
(a)
Interpretation:
The
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.
Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches and results in the formation of product with sigma bond.
Acid Catalyzed Hydration Reaction: The reaction involves breaking of phi bonds between carbon-carbon multiple bonds and addition of alcohol to more substituted position of carbon in the molecule.
First step is the acid donates proton to the alkene which leads to the formation of more stable carbo cation.
Then, the water is added to the given alkene through acid catalyzed reaction where the water gets added to the carbo cation finally, the removal of one proton from oxonium ion (oxygen with one positive charge) using water results in the formation of product.
(b)
Interpretation:
The alkene used to prepare the given compound should be determined.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.
Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches and results in the formation of product with sigma bond.
Regioselective reaction: They are reactions which contain more than one product which are actually molecules with same molecular formula but different in the way they are connected and among those products only one product is major.
Addition of halogen over alkene: The addition of halogen to an alkene compound forms cyclic 3 membered intermediate as the first step which then the leads to the product formation substituting the halogens over carbons present in carbon-carbon double bond.
(c)
Interpretation:
The alkene used to prepare the given compound should be determined.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.
Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches and results in the formation of product with sigma bond.
Hydroboration reaction: The reaction involves addition of
(d)
Interpretation:
The alkene used to prepare the given compound should be determined.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.
Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches and results in the formation of product with sigma bond.
Hydroboration reaction: The reaction involves addition of
(e)
Interpretation:
The alkene used to prepare the given compound should be determined.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.
Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches and results in the formation of product with sigma bond.
Hydroboration reaction: The reaction involves addition of
(f)
Interpretation:
The alkene used to prepare the given compound should be determined.
Concept introduction:
Nucleophile: Nucleophiles are electron rich compounds which donates electrons to electrophilic compounds which results in bond formation.
Nucleophilic nature depends on the negative charge present in the molecule, the solvent in which it present and the electronegativity of the atom.
Electrophile: Electrophiles are electron deficient compounds which accepts electrons from nucleophiles that results in bond formation.
Addition Reaction: It is defined as chemical reaction in which two given molecules combines and forms product. The types of addition reactions are electrophilic addition, nucleophilic addition, free radical additions and cycloadditions. Generally, compounds with carbon-hetero atom bonds favors addition reaction.
Electrophilic addition: It is a type of addition reaction in which the pi bond present in the molecule breaks as the electrophile approaches and results in the formation of product with sigma bond.
Hydroboration reaction: The reaction involves addition of

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Chapter 6 Solutions
Organic Chemistry
- Would the following organic synthesis occur in one step? Add any missing products, required catalysts, inorganic reagents, and other important conditions. Please include a detailed explanation and drawings showing how the reaction may occur in one step.arrow_forward(a) Sketch the 'H NMR of the following chemical including the approximate chemical shifts, the multiplicity (splitting) of all signals and the integration (b) How many signals would you expect in the 13C NMR? CH3arrow_forwardDraw the Show the major and minor product(s) for the following reaction mechanisms for both reactions and show all resonance structures for any Explain why the major product is favoured? intermediates H-Brarrow_forward
- 3. Draw ALL THE POSSBILE PRODUCTS AND THE MECHANISMS WITH ALL RESONANCE STRUCTURES. Explain using the resonance structures why the major product(s) are formed over the minor product(s). H₂SO4, HONO CHarrow_forward7. Provide the product(s), starting material(s) and/or condition(s) required for the No mechanisms required. below reaction HO + H-I CI FO Br2, FeBr3 O I-Oarrow_forward6. Design the most efficient synthesis of the following product starting from phenot Provide the reaction conditions for each step (more than one step is required) and explain the selectivity of each reaction. NO MECHANISMS ARE REQUIRED. OH step(s) CIarrow_forward
- What is the skeletal structure of the product of the following organic reaction?arrow_forwardIf a reaction occurs, what would be the major products? Please include a detailed explanation as well as a drawing showing how the reaction occurs and what the final product is.arrow_forwardWhat is the major organic product of the following nucleophilic acyl substitution reaction of an acid chloride below?arrow_forward
- Organic ChemistryChemistryISBN:9781305580350Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. FootePublisher:Cengage Learning

