Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)
2nd Edition
ISBN: 9780393655551
Author: KARTY, Joel
Publisher: W. W. Norton & Company
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Chapter 7, Problem 7.33P
Interpretation Introduction

Interpretation:

Curved arrows are to be drawn, and the product of each electrophilic addition step is to be shown where the nitro (NO2+) group adds to phenol to yield three nitro substituted phenols.

Concept introduction:

The curved arrow notation keeps track of electrons in an elementary step. Curved arrows are drawn from the electron rich to electron poor sites. An electrophilic addition step occurs when a species containing a non-polar pi bond (as part of a double or triple bond) approaches a strongly electron-deficient species (an electrophile). A new bond is formed between atoms of the pi bond and the electrophile. The product of each of the electrophilic addition is a carbocation, which is highly unstable and will react further because it has a positive charge and lacks an octet.

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Chapter 7 Solutions

Organic Chemistry: Principles And Mechanisms: Study Guide/solutions Manual (second)

Ch. 7 - Prob. 7.1PCh. 7 - Prob. 7.2PCh. 7 - Prob. 7.3PCh. 7 - Prob. 7.4PCh. 7 - Prob. 7.5PCh. 7 - Prob. 7.6PCh. 7 - Prob. 7.7PCh. 7 - Prob. 7.8PCh. 7 - Prob. 7.9PCh. 7 - Prob. 7.10P
Ch. 7 - Prob. 7.11PCh. 7 - Prob. 7.12PCh. 7 - Prob. 7.13PCh. 7 - Prob. 7.14PCh. 7 - Prob. 7.15PCh. 7 - Prob. 7.16PCh. 7 - Prob. 7.17PCh. 7 - Prob. 7.18PCh. 7 - Prob. 7.19PCh. 7 - Prob. 7.20PCh. 7 - Prob. 7.21PCh. 7 - Prob. 7.22PCh. 7 - Prob. 7.23PCh. 7 - Prob. 7.24PCh. 7 - Prob. 7.25PCh. 7 - Prob. 7.26PCh. 7 - Prob. 7.27PCh. 7 - Prob. 7.28PCh. 7 - Prob. 7.29PCh. 7 - Prob. 7.30PCh. 7 - Prob. 7.31PCh. 7 - Prob. 7.32PCh. 7 - Prob. 7.33PCh. 7 - Prob. 7.34PCh. 7 - Prob. 7.35PCh. 7 - Prob. 7.36PCh. 7 - Prob. 7.37PCh. 7 - Prob. 7.38PCh. 7 - Prob. 7.39PCh. 7 - Prob. 7.40PCh. 7 - Prob. 7.41PCh. 7 - Prob. 7.42PCh. 7 - Prob. 7.43PCh. 7 - Prob. 7.44PCh. 7 - Prob. 7.45PCh. 7 - Prob. 7.46PCh. 7 - Prob. 7.47PCh. 7 - Prob. 7.48PCh. 7 - Prob. 7.49PCh. 7 - Prob. 7.50PCh. 7 - Prob. 7.51PCh. 7 - Prob. 7.52PCh. 7 - Prob. 7.53PCh. 7 - Prob. 7.54PCh. 7 - Prob. 7.55PCh. 7 - Prob. 7.56PCh. 7 - Prob. 7.57PCh. 7 - Prob. 7.58PCh. 7 - Prob. 7.59PCh. 7 - Prob. 7.60PCh. 7 - Prob. 7.1YTCh. 7 - Prob. 7.2YTCh. 7 - Prob. 7.3YTCh. 7 - Prob. 7.4YTCh. 7 - Prob. 7.5YTCh. 7 - Prob. 7.6YTCh. 7 - Prob. 7.7YTCh. 7 - Prob. 7.8YTCh. 7 - Prob. 7.9YTCh. 7 - Prob. 7.10YTCh. 7 - Prob. 7.11YTCh. 7 - Prob. 7.12YTCh. 7 - Prob. 7.13YTCh. 7 - Prob. 7.14YTCh. 7 - Prob. 7.15YT
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