Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
Experimental Organic Chemistry: A Miniscale & Microscale Approach (Cengage Learning Laboratory Series for Organic Chemistry)
6th Edition
ISBN: 9781305080461
Author: John C. Gilbert, Stephen F. Martin
Publisher: Brooks Cole
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Chapter 4.2, Problem 4E
Interpretation Introduction

Interpretation:Fresh cup of tea made with boiling water is not as hot at higher altitude as it is at sea level should be explained.

Concept introduction:Dalton’s law of partial pressures states that total pressure over liquid is defined as sum of partial pressure of sample and that of air. In this, partial pressure of sample is taken as equal to equilibrium vapor pressure at specific temperature.

The expression for Dalton’s law of partial pressures is as follows:

  Ptotal=Psample+Pair

Where,

  • Ptotal is total pressure.
  • Psampleis pressure of sample.
  • Pairis pressure of gas.

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Transmitance 3. Which one of the following compounds corresponds to this IR spectrum? Point out the absorption band(s) that helped you decide. OH H3C OH H₂C CH3 H3C CH3 H3C INFRARED SPECTRUM 0.8- 0.6 0.4- 0.2 3000 2000 1000 Wavenumber (cm-1) 4. Consider this compound: H3C On the structure above, label the different types of H's as A, B, C, etc. In table form, list the labeled signals, and for each one state the number of hydrogens, their shifts, and the splitting you would observe for these hydrogens in the ¹H NMR spectrum. Label # of hydrogens splitting Shift (2)
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