Essential Organic Chemistry (3rd Edition)
Essential Organic Chemistry (3rd Edition)
3rd Edition
ISBN: 9780321937711
Author: Paula Yurkanis Bruice
Publisher: PEARSON
Question
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Chapter 6, Problem 34P

(a)

Interpretation Introduction

Interpretation:

The major product obtained from the reaction of given compound with excess of HCl should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

  Essential Organic Chemistry (3rd Edition), Chapter 6, Problem 34P , additional homework tip  1

If excess halides are present, a second addition reaction also occurs.

(b)

Interpretation Introduction

Interpretation:

The major product obtained from the reaction of given compound with excess of HCl should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

  Essential Organic Chemistry (3rd Edition), Chapter 6, Problem 34P , additional homework tip  2

If excess halides are present, a second addition reaction also occurs.

(c)

Interpretation Introduction

Interpretation:

The major product obtained from the reaction of given compound with excess of HCl should be determined.

Concept Introduction:

Addition of halides to alkynes: Halogens like chlorine and bromine add to the alkyne compounds. The general form of the reaction is given below.

  Essential Organic Chemistry (3rd Edition), Chapter 6, Problem 34P , additional homework tip  3

If excess halides are present, a second addition reaction also occurs.

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Q2: Ranking Acidity a) Rank the labeled protons in the following molecule in order of increasing pKa. Briefly explain the ranking. Use Table 2.2 as reference. Ha Нь HC H-N Ha OHe b) Atenolol is a drug used to treat high blood pressure. Which of the indicated N-H bonds is more acidic? Explain. (Hint: use resonance structures to help) Name the functional groups on atenolol. H H-N atenolol Ν H-N OH Н
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Essential Organic Chemistry (3rd Edition)

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