The groups that has to be considered as substituents and the name for them has to be given. Concept Introduction: All the molecules have their unique names. These names must be known in order to communicate. But remembering all the chemical names is impossible as there are many numbers of molecules. To avoid this, the IUPAC nomenclature of naming the molecules has to be understood. By use of this the name of the molecules can be derived from the rules. Every IUPAC name consist of five parts. They are, Stereoisomerism Substituents Parent Unsaturation Functional Group Stereoisomerism indicate if the considered molecule has any stereocenters are present (R,S) and if double bond is present are cis/trans . The groups that are connected to the main carbon chain is known as substituents. The substituents are identified after the carbon chain is identified and the functional group present in the given compound also identified. The substituents are named by adding “yl” to the end of the name which indicate that it is a substituent is an alkyl. The OH group is named as –hydroxy-, NH 2 group is named as –amino-, Ketone is named as –keto-, Aldehyde is named as –aldo- and Halogen is named as –halo-. If there are more than one number of the same substituent, then the required prefix, di-, tri-, tetra- are added. The longest carbon chain is known as the parent. Parent carbon chain is the lengthiest carbon chain in the molecule that must include the functional group that is present in the compound. The longest carbon chain is identified and the parent name is given by the number of carbon atoms that is present in it. It must be remembered that even though functional group is not present in parent carbon chain, the double bond, triple bond if present has to be included. Number of carbon atoms in chain Parent 1 Meth 2 Eth 3 Prop 4 But 5 Pent 6 Hex Unsaturation indicates that if any triple or double bonds are present in the molecule. If a compound contains a double bond it is named as “-en-” and if a triple bond is present “-yn-” is used. If a compound contains two double bonds, then it is named as “-dien-”. If three double bonds are present in the given compound, then it is named as “-trien-”. This same rule applies for the compound that contains multiple triple bonds also. Functional group is the one after which the considered compound is being named. Functional groups determine the chemical property of a compound. While naming a compound using IUPAC nomenclature, we add suffix to the name of the compound to show what functional group is present in it. Some of the examples are, Functional Group Class of compound Suffix Ester -oate Ketone -one Aldehyde -al Carboxylic acid -oic acid Alcohol -ol Amine -amine

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Answer 1

Question

Chapter 5.4, Problem 5.37P

Interpretation Introduction

Interpretation:

The groups that has to be considered as substituents and the name for them has to be given.

Concept Introduction:

All the molecules have their unique names. These names must be known in order to communicate. But remembering all the chemical names is impossible as there are many numbers of molecules. To avoid this, the IUPAC nomenclature of naming the molecules has to be understood. By use of this the name of the molecules can be derived from the rules. Every IUPAC name consist of five parts. They are,

Stereoisomerism Substituents Parent Unsaturation Functional Group

Stereoisomerism indicate if the considered molecule has any stereocenters are present (R,S) and if double bond is present are cis/trans.

The groups that are connected to the main carbon chain is known as substituents. The substituents are identified after the carbon chain is identified and the functional group present in the given compound also identified. The substituents are named by adding “yl” to the end of the name which indicate that it is a substituent is an alkyl. The OH group is named as –hydroxy-, NH2 group is named as –amino-, Ketone is named as –keto-, Aldehyde is named as –aldo- and Halogen is named as –halo-. If there are more than one number of the same substituent, then the required prefix, di-, tri-, tetra- are added.

The longest carbon chain is known as the parent. Parent carbon chain is the lengthiest carbon chain in the molecule that must include the functional group that is present in the compound. The longest carbon chain is identified and the parent name is given by the number of carbon atoms that is present in it. It must be remembered that even though functional group is not present in parent carbon chain, the double bond, triple bond if present has to be included.

Number of carbon atoms in chain Parent
1 Meth
2 Eth
3 Prop
4 But
5 Pent
6 Hex

Unsaturation indicates that if any triple or double bonds are present in the molecule. If a compound contains a double bond it is named as “-en-” and if a triple bond is present “-yn-” is used. If a compound contains two double bonds, then it is named as “-dien-”. If three double bonds are present in the given compound, then it is named as “-trien-”. This same rule applies for the compound that contains multiple triple bonds also.

Functional group is the one after which the considered compound is being named. Functional groups determine the chemical property of a compound. While naming a compound using IUPAC nomenclature, we add suffix to the name of the compound to show what functional group is present in it. Some of the examples are,

Functional Group Class of compound Suffix
Ester -oate
Ketone -one
Aldehyde -al
Carboxylic acid -oic acid
Alcohol -ol
Amine -amine

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Indicate the products obtained from the reaction of 4-methylbenzonitrile with a sulfonitric acid mixture (H2SO4 + HNO3). Indicate the majority if necessary.

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In organic chemistry, what is the correct name for the mixture H2SO4 + HNO3 used in reactions: sulphonitric mixture or sulfonitric mixture?

Answer 2

Question

Chapter 5.4, Problem 5.37P

Interpretation Introduction

Interpretation:

The groups that has to be considered as substituents and the name for them has to be given.

Concept Introduction:

All the molecules have their unique names. These names must be known in order to communicate. But remembering all the chemical names is impossible as there are many numbers of molecules. To avoid this, the IUPAC nomenclature of naming the molecules has to be understood. By use of this the name of the molecules can be derived from the rules. Every IUPAC name consist of five parts. They are,

Stereoisomerism Substituents Parent Unsaturation Functional Group

Stereoisomerism indicate if the considered molecule has any stereocenters are present (R,S) and if double bond is present are cis/trans.

The groups that are connected to the main carbon chain is known as substituents. The substituents are identified after the carbon chain is identified and the functional group present in the given compound also identified. The substituents are named by adding “yl” to the end of the name which indicate that it is a substituent is an alkyl. The OH group is named as –hydroxy-, NH2 group is named as –amino-, Ketone is named as –keto-, Aldehyde is named as –aldo- and Halogen is named as –halo-. If there are more than one number of the same substituent, then the required prefix, di-, tri-, tetra- are added.

The longest carbon chain is known as the parent. Parent carbon chain is the lengthiest carbon chain in the molecule that must include the functional group that is present in the compound. The longest carbon chain is identified and the parent name is given by the number of carbon atoms that is present in it. It must be remembered that even though functional group is not present in parent carbon chain, the double bond, triple bond if present has to be included.

Number of carbon atoms in chain Parent
1 Meth
2 Eth
3 Prop
4 But
5 Pent
6 Hex

Unsaturation indicates that if any triple or double bonds are present in the molecule. If a compound contains a double bond it is named as “-en-” and if a triple bond is present “-yn-” is used. If a compound contains two double bonds, then it is named as “-dien-”. If three double bonds are present in the given compound, then it is named as “-trien-”. This same rule applies for the compound that contains multiple triple bonds also.

Functional group is the one after which the considered compound is being named. Functional groups determine the chemical property of a compound. While naming a compound using IUPAC nomenclature, we add suffix to the name of the compound to show what functional group is present in it. Some of the examples are,

Functional Group Class of compound Suffix
Ester -oate
Ketone -one
Aldehyde -al
Carboxylic acid -oic acid
Alcohol -ol
Amine -amine

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Answer 3

Question

Chapter 5.4, Problem 5.37P

Interpretation Introduction

Interpretation:

The groups that has to be considered as substituents and the name for them has to be given.

Concept Introduction:

All the molecules have their unique names. These names must be known in order to communicate. But remembering all the chemical names is impossible as there are many numbers of molecules. To avoid this, the IUPAC nomenclature of naming the molecules has to be understood. By use of this the name of the molecules can be derived from the rules. Every IUPAC name consist of five parts. They are,

Stereoisomerism Substituents Parent Unsaturation Functional Group

Stereoisomerism indicate if the considered molecule has any stereocenters are present (R,S) and if double bond is present are cis/trans.

The groups that are connected to the main carbon chain is known as substituents. The substituents are identified after the carbon chain is identified and the functional group present in the given compound also identified. The substituents are named by adding “yl” to the end of the name which indicate that it is a substituent is an alkyl. The OH group is named as –hydroxy-, NH2 group is named as –amino-, Ketone is named as –keto-, Aldehyde is named as –aldo- and Halogen is named as –halo-. If there are more than one number of the same substituent, then the required prefix, di-, tri-, tetra- are added.

The longest carbon chain is known as the parent. Parent carbon chain is the lengthiest carbon chain in the molecule that must include the functional group that is present in the compound. The longest carbon chain is identified and the parent name is given by the number of carbon atoms that is present in it. It must be remembered that even though functional group is not present in parent carbon chain, the double bond, triple bond if present has to be included.

Number of carbon atoms in chain Parent
1 Meth
2 Eth
3 Prop
4 But
5 Pent
6 Hex

Unsaturation indicates that if any triple or double bonds are present in the molecule. If a compound contains a double bond it is named as “-en-” and if a triple bond is present “-yn-” is used. If a compound contains two double bonds, then it is named as “-dien-”. If three double bonds are present in the given compound, then it is named as “-trien-”. This same rule applies for the compound that contains multiple triple bonds also.

Functional group is the one after which the considered compound is being named. Functional groups determine the chemical property of a compound. While naming a compound using IUPAC nomenclature, we add suffix to the name of the compound to show what functional group is present in it. Some of the examples are,

Functional Group Class of compound Suffix
Ester -oate
Ketone -one
Aldehyde -al
Carboxylic acid -oic acid
Alcohol -ol
Amine -amine

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Answer 4

Question

Chapter 5.4, Problem 5.37P

Interpretation Introduction

Interpretation:

The groups that has to be considered as substituents and the name for them has to be given.

Concept Introduction:

All the molecules have their unique names. These names must be known in order to communicate. But remembering all the chemical names is impossible as there are many numbers of molecules. To avoid this, the IUPAC nomenclature of naming the molecules has to be understood. By use of this the name of the molecules can be derived from the rules. Every IUPAC name consist of five parts. They are,

Stereoisomerism Substituents Parent Unsaturation Functional Group

Stereoisomerism indicate if the considered molecule has any stereocenters are present (R,S) and if double bond is present are cis/trans.

The groups that are connected to the main carbon chain is known as substituents. The substituents are identified after the carbon chain is identified and the functional group present in the given compound also identified. The substituents are named by adding “yl” to the end of the name which indicate that it is a substituent is an alkyl. The OH group is named as –hydroxy-, NH2 group is named as –amino-, Ketone is named as –keto-, Aldehyde is named as –aldo- and Halogen is named as –halo-. If there are more than one number of the same substituent, then the required prefix, di-, tri-, tetra- are added.

The longest carbon chain is known as the parent. Parent carbon chain is the lengthiest carbon chain in the molecule that must include the functional group that is present in the compound. The longest carbon chain is identified and the parent name is given by the number of carbon atoms that is present in it. It must be remembered that even though functional group is not present in parent carbon chain, the double bond, triple bond if present has to be included.

Number of carbon atoms in chain Parent
1 Meth
2 Eth
3 Prop
4 But
5 Pent
6 Hex

Unsaturation indicates that if any triple or double bonds are present in the molecule. If a compound contains a double bond it is named as “-en-” and if a triple bond is present “-yn-” is used. If a compound contains two double bonds, then it is named as “-dien-”. If three double bonds are present in the given compound, then it is named as “-trien-”. This same rule applies for the compound that contains multiple triple bonds also.

Functional group is the one after which the considered compound is being named. Functional groups determine the chemical property of a compound. While naming a compound using IUPAC nomenclature, we add suffix to the name of the compound to show what functional group is present in it. Some of the examples are,

Functional Group Class of compound Suffix
Ester -oate
Ketone -one
Aldehyde -al
Carboxylic acid -oic acid
Alcohol -ol
Amine -amine

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Answer 5

Chapter 5.4, Problem 5.37P

Interpretation Introduction

Interpretation:

The groups that has to be considered as substituents and the name for them has to be given.

Concept Introduction:

All the molecules have their unique names. These names must be known in order to communicate. But remembering all the chemical names is impossible as there are many numbers of molecules. To avoid this, the IUPAC nomenclature of naming the molecules has to be understood. By use of this the name of the molecules can be derived from the rules. Every IUPAC name consist of five parts. They are,

Stereoisomerism Substituents Parent Unsaturation Functional Group

Stereoisomerism indicate if the considered molecule has any stereocenters are present (R,S) and if double bond is present are cis/trans.

The groups that are connected to the main carbon chain is known as substituents. The substituents are identified after the carbon chain is identified and the functional group present in the given compound also identified. The substituents are named by adding “yl” to the end of the name which indicate that it is a substituent is an alkyl. The OH group is named as –hydroxy-, NH2 group is named as –amino-, Ketone is named as –keto-, Aldehyde is named as –aldo- and Halogen is named as –halo-. If there are more than one number of the same substituent, then the required prefix, di-, tri-, tetra- are added.

The longest carbon chain is known as the parent. Parent carbon chain is the lengthiest carbon chain in the molecule that must include the functional group that is present in the compound. The longest carbon chain is identified and the parent name is given by the number of carbon atoms that is present in it. It must be remembered that even though functional group is not present in parent carbon chain, the double bond, triple bond if present has to be included.

Number of carbon atoms in chain Parent
1 Meth
2 Eth
3 Prop
4 But
5 Pent
6 Hex

Unsaturation indicates that if any triple or double bonds are present in the molecule. If a compound contains a double bond it is named as “-en-” and if a triple bond is present “-yn-” is used. If a compound contains two double bonds, then it is named as “-dien-”. If three double bonds are present in the given compound, then it is named as “-trien-”. This same rule applies for the compound that contains multiple triple bonds also.

Functional group is the one after which the considered compound is being named. Functional groups determine the chemical property of a compound. While naming a compound using IUPAC nomenclature, we add suffix to the name of the compound to show what functional group is present in it. Some of the examples are,

Functional Group Class of compound Suffix
Ester -oate
Ketone -one
Aldehyde -al
Carboxylic acid -oic acid
Alcohol -ol
Amine -amine

Answer 6

Chapter 5.4, Problem 5.37P

Interpretation Introduction

Interpretation:

The groups that has to be considered as substituents and the name for them has to be given.

Concept Introduction:

All the molecules have their unique names. These names must be known in order to communicate. But remembering all the chemical names is impossible as there are many numbers of molecules. To avoid this, the IUPAC nomenclature of naming the molecules has to be understood. By use of this the name of the molecules can be derived from the rules. Every IUPAC name consist of five parts. They are,

Stereoisomerism Substituents Parent Unsaturation Functional Group

Stereoisomerism indicate if the considered molecule has any stereocenters are present (R,S) and if double bond is present are cis/trans.

The groups that are connected to the main carbon chain is known as substituents. The substituents are identified after the carbon chain is identified and the functional group present in the given compound also identified. The substituents are named by adding “yl” to the end of the name which indicate that it is a substituent is an alkyl. The OH group is named as –hydroxy-, NH2 group is named as –amino-, Ketone is named as –keto-, Aldehyde is named as –aldo- and Halogen is named as –halo-. If there are more than one number of the same substituent, then the required prefix, di-, tri-, tetra- are added.

The longest carbon chain is known as the parent. Parent carbon chain is the lengthiest carbon chain in the molecule that must include the functional group that is present in the compound. The longest carbon chain is identified and the parent name is given by the number of carbon atoms that is present in it. It must be remembered that even though functional group is not present in parent carbon chain, the double bond, triple bond if present has to be included.

Number of carbon atoms in chain Parent
1 Meth
2 Eth
3 Prop
4 But
5 Pent
6 Hex

Unsaturation indicates that if any triple or double bonds are present in the molecule. If a compound contains a double bond it is named as “-en-” and if a triple bond is present “-yn-” is used. If a compound contains two double bonds, then it is named as “-dien-”. If three double bonds are present in the given compound, then it is named as “-trien-”. This same rule applies for the compound that contains multiple triple bonds also.

Functional group is the one after which the considered compound is being named. Functional groups determine the chemical property of a compound. While naming a compound using IUPAC nomenclature, we add suffix to the name of the compound to show what functional group is present in it. Some of the examples are,

Functional Group Class of compound Suffix
Ester -oate
Ketone -one
Aldehyde -al
Carboxylic acid -oic acid
Alcohol -ol
Amine -amine

Answer 7

Chapter 5.4, Problem 5.37P

Interpretation Introduction

Interpretation:

The groups that has to be considered as substituents and the name for them has to be given.

Concept Introduction:

All the molecules have their unique names. These names must be known in order to communicate. But remembering all the chemical names is impossible as there are many numbers of molecules. To avoid this, the IUPAC nomenclature of naming the molecules has to be understood. By use of this the name of the molecules can be derived from the rules. Every IUPAC name consist of five parts. They are,

Stereoisomerism Substituents Parent Unsaturation Functional Group

Stereoisomerism indicate if the considered molecule has any stereocenters are present (R,S) and if double bond is present are cis/trans.

The groups that are connected to the main carbon chain is known as substituents. The substituents are identified after the carbon chain is identified and the functional group present in the given compound also identified. The substituents are named by adding “yl” to the end of the name which indicate that it is a substituent is an alkyl. The OH group is named as –hydroxy-, NH2 group is named as –amino-, Ketone is named as –keto-, Aldehyde is named as –aldo- and Halogen is named as –halo-. If there are more than one number of the same substituent, then the required prefix, di-, tri-, tetra- are added.

The longest carbon chain is known as the parent. Parent carbon chain is the lengthiest carbon chain in the molecule that must include the functional group that is present in the compound. The longest carbon chain is identified and the parent name is given by the number of carbon atoms that is present in it. It must be remembered that even though functional group is not present in parent carbon chain, the double bond, triple bond if present has to be included.

Number of carbon atoms in chain Parent
1 Meth
2 Eth
3 Prop
4 But
5 Pent
6 Hex

Unsaturation indicates that if any triple or double bonds are present in the molecule. If a compound contains a double bond it is named as “-en-” and if a triple bond is present “-yn-” is used. If a compound contains two double bonds, then it is named as “-dien-”. If three double bonds are present in the given compound, then it is named as “-trien-”. This same rule applies for the compound that contains multiple triple bonds also.

Functional group is the one after which the considered compound is being named. Functional groups determine the chemical property of a compound. While naming a compound using IUPAC nomenclature, we add suffix to the name of the compound to show what functional group is present in it. Some of the examples are,

Functional Group Class of compound Suffix
Ester -oate
Ketone -one
Aldehyde -al
Carboxylic acid -oic acid
Alcohol -ol
Amine -amine

Answer 8

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Answer 9

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Answer 10

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Answer 11

Ch. 5.1 - Prob. 5.2P Ch. 5.1 - PROBLEMS Identify what suffix you would use in...Ch. 5.1 - Prob. 5.4P Ch. 5.1 - Prob. 5.5P Ch. 5.1 - Prob. 5.6P Ch. 5.1 - Prob. 5.7P Ch. 5.1 - Prob. 5.8P Ch. 5.1 - Prob. 5.9P Ch. 5.1 - Prob. 5.10P Ch. 5.2 - Prob. 5.12P

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Chapter 5 Solutions

Number of carbon atoms in chain	Parent
1	Meth
2	Eth
3	Prop
4	But
5	Pent
6	Hex

Functional Group	Class of compound	Suffix
	Ester	-oate
	Ketone	-one
	Aldehyde	-al
	Carboxylic acid	-oic acid
	Alcohol	-ol
	Amine	-amine