Physical Chemistry
2nd Edition
ISBN: 9781133958437
Author: Ball, David W. (david Warren), BAER, Tomas
Publisher: Wadsworth Cengage Learning,
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Textbook Question
Chapter 5, Problem 5.33E
Use the data in Appendix
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A chemical system is set up by placing some solid ammonium chloride in an ammonia solution.
The equilibrium established can be represented as follows:
NH4*(aq) + H2O(e) 2 H30*(aq) + NH3(aq)
The pH of the solution is taken, then a small amount of NaOH(aq) is added and the pH is taken
again.
What can be said about the change in pH for the solution?
The pH significantly increases because a strong base has been added to the solution.
The pH significantly decreases because a strong base has been added to the solution.
There is very little change to the pH of the solution. If anything the pH of the solution
decreases slightly.
There is very little change to the pH of the solution. If anything the pH of the solution
increases slightly.
Cu2+(aq) + H2O(l) ⇌ CuOH+(aq) + H+(aq) Keq = 1.2 x 10−8
A 1.00 M solution of copper(II) nitrate is created and the system shown above reaches equilibrium. What happens to the pH of the system if more CuOH+ is added after reaching equilibrium?
The pH of the system will not change because of the small size of K.
The pH of the system will increase because of the increased concentration of CuOH+.
The pH of the system will increase as the reverse reaction proceeds at a faster rate to reestablish equilibrium.
The pH of the system will decrease as the forward reaction proceeds at a faster rate to reestablish equilibrium.
Write the equation for the equilibrium constant (K) of the reaction studied in this exercise.
2CrO4 2−(aq)+2H+(aq)⇌Cr2O7 2−(aq)+H2O(l)
Chapter 5 Solutions
Physical Chemistry
Ch. 5 - 5.1. Can a battery that has a voltage be...Ch. 5 - 5.2. What is the difference between a static...Ch. 5 - Which system in each pair best represents...Ch. 5 -
5.4. Supersaturated solutions can be made in...Ch. 5 -
5.5. Following is a chemical reaction between...Ch. 5 - 5.6. The following is a reaction with its initial...Ch. 5 - The following is a reaction with initial amounts...Ch. 5 - 5.8. The hemoglobin in blood establishes an...Ch. 5 - Prob. 5.9ECh. 5 - 5.10. If and gases were contained in a system...
Ch. 5 - 5.11. Determine the numerical value of Q for the...Ch. 5 - 5.12. True or false: If all the partial pressures...Ch. 5 - For the reaction 2SO3(g)2SO2(g)+O2(g) when 2mol of...Ch. 5 - 5.14. Determine and for the following reaction at...Ch. 5 - 5.15. Consider the reaction
If the partial...Ch. 5 -
5.16. In atmospheric chemistry, the following...Ch. 5 - Prob. 5.17ECh. 5 - 5.18. Hydrogen cyanide can isomerize to hydrogen...Ch. 5 - 5.19. Assume that a reaction exists such that...Ch. 5 - Prob. 5.20ECh. 5 - 5.21. Show that if the coefficients of a balanced...Ch. 5 - 5.22. True or false: If for a gas-phase reaction,...Ch. 5 - 5.23. The balanced chemical reaction for the...Ch. 5 - The answers in exercise 5.23 should show that...Ch. 5 - At a high enough temperature, the equilibrium...Ch. 5 - Prob. 5.26ECh. 5 - 5.27. Nitrogen dioxide,, dimerizes easily to form...Ch. 5 - 5.28. Another nitrogen-oxygen reaction of some...Ch. 5 - Prob. 5.29ECh. 5 - Prob. 5.30ECh. 5 - Prob. 5.31ECh. 5 - 5.32. For the reaction
. (a) Using in Appendix...Ch. 5 - 5.33. Use the data in Appendix to calculate ...Ch. 5 - 5.34. The of diamond, a crystalline form of...Ch. 5 - 5.35. The densities of graphite and diamond are ...Ch. 5 - Buckminsterfullerene, C60, is a spherical molecule...Ch. 5 - Prob. 5.37ECh. 5 - At what pressure does H2O have an activity of...Ch. 5 - The bisulfate or hydrogen sulfate anion, HSO4, is...Ch. 5 - Prob. 5.40ECh. 5 - Write the equilibrium constant expression for each...Ch. 5 - Prob. 5.42ECh. 5 - For the given chemical equilibrium, these data are...Ch. 5 - Biological standard states include specifying a...Ch. 5 - a At 25.0C, Kw for the autoionization of water is...Ch. 5 - 5.46. For a reaction whose standard enthalpy...Ch. 5 - 5.47. For the reaction
and . Estimate for this...Ch. 5 - 5.48. The isotope exchange reaction
has an...Ch. 5 - 5.49. Consider the following equilibrium:
What...Ch. 5 - 5.50. For the equilibrium
Equilibrium partial...Ch. 5 - The decomposition of NaHCO3, used in kitchens to...Ch. 5 - 5.52. For the equilibrium
at,. In a flask, of...Ch. 5 - Prob. 5.53ECh. 5 - 5.54. For the reaction
The equilibrium...Ch. 5 - Prob. 5.55ECh. 5 - 5.56. Of the amino acids listed in Table , which...Ch. 5 - 5.57. Determine the concentration of the three...Ch. 5 - 5.58. The formation of zwitterionic glycine, ,...Ch. 5 - 5.59. Monosodium glutamate, or MSG, is the sodium...Ch. 5 - Prob. 5.60ECh. 5 - Consider the balanced chemical reaction...Ch. 5 - For the gas-phase reaction 2H2+O22H2O rxnG is...Ch. 5 - Prob. 5.63ECh. 5 - Prob. 5.64E
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- Write the chemical equation and the expression for the equilibrium constant, and calculate Kb for the reaction of each of the following ions as a base. (a) sulfate ion (b) citrate ionarrow_forwardThe hydrogen phthalate ion, C8HsO4, is a weak acid with Ka = 3.91 106. C8H5O4(aq)+H2O(l)C8H4O42(aq)+H3O+(aq) What is the pH of a 0.050 M solution of potassium hydrogen phthalate. KC8H5O4? Note: To find the pH for a solution of the anion, we must take into account that the ion is amphiprotic. It can be shown that, for most cases of amphiprotic ions, the H3O+ concentration is [H3O+]=Ka1Ka2 For phthalic acid, C8H6O4 is Ka1 is 1.12 103, and Ka2 is 3.91 106.arrow_forwardAcrylic acid is used in the polymer industry in the production of acrylates. Its K, is 5.6 X 10“’. What is the pH of a 0.11 M solution of acrylic acid, CH2CHCOOH?arrow_forward
- Complete each of these reactions by filling in the blanks. Predict whether each reaction is product-favored or reactant-favored, and explain your reasoning. (a) _________ (aq) + Br(aq) NH3(aq) + HBr(aq) (b) CH3COOH(aq) + CN(aq) ________ (aq) + HCN(aq) (c) ________ (aq)+H2O () NH3(aq) + OH(aq)arrow_forwardSwimming pool disinfectants produce hypochlorous acid upon dissolution. The weak acid ionizes as follows: HClO (aq) ⇄ H+ (aq) + ClO‒ (aq) Ka=3.0 x 10 ‒8 As strong oxidizing agents, both acid and its conjugate base kill bacteria. However, too high [HClO] is irritating to swimmers’ eyes and too high [ClO‒] will cause the ions to decompose in sunlight. The recommended pH to circumvent both problems is 7.8. Determine the ratio of the weak acid and its conjugate base at this pH.arrow_forwardWrite the equilibrium constant expression for this reaction: H₂CO3(aq) → 2 H (aq) + CO (aq) Do 8 Ś 0 X ?arrow_forward
- Write the equilibrium constant expression for this reaction: CH;Cl(aq)+OH (aq) → CH;OH(aq)+Cl (aq)arrow_forwardGiven 0.01 M solutions of each of the following acids, which solution would have the lowest pH? -117 Hypoiodous acid (HOI), K = 2.3 x 10 Hypobromous acid (HOBr), K = 2.5 x 10 Lactic acid (HC₂H₂O₂), K = 1.3 x 10 Chlorous acid (HClO₂), K = 1.1 x 10²arrow_forwarda) What is the equilibrium constant for HF(aq) ⇌ H+ (aq) + F– (aq)?, b) is it Homogenous or Heterogenous?arrow_forward
- Calculate the change in pH when 6.00 mL of 0.100 M HCl(aq) is added to 100.0 mL of a buffer solution that is 0.100 M in NH3(aq) and 0.100 M in NH4Cl(aq). Consult the table of ionization constants as needed. ΔpH=? Calculate the change in pH when 6.00 mL of 0.100 M NaOH is added to the original buffer solution. ΔpH=?arrow_forwardWrite the equilibrium constant expression for this reaction: →>> H3PO4(aq) 3 H(aq) +PO(aq)arrow_forwardDetermine the equilibrium constant for the following reaction: Ca(OH)2(s) + 2 H+(aq) --> Ca2+(aq) + 2 H2O(l) given the chemical reactions below. Ca(OH)2(s) --> Ca2+(aq) + 2 OH-(aq) K = 6.5 X 10-6 H2O(l) --> H+(aq) + OH-(aq) K = 1.0 X 10-14arrow_forward
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