Chemistry
9th Edition
ISBN: 9781133611097
Author: Steven S. Zumdahl
Publisher: Cengage Learning
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Chapter 5, Problem 143CWP
A certain flexible weather balloon contains helium gas at a volume of 855 L. Initially, the balloon is at sea level where the temperature is 25°C and the barometric pressure is 730 torr. The balloon then rises to an altitude of 6000 ft, where the pressure is 605 torr and the temperature is 15°C. What is the change in volume of the balloon as it ascends from sea level to 6000 ft?
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11. (10pts total) Consider the radical chlorination of 1,3-diethylcyclohexane depicted below. 4
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a) (6pts) How many unique mono-chlorinated products can be formed and what are the
structures for the thermodynamically and statistically favored products?
Product
6
Number of Unique
Mono-Chlorinated Products
Thermodynamically
Favored Product
Statistically
Favored Product
b) (4pts) Draw the arrow pushing mechanism for the FIRST propagation step (p-1) for the
formation of the thermodynamically favored product. Only draw the p-1 step. You do
not need to include lone pairs of electrons. No enthalpy calculation necessary
H
H-Cl
Waterfox
10. (5pts) Provide the complete arrow pushing mechanism for the chemical transformation →
depicted below
Use proper curved arrow notation that explicitly illustrates all bonds being broken, and
all bonds formed in the transformation.
Also, be sure to include all lone pairs and formal charges on all atoms involved in the
flow of electrons.
CH3O
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HA
H
CH3O-H
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①
Do the Lone Pairs get added bc its valence e's are a total of 6 for oxygen and that completes it or due to other reasons. How do we know the particular indication of such.
Chapter 5 Solutions
Chemistry
Ch. 5 - Prob. 1RQCh. 5 - Prob. 2RQCh. 5 - Prob. 3RQCh. 5 - Prob. 4RQCh. 5 - Prob. 5RQCh. 5 - Prob. 6RQCh. 5 - Prob. 7RQCh. 5 - Prob. 8RQCh. 5 - Prob. 9RQCh. 5 - Why do real gases not always behave ideally? Under...
Ch. 5 - Prob. 3ALQCh. 5 - Prob. 4ALQCh. 5 - Prob. 6ALQCh. 5 - Prob. 8ALQCh. 5 - Prob. 11ALQCh. 5 - Prob. 12ALQCh. 5 - Prob. 15ALQCh. 5 - Prob. 16ALQCh. 5 - Draw molecular-level views that show the...Ch. 5 - Prob. 20QCh. 5 - Prob. 21QCh. 5 - Prob. 22QCh. 5 - Prob. 23QCh. 5 - As weather balloons rise from the earths surface,...Ch. 5 - Prob. 25QCh. 5 - Consider two different containers, each filled...Ch. 5 - Prob. 27QCh. 5 - Prob. 28QCh. 5 - Prob. 29QCh. 5 - Prob. 30QCh. 5 - Prob. 31QCh. 5 - Prob. 32QCh. 5 - Prob. 33QCh. 5 - Without looking at a table of values, which of the...Ch. 5 - Prob. 35QCh. 5 - Prob. 36QCh. 5 - Prob. 37ECh. 5 - Prob. 38ECh. 5 - A sealed-tube manometer (as shown below) can be...Ch. 5 - Prob. 40ECh. 5 - A diagram for an open-tube manometer is shown...Ch. 5 - Prob. 42ECh. 5 - Prob. 43ECh. 5 - Prob. 44ECh. 5 - Prob. 45ECh. 5 - Prob. 46ECh. 5 - Prob. 47ECh. 5 - Prob. 48ECh. 5 - Prob. 49ECh. 5 - Prob. 50ECh. 5 - The Steel reaction vessel of a bomb calorimeter,...Ch. 5 - A 5.0-L flask contains 0.60 g O2 at a temperature...Ch. 5 - Prob. 53ECh. 5 - A person accidentally swallows a drop of liquid...Ch. 5 - A gas sample containing 1.50 moles at 25C exerts a...Ch. 5 - Prob. 56ECh. 5 - Prob. 57ECh. 5 - What will be the effect on the volume of an ideal...Ch. 5 - Prob. 59ECh. 5 - Prob. 60ECh. 5 - An ideal gas is contained in a cylinder with a...Ch. 5 - Prob. 62ECh. 5 - A sealed balloon is filled with 1.00 L helium at...Ch. 5 - Prob. 64ECh. 5 - Consider the following reaction:...Ch. 5 - A student adds 4.00 g of dry ice (solid CO2) to an...Ch. 5 - Air bags are activated when a severe impact causes...Ch. 5 - Concentrated hydrogen peroxide solutions are...Ch. 5 - In 1897 the Swedish explorer Andre tried to reach...Ch. 5 - Sulfur trioxide, SO3, is produced in enormous...Ch. 5 - A 15.0-L rigid container was charged with 0.500...Ch. 5 - An important process for the production of...Ch. 5 - Consider the reaction between 50.0 mL liquid...Ch. 5 - Urea (H2NCONH2) is used extensively as a nitrogen...Ch. 5 - Prob. 75ECh. 5 - Prob. 76ECh. 5 - Prob. 77ECh. 5 - A compound has the empirical formula CHCl. A...Ch. 5 - Prob. 79ECh. 5 - Given that a sample of air is made up of nitrogen,...Ch. 5 - Prob. 81ECh. 5 - Prob. 82ECh. 5 - A piece of solid carbon dioxide, with a mass of...Ch. 5 - Prob. 84ECh. 5 - Consider the flasks in the following diagram. What...Ch. 5 - Consider the flask apparatus in Exercise 85, which...Ch. 5 - Prob. 87ECh. 5 - At 0C a 1.0-L flask contains 5.0 102 mole of N2,...Ch. 5 - Prob. 89ECh. 5 - A tank contains a mixture of 52.5 g oxygen gas and...Ch. 5 - Prob. 91ECh. 5 - Helium is collected over water at 25C and 1.00 atm...Ch. 5 - At elevated temperatures, sodium chlorate...Ch. 5 - Xenon and fluorine will react to form binary...Ch. 5 - Methanol (CH3OH) can be produced by the following...Ch. 5 - In the Mthode Champenoise, grape juice is...Ch. 5 - Hydrogen azide, HN3, decomposes on heating by the...Ch. 5 - Prob. 98ECh. 5 - Prob. 99ECh. 5 - The oxides of Group 2A metals (symbolized by M...Ch. 5 - Prob. 101ECh. 5 - Prob. 102ECh. 5 - Prob. 103ECh. 5 - Prob. 104ECh. 5 - Prob. 105ECh. 5 - Prob. 106ECh. 5 - Prob. 107ECh. 5 - Prob. 108ECh. 5 - Prob. 109ECh. 5 - Prob. 110ECh. 5 - Prob. 111ECh. 5 - Prob. 112ECh. 5 - Prob. 113ECh. 5 - Prob. 114ECh. 5 - Prob. 115ECh. 5 - Prob. 116ECh. 5 - Use the data in Table 84 to calculate the partial...Ch. 5 - Prob. 118ECh. 5 - Prob. 119ECh. 5 - Prob. 120ECh. 5 - Prob. 121ECh. 5 - Prob. 122ECh. 5 - Prob. 123AECh. 5 - At STP, 1.0 L Br2 reacts completely with 3.0 L F2,...Ch. 5 - Prob. 125AECh. 5 - Prob. 126AECh. 5 - Prob. 127AECh. 5 - Cyclopropane, a gas that when mixed with oxygen is...Ch. 5 - The nitrogen content of organic compounds can be...Ch. 5 - Prob. 130AECh. 5 - A 15.0L tank is filled with H2 to a pressure of...Ch. 5 - A spherical glass container of unknown volume...Ch. 5 - Prob. 133AECh. 5 - A 20.0L stainless steel container at 25C was...Ch. 5 - Metallic molybdenum can be produced from the...Ch. 5 - Prob. 136AECh. 5 - Prob. 137AECh. 5 - One of the chemical controversies of the...Ch. 5 - An organic compound contains C, H, N, and O....Ch. 5 - Prob. 140AECh. 5 - Prob. 141CWPCh. 5 - Prob. 142CWPCh. 5 - A certain flexible weather balloon contains helium...Ch. 5 - A large flask with a volume of 936 mL is evacuated...Ch. 5 - A 20.0L nickel container was charged with 0.859...Ch. 5 - Consider the unbalanced chemical equation below:...Ch. 5 - Prob. 147CWPCh. 5 - Which of the following statements is(are) true? a....Ch. 5 - A chemist weighed out 5.14 g of a mixture...Ch. 5 - A mixture of chromium and zinc weighing 0.362 g...Ch. 5 - Prob. 151CPCh. 5 - You have an equimolar mixture of the gases SO2 and...Ch. 5 - Methane (CH4) gas flows into a combustion chamber...Ch. 5 - Prob. 154CPCh. 5 - Prob. 155CPCh. 5 - Prob. 156CPCh. 5 - You have a helium balloon at 1.00 atm and 25C. You...Ch. 5 - We state that the ideal gas law tends to hold best...Ch. 5 - You are given an unknown gaseous binary compound...Ch. 5 - Prob. 160CPCh. 5 - In the presence of nitric acid, UO2+ undergoes a...Ch. 5 - Silane, SiH4, is the silicon analogue of methane,...Ch. 5 - Prob. 163IPCh. 5 - Prob. 164IPCh. 5 - Prob. 165MP
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