile. So they are only counted once. You should be
able to do at least 10 in each column, in addition to the H and X- that I've already done for you! That means 10 more in each
column. I will only look at the first 10 that you give me as I look down your list. Enjoy!
Electrophiles
0. H+ (i.e. HCI, HBr, H2SO4, H2O, ROH, etc.)
1.
2.
3.
7.
9.
10.
Nucleophiles
0. X (i.e. F, CI", Br", 1)
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
Please draw it for me
Draw structural formulas for the major organic product(s) of the reaction shown below.
OCH3
AICI3
+ (CH3)2CHCI
You do not have to consider stereochemistry.
• If no reaction occurs, draw the organic starting material.
• Remember to include all of the formal charges on the atoms of any nitro groups.
• Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner.
• Separate multiple products using the + sign from the drop-down menu.
opy
aste
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Chapter 7 Solutions
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
Ch. 7 - Prob. 7.1PCh. 7 - Prob. 7.2PCh. 7 - Prob. 7.3PCh. 7 - Prob. 7.4PCh. 7 - Prob. 7.5PCh. 7 - Prob. 7.6PCh. 7 - Prob. 7.7PCh. 7 - Prob. 7.8PCh. 7 - Prob. 7.9PCh. 7 - Prob. 7.10P
Ch. 7 - Prob. 7.11PCh. 7 - Prob. 7.12PCh. 7 - Prob. 7.13PCh. 7 - Prob. 7.14PCh. 7 - Prob. 7.15PCh. 7 - Prob. 7.16PCh. 7 - Prob. 7.17PCh. 7 - Prob. 7.18PCh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20PCh. 7 - Prob. 7.21PCh. 7 - Prob. 7.22PCh. 7 - Prob. 7.23PCh. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - Prob. 7.26PCh. 7 - Prob. 7.27PCh. 7 - Prob. 7.28PCh. 7 - Prob. 7.29PCh. 7 - Prob. 7.30PCh. 7 - Prob. 7.31PCh. 7 - Prob. 7.32PCh. 7 - Prob. 7.33PCh. 7 - Prob. 7.34PCh. 7 - Prob. 7.35PCh. 7 - Prob. 7.36PCh. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - Prob. 7.39PCh. 7 - Prob. 7.40PCh. 7 - Prob. 7.41PCh. 7 - Prob. 7.42PCh. 7 - Prob. 7.43PCh. 7 - Prob. 7.44PCh. 7 - Prob. 7.45PCh. 7 - Prob. 7.46PCh. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - Prob. 7.49PCh. 7 - Prob. 7.50PCh. 7 - Prob. 7.51PCh. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - Prob. 7.57PCh. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.1YTCh. 7 - Prob. 7.2YTCh. 7 - Prob. 7.3YTCh. 7 - Prob. 7.4YTCh. 7 - Prob. 7.5YTCh. 7 - Prob. 7.6YTCh. 7 - Prob. 7.7YTCh. 7 - Prob. 7.8YTCh. 7 - Prob. 7.9YTCh. 7 - Prob. 7.10YTCh. 7 - Prob. 7.11YTCh. 7 - Prob. 7.12YTCh. 7 - Prob. 7.13YTCh. 7 - Prob. 7.14YTCh. 7 - Prob. 7.15YT
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