Essential Organic Chemistry, Global Edition
Essential Organic Chemistry, Global Edition
3rd Edition
ISBN: 9781292089034
Author: Paula Yurkanis Bruice
Publisher: PEARSON
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Chapter 5, Problem 10P

(a)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons and also the product of the reaction has to be identified.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

(b)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons and also the product of the reaction has to be identified.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

Carbanion: Carbanion is a negative charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

(c)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons and also the product of the reaction has to be identified.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

Carbanion: Carbanion is a negative charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

(d)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons and also the product of the reaction has to be identified.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

(e)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons and also the product of the reaction has to be identified.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

Carbanion: Carbanion is a negative charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

(f)

Interpretation Introduction

Interpretation:

The curve arrow should be drawn for showing the movement of electrons and also the product of the reaction has to be identified.

Concept introduction:

Nucleophile: A Nucleophile carries electron pair (negative charged anion) on the molecule and it attacks the positive charged ions to form a chemical bond in reaction.

Electrophile: Electrophiles are neutral or positively charged species having empty orbitals that are attract by the electron rich centre.

Carbocation: Carbocation is a positive charged species and vital intermediate in organic synthesis and its movement depends on the stability of the intermediate and the product formation.

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If you use a catalyst to speed up the reaction, how will that affect the reaction  coordinate?
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For each reaction in question 20, sketch a reaction coordinate energy diagram indicating the starting materials, transition states and any intermediates, if present, in the reaction. Don't worry about the absolute energy of starting materials and products but you can assume that the product is more stable than the starting materials.

Chapter 5 Solutions

Essential Organic Chemistry, Global Edition

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