The condensed structural formula and systematic name should be given for the molecular formula of C 6 H 12 compound. Concept introduction: A condensed structural formula is a system of writing organic structures in a line of text. Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer. Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer) . Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word. Prefix - Represents the substituent present in the molecule and its position in the root name. Suffix - Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne , alcohol, carboxylic acid , alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on Root word - Represents the longest continuous carbon skeleton of the organic molecule. Alkenes : Alkenes are a class of hydrocarbons. The carbon-carbon double bond is called as alkenes and it is also called as olefins.

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Answer 1

Question

Chapter 5, Problem 26P

(a)

Interpretation Introduction

Interpretation:

The condensed structural formula and systematic name should be given for the molecular formula of C6H12 compound.

Concept introduction:

A condensed structural formula is a system of writing organic structures in a line of text.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Alkenes:

Alkenes are a class of hydrocarbons. The carbon-carbon double bond is called as alkenes and it is also called as olefins.

(b)

Interpretation Introduction

Interpretation:

The E and Z isomer of the alkene has to be identified.

Concept introduction:

E and Z isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

(c)

Interpretation Introduction

Interpretation:

The most stable alkene has to be identified.

Concept Introduction:

Stability of alkene:

Stability of alkene depends on the following factors,

The smallest heat hydrogenation of alkene is more stable. The number of hydrogens bonded to its sp2 carbons decreases the stability of an alkene increases. The number of substituent increases the stability of the alkene is increases (heat hydrogenation decreases).

**Stability of Cis–trans alkene:**

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

In cis alkene, molecule are close to each other, hence electron clouds interfere each other therefore strain in the molecule so cis alkene is less stable. Whereas molecule is away from each other, hence electron clouds are will not interfere each other therefore less strain in the molecule, so trans alkene is stable.

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1,4-Dimethyl-1,3-cyclohexadiene can undergo 1,2- or 1,4-addition with hydrogen halides. (a) 1,2-Addition i. Draw the carbocation intermediate(s) formed during the 1,2-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,2-addition product formed during the reaction in (i)? (b) 1,4-Addition i. Draw the carbocation intermediate(s) formed during the 1,4-addition of hydrobromic acid to 1,4-dimethyl-1,3-cyclohexadiene. ii. What is the major 1,4-addition product formed from the reaction in (i)? (c) What is the kinetic product from the reaction of one mole of hydrobromic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (d) What is the thermodynamic product from the reaction of one mole of hydrobro-mic acid with 1,4-dimethyl-1,3-cyclohexadiene? Explain your reasoning. (e) What major product will result when 1,4-dimethyl-1,3-cyclohexadiene is treated with one mole of hydrobromic acid at - 78 deg * C ? Explain your reasoning.

Give the product of the bimolecular elimination from each of the isomeric halogenated compounds. Reaction A Reaction B. КОВ CH₂ HotBu +B+ ко HOIBU +Br+ Templates More QQQ Select Cv Templates More Cras QQQ One of these compounds undergoes elimination 50x faster than the other. Which one and why? Reaction A because the conformation needed for elimination places the phenyl groups and to each other Reaction A because the conformation needed for elimination places the phenyl groups gauche to each other. ◇ Reaction B because the conformation needed for elimination places the phenyl groups gach to each other. Reaction B because the conformation needed for elimination places the phenyl groups anti to each other.

Five isomeric alkenes. A through each undergo catalytic hydrogenation to give 2-methylpentane The IR spectra of these five alkenes have the key absorptions (in cm Compound Compound A –912. (§), 994 (5), 1643 (%), 3077 (1) Compound B 833 (3), 1667 (W), 3050 (weak shoulder on C-Habsorption) Compound C Compound D) –714 (5), 1665 (w), 3010 (m) 885 (3), 1650 (m), 3086 (m) 967 (5), no aharption 1600 to 1700, 3040 (m) Compound K Match each compound to the data presented. Compound A Compound B Compound C Compound D Compound

Answer 2

Question

Chapter 5, Problem 26P

(a)

Interpretation Introduction

Interpretation:

The condensed structural formula and systematic name should be given for the molecular formula of C6H12 compound.

Concept introduction:

A condensed structural formula is a system of writing organic structures in a line of text.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Alkenes:

Alkenes are a class of hydrocarbons. The carbon-carbon double bond is called as alkenes and it is also called as olefins.

(b)

Interpretation Introduction

Interpretation:

The E and Z isomer of the alkene has to be identified.

Concept introduction:

E and Z isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

(c)

Interpretation Introduction

Interpretation:

The most stable alkene has to be identified.

Concept Introduction:

Stability of alkene:

Stability of alkene depends on the following factors,

The smallest heat hydrogenation of alkene is more stable. The number of hydrogens bonded to its sp2 carbons decreases the stability of an alkene increases. The number of substituent increases the stability of the alkene is increases (heat hydrogenation decreases).

**Stability of Cis–trans alkene:**

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

In cis alkene, molecule are close to each other, hence electron clouds interfere each other therefore strain in the molecule so cis alkene is less stable. Whereas molecule is away from each other, hence electron clouds are will not interfere each other therefore less strain in the molecule, so trans alkene is stable.

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Answer 3

Question

Chapter 5, Problem 26P

(a)

Interpretation Introduction

Interpretation:

The condensed structural formula and systematic name should be given for the molecular formula of C6H12 compound.

Concept introduction:

A condensed structural formula is a system of writing organic structures in a line of text.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Alkenes:

Alkenes are a class of hydrocarbons. The carbon-carbon double bond is called as alkenes and it is also called as olefins.

(b)

Interpretation Introduction

Interpretation:

The E and Z isomer of the alkene has to be identified.

Concept introduction:

E and Z isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

(c)

Interpretation Introduction

Interpretation:

The most stable alkene has to be identified.

Concept Introduction:

Stability of alkene:

Stability of alkene depends on the following factors,

The smallest heat hydrogenation of alkene is more stable. The number of hydrogens bonded to its sp2 carbons decreases the stability of an alkene increases. The number of substituent increases the stability of the alkene is increases (heat hydrogenation decreases).

**Stability of Cis–trans alkene:**

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

In cis alkene, molecule are close to each other, hence electron clouds interfere each other therefore strain in the molecule so cis alkene is less stable. Whereas molecule is away from each other, hence electron clouds are will not interfere each other therefore less strain in the molecule, so trans alkene is stable.

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Answer 4

Question

Chapter 5, Problem 26P

(a)

Interpretation Introduction

Interpretation:

The condensed structural formula and systematic name should be given for the molecular formula of C6H12 compound.

Concept introduction:

A condensed structural formula is a system of writing organic structures in a line of text.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Alkenes:

Alkenes are a class of hydrocarbons. The carbon-carbon double bond is called as alkenes and it is also called as olefins.

(b)

Interpretation Introduction

Interpretation:

The E and Z isomer of the alkene has to be identified.

Concept introduction:

E and Z isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

(c)

Interpretation Introduction

Interpretation:

The most stable alkene has to be identified.

Concept Introduction:

Stability of alkene:

Stability of alkene depends on the following factors,

The smallest heat hydrogenation of alkene is more stable. The number of hydrogens bonded to its sp2 carbons decreases the stability of an alkene increases. The number of substituent increases the stability of the alkene is increases (heat hydrogenation decreases).

**Stability of Cis–trans alkene:**

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

In cis alkene, molecule are close to each other, hence electron clouds interfere each other therefore strain in the molecule so cis alkene is less stable. Whereas molecule is away from each other, hence electron clouds are will not interfere each other therefore less strain in the molecule, so trans alkene is stable.

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Answer 5

Chapter 5, Problem 26P

(a)

Interpretation Introduction

Interpretation:

The condensed structural formula and systematic name should be given for the molecular formula of C6H12 compound.

Concept introduction:

A condensed structural formula is a system of writing organic structures in a line of text.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Alkenes:

Alkenes are a class of hydrocarbons. The carbon-carbon double bond is called as alkenes and it is also called as olefins.

(b)

Interpretation Introduction

Interpretation:

The E and Z isomer of the alkene has to be identified.

Concept introduction:

E and Z isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

(c)

Interpretation Introduction

Interpretation:

The most stable alkene has to be identified.

Concept Introduction:

Stability of alkene:

Stability of alkene depends on the following factors,

The smallest heat hydrogenation of alkene is more stable. The number of hydrogens bonded to its sp2 carbons decreases the stability of an alkene increases. The number of substituent increases the stability of the alkene is increases (heat hydrogenation decreases).

**Stability of Cis–trans alkene:**

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

In cis alkene, molecule are close to each other, hence electron clouds interfere each other therefore strain in the molecule so cis alkene is less stable. Whereas molecule is away from each other, hence electron clouds are will not interfere each other therefore less strain in the molecule, so trans alkene is stable.

Answer 6

Chapter 5, Problem 26P

(a)

Interpretation Introduction

Interpretation:

The condensed structural formula and systematic name should be given for the molecular formula of C6H12 compound.

Concept introduction:

A condensed structural formula is a system of writing organic structures in a line of text.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Alkenes:

Alkenes are a class of hydrocarbons. The carbon-carbon double bond is called as alkenes and it is also called as olefins.

Answer 7

Chapter 5, Problem 26P

(a)

Interpretation Introduction

Interpretation:

The condensed structural formula and systematic name should be given for the molecular formula of C6H12 compound.

Concept introduction:

A condensed structural formula is a system of writing organic structures in a line of text.

Isomer: A molecule having the same molecular formula but with different chemical structure is called isomer.

Constitutional Isomers: A molecule having same molecular formula with different structural formulas (Difference in the connectivity of the molecule is called constitutional isomer).

Any organic molecule can be named by using certain rules given by IUPAC (International Union for Pure and applied chemistry).IUPAC name consists of three parts, namely Prefix, suffix and root word.

Prefix- Represents the substituent present in the molecule and its position in the root name.

Suffix- Denotes the presence of functional group if any in the molecule. It can be an alkene, alkyne, alcohol, carboxylic acid, alcohol etc. To add suffix to name a compound, the suffix “-ane” in the parent alkane is replaced by the respective suffix, which corresponds to the functional group present in the given compound. For carboxylic acid, suffix “-oic” will be added, for alcohol, suffix “-ol” will be added and so on

Root word - Represents the longest continuous carbon skeleton of the organic molecule.

Alkenes:

Alkenes are a class of hydrocarbons. The carbon-carbon double bond is called as alkenes and it is also called as olefins.

Answer 8

(b)

Interpretation Introduction

Interpretation:

The E and Z isomer of the alkene has to be identified.

Concept introduction:

E and Z isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

Answer 9

(b)

Interpretation Introduction

Interpretation:

The E and Z isomer of the alkene has to be identified.

Concept introduction:

E and Z isomerism:

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

Example:

Answer 10

(c)

Interpretation Introduction

Interpretation:

The most stable alkene has to be identified.

Concept Introduction:

Stability of alkene:

Stability of alkene depends on the following factors,

The smallest heat hydrogenation of alkene is more stable. The number of hydrogens bonded to its sp2 carbons decreases the stability of an alkene increases. The number of substituent increases the stability of the alkene is increases (heat hydrogenation decreases).

**Stability of Cis–trans alkene:**

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

In cis alkene, molecule are close to each other, hence electron clouds interfere each other therefore strain in the molecule so cis alkene is less stable. Whereas molecule is away from each other, hence electron clouds are will not interfere each other therefore less strain in the molecule, so trans alkene is stable.

Answer 11

(c)

Interpretation Introduction

Interpretation:

The most stable alkene has to be identified.

Concept Introduction:

Stability of alkene:

Stability of alkene depends on the following factors,

The smallest heat hydrogenation of alkene is more stable. The number of hydrogens bonded to its sp2 carbons decreases the stability of an alkene increases. The number of substituent increases the stability of the alkene is increases (heat hydrogenation decreases).

**Stability of Cis–trans alkene:**

The two similar groups (or higher priority groups) are in same side in double bond of alkenes is called as cis isomer (or Z-isomer). Two similar groups (or higher priority groups) are opposite side in double bond of alkenes is called as trans isomer (or E-isomer).

In cis alkene, molecule are close to each other, hence electron clouds interfere each other therefore strain in the molecule so cis alkene is less stable. Whereas molecule is away from each other, hence electron clouds are will not interfere each other therefore less strain in the molecule, so trans alkene is stable.

Answer 12

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Answer 13

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Answer 15

Ch. 5.1 - Prob. 1P Ch. 5.1 - Draw the structure for each of the following: a....Ch. 5.1 - What is each compounds systematic name?Ch. 5.3 - Prob. 4P Ch. 5.3 - Prob. 5P Ch. 5.3 - Prob. 7P Ch. 5.4 - a. For which reaction in each set below will S be...Ch. 5.6 - Prob. 9P Ch. 5.6 - How many different alkenes can be hydrogenated to...Ch. 5.6 - The same alkane is obtained from the catalytic...

Solution Summary: The author explains the condensed structural formula and systematic name of a compound.

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