Organic Chemistry
7th Edition
ISBN: 9780321803221
Author: Paula Y. Bruice
Publisher: Prentice Hall
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Chapter 6.8, Problem 18P
Which is more highly regionselective: reaction of an
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Which represents an efficient synthetic route to go from an alkane to an alkene?
O elimination with NaNH2, followed by a water workup
O anti-Markovnikov hydrohalogenation, followed by elimination
O radical bromination, followed by elimination
O hydration, followed by elimination
O hydration, followed by ozonolysis of the double bond
See atachment for the question. Thank you!
Which alkene when hydrochlorinated (hydrohalogenation reaction) will give this alkyl halide as product
H3C
CH3
CI
CH3
2-methyl-1-pentene
2,3-dimethyl-1-pentene
2-methyl-2-butene
3-methyl-2-pentene
Chapter 6 Solutions
Organic Chemistry
Ch. 6.1 - Draw the mechanism for the reaction of cyclohexene...Ch. 6.2 - a. How many bond orbitals are avilable for...Ch. 6.2 - Prob. 3PCh. 6.2 - Prob. 4PCh. 6.3 - Prob. 5PCh. 6.4 - Prob. 6PCh. 6.4 - What alkene should be used to synthesize each of...Ch. 6.4 - Prob. 8PCh. 6.5 - The pKa of a protonated alcohol is about 2.5, and...Ch. 6.5 - Prob. 10P
Ch. 6.5 - Prob. 11PCh. 6.6 - a. What is the major product or each or the...Ch. 6.6 - Prob. 14PCh. 6.6 - Prob. 15PCh. 6.7 - What is the major product obtained from the...Ch. 6.8 - Which is more highly regionselective: reaction of...Ch. 6.8 - Prob. 19PCh. 6.9 - What will be the product of the preceding reaction...Ch. 6.9 - Prob. 21PCh. 6.9 - Prob. 22PCh. 6.9 - Prob. 23PCh. 6.9 - What is the product of the addition of 1Cl to...Ch. 6.9 - What will be the major product obtained from the...Ch. 6.9 - Propose a mechanism for the following reaction:Ch. 6.10 - Draw structures for the following: a. 24...Ch. 6.10 - What alkene would you treat with a peroxyacid in...Ch. 6.11 - What products are formed when the following...Ch. 6.11 - Prob. 30PCh. 6.11 - Prob. 31PCh. 6.12 - Prob. 34PCh. 6.12 - Prob. 35PCh. 6.13 - Prob. 36PCh. 6.13 - Prob. 37PCh. 6.13 - Prob. 38PCh. 6.14 - What characteristics must the reactant of a...Ch. 6.15 - Prob. 40PCh. 6.15 - What stereoisomers are obtained from each of the...Ch. 6.15 - Prob. 45PCh. 6.15 - Prob. 46PCh. 6.15 - Prob. 47PCh. 6.15 - Prob. 49PCh. 6.15 - Prob. 50PCh. 6.15 - Prob. 51PCh. 6.15 - Prob. 52PCh. 6.15 - Prob. 53PCh. 6.16 - Prob. 54PCh. 6.17 - Prob. 55PCh. 6.18 - Explain why 3-methykyclohexene should not be used...Ch. 6.18 - Prob. 58PCh. 6 - Prob. 59PCh. 6 - Prob. 60PCh. 6 - What is the major product of the reaction of...Ch. 6 - Give two names for each of the following:Ch. 6 - Prob. 63PCh. 6 - Prob. 64PCh. 6 - Prob. 65PCh. 6 - What are the products of the following reactions?...Ch. 6 - When 3-methyl-1-butene reacts with HBr, two alkyl...Ch. 6 - Prob. 68PCh. 6 - Draw curved arrows to show the flow of electrons...Ch. 6 - What reagents are needed to carry out the...Ch. 6 - Prob. 71PCh. 6 - Prob. 72PCh. 6 - Prob. 73PCh. 6 - Prob. 74PCh. 6 - a. Draw the product or products that will be...Ch. 6 - The second-order rate constant (in units of M1s1)...Ch. 6 - Which compound has the greater dipole moment?Ch. 6 - Prob. 78PCh. 6 - Prob. 79PCh. 6 - Prob. 80PCh. 6 - Prob. 81PCh. 6 - Prob. 82PCh. 6 - Prob. 83PCh. 6 - Prob. 84PCh. 6 - Prob. 85PCh. 6 - Prob. 86PCh. 6 - Prob. 87PCh. 6 - Prob. 88PCh. 6 - Prob. 89PCh. 6 - Prob. 90PCh. 6 - 91. a. How many alkenes could you treat with H2,...Ch. 6 - Draw the products of the following reactions. If...Ch. 6 - Prob. 93PCh. 6 - Prob. 94PCh. 6 - Two chemists at Dupont found that lCH2Znl is...Ch. 6 - Prob. 96PCh. 6 - Prob. 97PCh. 6 - What alkene gives the product shown after...Ch. 6 - Prob. 99PCh. 6 - Prob. 100PCh. 6 - Prob. 101PCh. 6 - Prob. 102PCh. 6 - Prob. 103PCh. 6 - Propose a mechanism for the following reaction:Ch. 6 - Prob. 106PCh. 6 - Prob. 107P
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- Alcohols are important for organic synthesis, especially in situations involving alkenes. The alcohol might be the desired product, or the OH group might be transformed into another functional group via halogenation, oxidation, or perhaps conversion to a sulfonic ester derivative. Formation of an alcohol from an alkene is particularly powerful because conditions can be chosen to produce either the Markovnikov or non-Markovnikov product from an unsymmetrical alkene. Using your reaction roadmap as a guide, show how to convert 4-methyl-1-pentene into 5-methylhexanenitrile. You must use 4-methyl-1-pentene and sodium cyanide as the source of all carbon atoms in the target molecule. Show all reagents needed and all molecules synthesized along the way.arrow_forwardTake 1-methylcyclohexene as the alkene and treat it with the reagent.arrow_forward7:51 PM Sun Oct 16 ← Question 9 of 15 HO Curved arrows are used to illustrate the flow of electrons. Follow the curved arrows and draw the hydrocarbon product of the following reaction. Include all lone pairs and charges as appropriate. Ignore inorganic byproducts. H3C. CH3 CH3 @ 100% Select to Draw Submitarrow_forward
- Which of the following alkene reactions occurs with a complete cleavage of the C=C ( breaking both pi and sigma bond components) ? Select one: A. Alkene + H2O2 with catalytic amount of OsO4 B. Reaction of an alkene with KMnO4/OH- at room temperature. C. Treating the alkene with O3 gas, followed by reduction with Zn / H2O D. Reaction of an alkene with water (H2O) in the presence of a H+ catalyst.arrow_forwardQuestão 10A certain hydrocarbon had the molecular formula C16H26 and contained two triple bonds. Ozonolysis resulted in CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. What is the reasonable structure for this hydrocarbon? Hexadec-6,10-dino undec-1,5-dino Hept-1,5-dino hex-1,5-dino naharrow_forwardDraw the structure for an alkene that gives the following reaction product. CH212, Zn/Cu Ignore alkene stereochemistry. • You do not have to explicitly draw H atoms. In cases where there is more than one answer, just draw one. C P opy aste ChemDoodle®arrow_forward
- Draw the structural formula of the alkene that reacts with ozone followed by dimethyl sulfide to give product or set of products.arrow_forwardDraw the alkene that would react with the reagent given to account for the product formed. ? + + H₂O **** H₂S04 • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. CH3 CH3 CHCCH3 | | OH CH3 +1arrow_forwardDraw the major organic product formed by reaction of 2-hexyne with the following reagent: H₂O in H₂SO4 / HgSO4. • Consider E/Z stereochemistry of alkenes. • In cases where there is more than one answer, just draw one. • If no reaction occurs, draw the organic starting material.arrow_forward
- How many alkenes could you treat with H2, Pd/C to prepare methylcyclopentane?arrow_forwardDraw the structure for an alkene that gives the following reaction product. 7 CH2l2, Zn/Cu Ignore alkene stereochemistry. • You do not have to explicitly draw H atoms. • In cases where there is more than one answer, just draw one. / [F ?arrow_forward4. A student was asked to prepare an alkene X in high yield using any alcohol as starting material CH3 CH,-C -CH=CH, CH3 X He chose 3, 3-dimethylbutan-2-ol (XI) and carried out a dehydration reaction. He was however horrified to note that the only alkene obtained was XII. CH3 OH CH3 CH;-C=C-CH3 conc. H,SO4 CH-CH3 heat CH3 CH3 XI XII i) Explain what went wrong here, and why X could not be formed from 3, 3-dimethylbutan-2-ol. Use structures to help support your answer. ii) Give an equation to show a much better method for preparing X in high yield. 5. Analyze the following structure and write one combination for Grignard reagent and a carbonyl that would give rise to it. CH,-CH,-OHarrow_forward
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