Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Textbook Question
Chapter 6.1, Problem 1P
Draw the mechanism for the reaction of cyclohexene with HCl.
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Ethyl butyrate, CH3CH2CH2CO2CH2CH3, is an artificial fruit flavor commonly used in the food industry for such flavors as orange and pineapple. Its fragrance and taste are often associated with fresh orange juice, and thus it is most commonly used as orange flavoring.It can be produced by the reaction of butanoic acid with ethanol in the presence of an acid catalyst (H+): CH3CH2CH2CO2H(l)+CH2CH3OH(l)H+⟶CH3CH2CH2CO2CH2CH3(l)+H2O(l). The chemist discovers a more efficient catalyst that can produce ethyl butyrate with a 78.0% yield. How many grams would be produced from 8.50 gof butanoic acid and excess ethanol? Express your answer in grams to three significant figures.
Chapter 6 Solutions
Organic Chemistry
Ch. 6.1 - Draw the mechanism for the reaction of cyclohexene...Ch. 6.2 - a. How many bond orbitals are avilable for...Ch. 6.2 - Prob. 3PCh. 6.2 - Prob. 4PCh. 6.3 - Prob. 5PCh. 6.4 - Prob. 6PCh. 6.4 - What alkene should be used to synthesize each of...Ch. 6.4 - Prob. 8PCh. 6.5 - The pKa of a protonated alcohol is about 2.5, and...Ch. 6.5 - Prob. 10P
Ch. 6.5 - Prob. 11PCh. 6.6 - a. What is the major product or each or the...Ch. 6.6 - Prob. 14PCh. 6.6 - Prob. 15PCh. 6.7 - What is the major product obtained from the...Ch. 6.8 - Which is more highly regionselective: reaction of...Ch. 6.8 - Prob. 19PCh. 6.9 - What will be the product of the preceding reaction...Ch. 6.9 - Prob. 21PCh. 6.9 - Prob. 22PCh. 6.9 - Prob. 23PCh. 6.9 - What is the product of the addition of 1Cl to...Ch. 6.9 - What will be the major product obtained from the...Ch. 6.9 - Propose a mechanism for the following reaction:Ch. 6.10 - Draw structures for the following: a. 24...Ch. 6.10 - What alkene would you treat with a peroxyacid in...Ch. 6.11 - What products are formed when the following...Ch. 6.11 - Prob. 30PCh. 6.11 - Prob. 31PCh. 6.12 - Prob. 34PCh. 6.12 - Prob. 35PCh. 6.13 - Prob. 36PCh. 6.13 - Prob. 37PCh. 6.13 - Prob. 38PCh. 6.14 - What characteristics must the reactant of a...Ch. 6.15 - Prob. 40PCh. 6.15 - What stereoisomers are obtained from each of the...Ch. 6.15 - Prob. 45PCh. 6.15 - Prob. 46PCh. 6.15 - Prob. 47PCh. 6.15 - Prob. 49PCh. 6.15 - Prob. 50PCh. 6.15 - Prob. 51PCh. 6.15 - Prob. 52PCh. 6.15 - Prob. 53PCh. 6.16 - Prob. 54PCh. 6.17 - Prob. 55PCh. 6.18 - Explain why 3-methykyclohexene should not be used...Ch. 6.18 - Prob. 58PCh. 6 - Prob. 59PCh. 6 - Prob. 60PCh. 6 - What is the major product of the reaction of...Ch. 6 - Give two names for each of the following:Ch. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Prob. 65PCh. 6 - What are the products of the following reactions?...Ch. 6 - When 3-methyl-1-butene reacts with HBr, two alkyl...Ch. 6 - Prob. 68PCh. 6 - Draw curved arrows to show the flow of electrons...Ch. 6 - What reagents are needed to carry out the...Ch. 6 - Prob. 71PCh. 6 - Prob. 72PCh. 6 - Prob. 73PCh. 6 - Prob. 74PCh. 6 - a. Draw the product or products that will be...Ch. 6 - The second-order rate constant (in units of M1s1)...Ch. 6 - Which compound has the greater dipole moment?Ch. 6 - Prob. 78PCh. 6 - Prob. 79PCh. 6 - Prob. 80PCh. 6 - Prob. 81PCh. 6 - Prob. 82PCh. 6 - Prob. 83PCh. 6 - Prob. 84PCh. 6 - Prob. 85PCh. 6 - Prob. 86PCh. 6 - Prob. 87PCh. 6 - Prob. 88PCh. 6 - Prob. 89PCh. 6 - Prob. 90PCh. 6 - 91. a. How many alkenes could you treat with H2,...Ch. 6 - Draw the products of the following reactions. If...Ch. 6 - Prob. 93PCh. 6 - Prob. 94PCh. 6 - Two chemists at Dupont found that lCH2Znl is...Ch. 6 - Prob. 96PCh. 6 - Prob. 97PCh. 6 - What alkene gives the product shown after...Ch. 6 - Prob. 99PCh. 6 - Prob. 100PCh. 6 - Prob. 101PCh. 6 - Prob. 102PCh. 6 - Prob. 103PCh. 6 - Propose a mechanism for the following reaction:Ch. 6 - Prob. 106PCh. 6 - Prob. 107P
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