Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
expand_more
expand_more
format_list_bulleted
Concept explainers
Question
Chapter 4.6, Problem 9E
Interpretation Introduction
Interpretation:Dependence of boiling point of binary mixture on miscibility of two liquids should be determined with use of Raoult’s and Dalton’s law.
Concept introduction:Boiling point is defined as temperature that has vapor pressure of liquid equal to pressure that is present around liquid. At this temperature, substance gets converted from liquid state to vapor or gaseous phase.
Expert Solution & Answer
Want to see the full answer?
Check out a sample textbook solutionStudents have asked these similar questions
The organic compounds chloroform and dichloromethane form ideal solutions when mixed together; at 25 �C the total vapor pressure from a mixture of these two compounds was 345.322 torr. What is the mole fraction of chloroform? Given that the vapor pressure of pure chloroform and pure dichloromethane are 205 torr and 415 torr, respectively, at 25�C.
0.6682
0.4430
0.3318
0.5570
Consider a solution containing two liquids A and B. In this mixture, the molar fraction of A is 0.3713. In addition, the partial molar volumes of A and B are worth 188.2 cm³ mol-1 and 176.14 cm³ mol-1 respectively. The molar masses of A and B are 241g mol-1 and 198g mol-1, respectively. At constant pressure and temperature, what is the volume of a solution of mass equal to 1kg?
a - 1000 cm³
b - 843,5 cm³
c- 678,9 cm³
d - 364,3 cm³
Use Henry’s law to calculate equilibriumsolubility values for gases.
Chapter 4 Solutions
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Ch. 4.2 - Prob. 1ECh. 4.2 - Prob. 2ECh. 4.2 - Prob. 3ECh. 4.2 - Prob. 4ECh. 4.2 - Prob. 5ECh. 4.2 - Prob. 6ECh. 4.2 - Prob. 7ECh. 4.2 - Prob. 8ECh. 4.2 - Prob. 9ECh. 4.3 - Prob. 1E
Ch. 4.3 - Prob. 2ECh. 4.3 - Prob. 3ECh. 4.3 - Prob. 4ECh. 4.3 - Prob. 5ECh. 4.3 - Prob. 6ECh. 4.3 - Prob. 7ECh. 4.3 - Prob. 8ECh. 4.4 - Prob. 1ECh. 4.4 - Prob. 2ECh. 4.4 - Prob. 3ECh. 4.4 - Prob. 4ECh. 4.4 - Prob. 5ECh. 4.4 - Prob. 6ECh. 4.4 - Prob. 7ECh. 4.4 - Prob. 8ECh. 4.4 - Prob. 9ECh. 4.4 - Prob. 11ECh. 4.4 - Prob. 12ECh. 4.4 - Prob. 13ECh. 4.4 - Prob. 14ECh. 4.6 - Prob. 1ECh. 4.6 - Prob. 2ECh. 4.6 - Prob. 3ECh. 4.6 - Prob. 4ECh. 4.6 - Prob. 5ECh. 4.6 - Prob. 6ECh. 4.6 - Prob. 7ECh. 4.6 - Prob. 8ECh. 4.6 - Prob. 9E
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Similar questions
- The vapor pressures of several solutions of water-propanol (CH3CH2CH2OH) were determined at various compositions, with the following data collected at 45C: H2O Vapor pressure(torr) 0 74.0 0.15 77.3 0.37 80.2 0.54 81.6 0.69 80.6 0.83 78.2 1.00 71.9 a. Are solutions of water and propanol ideal? Explain. b. Predict the sign of Hsoln for water-propanol solutions. c. Are the interactive forces between propanol and water molecules weaker than, stronger than, or equal to the interactive forces between the pure substances? Explain. d. Which of the solutions in the data would have the lowest normal boiling point?arrow_forwardVapor-pressure lowering is a colligative property, as are freezing-point depression and boiling-point elevation. What is a colligative property? Why is the freezing point depressed for a solution as compared to the pure solvent? Why is the boiling point elevated for a solution as compared to the pure solvent? Explain how to calculate T for a freezing-point depression problem or a boiling-point elevation problem. Of the solvents listed in Table 10-5, which would have the largest freezing-point depression for a 0.50 molal solution? Which would have the smallest boiling-point elevation for a 0.50 molal solution? A common application of freezing-point depression and boiling-point elevation experiments is to provide a means to calculate the molar mass of a nonvolatile solute. What data are needed to calculate the molar mass of a nonvolatile solute? Explain how you would manipulate these data to calculate the molar mass of the nonvolatile solute.arrow_forwardRationalize the temperature dependence of the solubility of a gas in water in terms of the kinetic molecular theory.arrow_forward
- A solution is made by dissolving 34.0 g of NaCl in 100 g of H2O at 0C. Based on the data in Table 8-1, should this solution be characterized as a. saturated or unsaturated b. dilute or concentratedarrow_forwardCreate a flow diagram, similar to those used in the example problems of this chapter, that outlines the determination of the molar mass of a compound from freezing-point depression measurements. Clearly indicate the data needed for this determination.arrow_forwardThe vapor pressure of an aqueous solution of urea. CH4N2O, is 291.2 mmHg at a measured temperature. The vapor pressure of pure water at that temperature is 355.1 mmHg. Calculate the mole fraction of each component.arrow_forward
- Predict the relative solubility of each compound in the two solvents, based on the intermolecular attractions. (a) Is potassium iodide more soluble in water or in methylene chloride (CH2Cl2)? (b) Is toluene (C6H5CH3) more soluble in benzene (C6H6) or in water? (c) Is ethylene glycol (C2H4(OH)2) more soluble in hexane (C6H14) or in ethanol (C2H5OH)?arrow_forwardThe freezing point of a substance is the temperature at which the solid and liquid forms can coexist indefinitely, at equilibrium. Under these conditions molecules pass between the 2 phases at equal rates because their escaping tendencies from the two phases are identical. Like the boiling point elevation, the freezing point of a solution is directly proportional to the molal concentration of the solution, that is, AT= Kr m Where, ATr refers to the freezing point lowering, Kf, the freezing point depression constant, and m, the molality of the solution. Some of the Kf values are shown in Table 1. For water, Kf is 1.86 °C/m, therefore, any 1 m aqueous solution of nonvolatile solute or a 0.5 m aqueous solution of NaCl will freeze at 1.86 °C lower than pure water. EXERCISE: Problem Solving: Show your solution! 1. A solution containing a nonelectrolyte dissolved in water has a boiling point of 0.305 °C. Calculate the freezing point of the same solution.arrow_forwardExplain the meaning of the van Hoff factor and its role in determining the colligative properties of solutions containing ionic solutes?arrow_forward
- The normal boiling point of diethyl ether is 34.58C. A solution containing a nonvolatile solute dissolved in diethyl ether has a vapor pressure of 698 torr at 34.58C. What is the mole fraction of diethyl ether in this solution?arrow_forwardwhich solid has an anomalous temperature-dependance of its solubility, sugar, KNO3 NaNO3, NaBr Ce2(SO4)3arrow_forwardAt a certain temperature the vapor pressure of pure benzene and pure toluene are 380 torr and 130 torr, respectively. If the mole fraction of benzene is 0.48, what is the total vapor pressure.arrow_forward
arrow_back_ios
SEE MORE QUESTIONS
arrow_forward_ios
Recommended textbooks for you
- Principles of Modern ChemistryChemistryISBN:9781305079113Author:David W. Oxtoby, H. Pat Gillis, Laurie J. ButlerPublisher:Cengage LearningChemistry: The Molecular ScienceChemistryISBN:9781285199047Author:John W. Moore, Conrad L. StanitskiPublisher:Cengage LearningChemistry: Principles and PracticeChemistryISBN:9780534420123Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward MercerPublisher:Cengage Learning
- Chemistry: Matter and ChangeChemistryISBN:9780078746376Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl WistromPublisher:Glencoe/McGraw-Hill School Pub CoGeneral, Organic, and Biological ChemistryChemistryISBN:9781285853918Author:H. Stephen StokerPublisher:Cengage Learning
Principles of Modern Chemistry
Chemistry
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:Cengage Learning
Chemistry: The Molecular Science
Chemistry
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:Cengage Learning
Chemistry: Principles and Practice
Chemistry
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Cengage Learning
Chemistry: Matter and Change
Chemistry
ISBN:9780078746376
Author:Dinah Zike, Laurel Dingrando, Nicholas Hainen, Cheryl Wistrom
Publisher:Glencoe/McGraw-Hill School Pub Co
General, Organic, and Biological Chemistry
Chemistry
ISBN:9781285853918
Author:H. Stephen Stoker
Publisher:Cengage Learning
Solutions: Crash Course Chemistry #27; Author: Crash Course;https://www.youtube.com/watch?v=9h2f1Bjr0p4;License: Standard YouTube License, CC-BY