It is to be explained why most ketones and aldehydes exist primarily in their keto forms but Propanedial exists primarily (>99%) in its enol form. Concept introduction: As a ketone or aldehyde, the species is called the keto form. In the enol form, the species has a carbon atom that is simultaneously a part of a C = C bond, characteristic of an alkene , and is bonded to OH, characteristic of an alcohol. In the keto form, there is a hydrogen atom on the carbon atom that is adjacent to the C = O group, so called alpha carbon, whereas in the enol form, the hydrogen appears on the oxygen atom instead. In a keto-enol tautomerization, the keto form is in equilibrium with its enol form via proton transfer steps. In general, keto form is more stable than enol because the total bond energy for the keto form is roughly greater than that of the enol form.

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Answer 1

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 7, Problem 7.43P

Interpretation Introduction

Interpretation:

It is to be explained why most ketones and aldehydes exist primarily in their keto forms but Propanedial exists primarily (>99%) in its enol form.

Concept introduction:

As a ketone or aldehyde, the species is called the keto form. In the enol form, the species has a carbon atom that is simultaneously a part of a C = C bond, characteristic of an alkene, and is bonded to OH, characteristic of an alcohol. In the keto form, there is a hydrogen atom on the carbon atom that is adjacent to the C = O group, so called alpha carbon, whereas in the enol form, the hydrogen appears on the oxygen atom instead. In a keto-enol tautomerization, the keto form is in equilibrium with its enol form via proton transfer steps. In general, keto form is more stable than enol because the total bond energy for the keto form is roughly greater than that of the enol form.

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Answer 2

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 7, Problem 7.43P

Interpretation Introduction

Interpretation:

It is to be explained why most ketones and aldehydes exist primarily in their keto forms but Propanedial exists primarily (>99%) in its enol form.

Concept introduction:

As a ketone or aldehyde, the species is called the keto form. In the enol form, the species has a carbon atom that is simultaneously a part of a C = C bond, characteristic of an alkene, and is bonded to OH, characteristic of an alcohol. In the keto form, there is a hydrogen atom on the carbon atom that is adjacent to the C = O group, so called alpha carbon, whereas in the enol form, the hydrogen appears on the oxygen atom instead. In a keto-enol tautomerization, the keto form is in equilibrium with its enol form via proton transfer steps. In general, keto form is more stable than enol because the total bond energy for the keto form is roughly greater than that of the enol form.

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Answer 3

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Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 7, Problem 7.43P

Interpretation Introduction

Interpretation:

It is to be explained why most ketones and aldehydes exist primarily in their keto forms but Propanedial exists primarily (>99%) in its enol form.

Concept introduction:

As a ketone or aldehyde, the species is called the keto form. In the enol form, the species has a carbon atom that is simultaneously a part of a C = C bond, characteristic of an alkene, and is bonded to OH, characteristic of an alcohol. In the keto form, there is a hydrogen atom on the carbon atom that is adjacent to the C = O group, so called alpha carbon, whereas in the enol form, the hydrogen appears on the oxygen atom instead. In a keto-enol tautomerization, the keto form is in equilibrium with its enol form via proton transfer steps. In general, keto form is more stable than enol because the total bond energy for the keto form is roughly greater than that of the enol form.

Expert Solution & Answer

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Check out a sample textbook solution

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Answer 4

Question

Definition Definition Organic compounds that have a carbonyl group, C=O, as their functional group. The carbonyl group in aldehydes is placed at the end of the molecular structure, which means the C=O is attached to one hydrogen atom and an alkyl group or a benzene ring. Just like all the other homologous series in organic chemistry, the naming of aldehydes uses the suffix “-al”. The general molecular formula is C n H 2n O.

Chapter 7, Problem 7.43P

Interpretation Introduction