Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Chapter 5, Problem 5.43E
For the given
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Determine
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Q3: Curved Arrows, Lewis Acids & Bases, Nucleophiles and Electrophiles
Considering the following reactions:
a) Predict the products to complete the reactions.
b) Use curved electron-pushing arrows to show the mechanism for the reaction in
the forward direction. Redraw some of the compounds to explicitly illustrate all
bonds that are broken and all bonds that are formed.
c) Label Lewis acids and bases, nucleophiles and electrophiles in the reactions.
A.
S
+
AICI 3
B.
+
H₂O
3. A thermometer is placed in a test tube of chipped ice at -5.0 °C. The temperature is recorded at the
time intervals shown below until room temperature is reached. Plot the data given below on graph
paper and explain all flat, horizontal portions of the curve. Plot time on the X-axis!
Time (min)
Temperature (°C)
0
-5.0
2
-2.5
4
-1.0
6
0.0
10
0.0
15
0.0
20
0.0
25
0.0
30
1.5
35
4.0
40
8.0
45
11.5
50
15.0
55
17.5
60
19.0
65
20.0
70
20.0
75
20.0
80
20.0
Naming the Alkanes
a) Write the IUPAC nomenclature of the compound below
b) Draw 4-isopropyl-2,4,5-trimethylheptane, identify the primary, secondary, tertiary, and
quaternary carbons.
c) Rank pentane, neopentane and isopentane for boiling point.
pentane:
H3C-CH2-CH2-CH2-CH3
neopentane:
CH3
H3C-Ċ-CH3
I
CH3
isopentane:
CH3
H3C-CH2-CH-CH3
Chapter 5 Solutions
Physical Chemistry
Ch. 5 - 5.1. Can a battery that has a voltage be...Ch. 5 - 5.2. What is the difference between a static...Ch. 5 - Which system in each pair best represents...Ch. 5 -
5.4. Supersaturated solutions can be made in...Ch. 5 -
5.5. Following is a chemical reaction between...Ch. 5 - 5.6. The following is a reaction with its initial...Ch. 5 - The following is a reaction with initial amounts...Ch. 5 - 5.8. The hemoglobin in blood establishes an...Ch. 5 - Prob. 5.9ECh. 5 - 5.10. If and gases were contained in a system...
Ch. 5 - 5.11. Determine the numerical value of Q for the...Ch. 5 - 5.12. True or false: If all the partial pressures...Ch. 5 - For the reaction 2SO3(g)2SO2(g)+O2(g) when 2mol of...Ch. 5 - 5.14. Determine and for the following reaction at...Ch. 5 - 5.15. Consider the reaction
If the partial...Ch. 5 -
5.16. In atmospheric chemistry, the following...Ch. 5 - Prob. 5.17ECh. 5 - 5.18. Hydrogen cyanide can isomerize to hydrogen...Ch. 5 - 5.19. Assume that a reaction exists such that...Ch. 5 - Prob. 5.20ECh. 5 - 5.21. Show that if the coefficients of a balanced...Ch. 5 - 5.22. True or false: If for a gas-phase reaction,...Ch. 5 - 5.23. The balanced chemical reaction for the...Ch. 5 - The answers in exercise 5.23 should show that...Ch. 5 - At a high enough temperature, the equilibrium...Ch. 5 - Prob. 5.26ECh. 5 - 5.27. Nitrogen dioxide,, dimerizes easily to form...Ch. 5 - 5.28. Another nitrogen-oxygen reaction of some...Ch. 5 - Prob. 5.29ECh. 5 - Prob. 5.30ECh. 5 - Prob. 5.31ECh. 5 - 5.32. For the reaction
. (a) Using in Appendix...Ch. 5 - 5.33. Use the data in Appendix to calculate ...Ch. 5 - 5.34. The of diamond, a crystalline form of...Ch. 5 - 5.35. The densities of graphite and diamond are ...Ch. 5 - Buckminsterfullerene, C60, is a spherical molecule...Ch. 5 - Prob. 5.37ECh. 5 - At what pressure does H2O have an activity of...Ch. 5 - The bisulfate or hydrogen sulfate anion, HSO4, is...Ch. 5 - Prob. 5.40ECh. 5 - Write the equilibrium constant expression for each...Ch. 5 - Prob. 5.42ECh. 5 - For the given chemical equilibrium, these data are...Ch. 5 - Biological standard states include specifying a...Ch. 5 - a At 25.0C, Kw for the autoionization of water is...Ch. 5 - 5.46. For a reaction whose standard enthalpy...Ch. 5 - 5.47. For the reaction
and . Estimate for this...Ch. 5 - 5.48. The isotope exchange reaction
has an...Ch. 5 - 5.49. Consider the following equilibrium:
What...Ch. 5 - 5.50. For the equilibrium
Equilibrium partial...Ch. 5 - The decomposition of NaHCO3, used in kitchens to...Ch. 5 - 5.52. For the equilibrium
at,. In a flask, of...Ch. 5 - Prob. 5.53ECh. 5 - 5.54. For the reaction
The equilibrium...Ch. 5 - Prob. 5.55ECh. 5 - 5.56. Of the amino acids listed in Table , which...Ch. 5 - 5.57. Determine the concentration of the three...Ch. 5 - 5.58. The formation of zwitterionic glycine, ,...Ch. 5 - 5.59. Monosodium glutamate, or MSG, is the sodium...Ch. 5 - Prob. 5.60ECh. 5 - Consider the balanced chemical reaction...Ch. 5 - For the gas-phase reaction 2H2+O22H2O rxnG is...Ch. 5 - Prob. 5.63ECh. 5 - Prob. 5.64E
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