ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 4.4, Problem 5P
Interpretation Introduction

Interpretation:

The percentage of each enantiomer of limonene and percent enantiomeric excess is to be determined in the sample, which is 95% enantiopure.

Concept introduction:

The percent enantiomeric excess is the difference between the percent of the major enantiomer and the minor enantiomer.

%Enantiomeric excess=(% Major enantiomer)-(% Minor enantiomer)

When a sample contains a chiral compound and one enantiomer is present in excess than the other, the sample is optically active.

When all the molecules have the same handedness, it is called enantiopure.

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Lipases are enzymes that catalyze the hydrolysis of esters, especially esters of glycerol. Because enzymes are chiral catalysts, they catalyze the hydrolysis of only one enantiomer of a racemic mixture. For example, porcine pancreatic lipase catalyzes the hydrolysis of only one enantiomer of the following racemic epoxyester. Calculate the number of grams of epoxyalcohol that can be obtained from 100 g of racemic epoxyester by this method." „HO 'OH + On lipase CHO. H H A racemic mixture This enantiomer This epoxyalcohol is recovered is obtained in unhydrolyzed pure form
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Chapter 4 Solutions

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