For a given two 200.0L tanks with the gases helium and hydrogen, the mass of each gas is needed to be determined to produce a pressure of 2.70 atm in its respective tank at 24°C . Concept introduction: By combining the three gaseous laws namely Boyle’s law, Charles’s law and Avogadro’s law a combined gaseous equation is obtained. This combined gaseous equation is called Ideal gas law . According to ideal gas law, PV=nRT Where, P = pressure in atmospheres V= volumes in liters n = number of moles R =universal gas constant ( 0.08206 L ⋅ a t m / K ⋅ m o l ) T = temperature in kelvins By knowing any three of these properties, the state of a gas can be simply identified with applying the ideal gas equation. The mass of a given substance can be calculated by, M a s s i n g r a m = n u m b e r o f m o l e s × g r a m m o l e c u l a r m a s s
For a given two 200.0L tanks with the gases helium and hydrogen, the mass of each gas is needed to be determined to produce a pressure of 2.70 atm in its respective tank at 24°C . Concept introduction: By combining the three gaseous laws namely Boyle’s law, Charles’s law and Avogadro’s law a combined gaseous equation is obtained. This combined gaseous equation is called Ideal gas law . According to ideal gas law, PV=nRT Where, P = pressure in atmospheres V= volumes in liters n = number of moles R =universal gas constant ( 0.08206 L ⋅ a t m / K ⋅ m o l ) T = temperature in kelvins By knowing any three of these properties, the state of a gas can be simply identified with applying the ideal gas equation. The mass of a given substance can be calculated by, M a s s i n g r a m = n u m b e r o f m o l e s × g r a m m o l e c u l a r m a s s
Definition Definition Number of atoms/molecules present in one mole of any substance. Avogadro's number is a constant. Its value is 6.02214076 × 10 23 per mole.
Chapter 5, Problem 49E
Interpretation Introduction
Interpretation: For a given two 200.0L tanks with the gases helium and hydrogen, the mass of each gas is needed to be determined to produce a pressure of 2.70 atm in its respective tank at
24°C.
Concept introduction:
By combining the three gaseous laws namely Boyle’s law, Charles’s law and Avogadro’s law a combined gaseous equation is obtained. This combined gaseous equation is called Ideal gas law.
According to ideal gas law,
PV=nRT
Where,
P = pressure in atmospheres
V= volumes in liters
n = number of moles
R =universal gas constant (
0.08206L⋅atm/K⋅mol)
T = temperature in kelvins
By knowing any three of these properties, the state of a gas can be simply identified with applying the ideal gas equation.
The mass of a given substance can be calculated by,
Indicate how to find the energy difference between two levels in cm-1, knowing that its value is 2.5x10-25 joules.
The gyromagnetic ratio (gamma) for 1H is 2.675x108 s-1 T-1. If the applied field is 1,409 T what will be the separation between nuclear energy levels?
Chances
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11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
• 6H total $4th total
Statistical
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21 total
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• 4H totul
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a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
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Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
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