ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
ORGANIC CHEMISTRY-PACKAGE >CUSTOM<
10th Edition
ISBN: 9781260028355
Author: Carey
Publisher: MCG CUSTOM
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Chapter 4, Problem 29P
Interpretation Introduction

Interpretation:

The compound 2,3-pentanediol and 2,4-pentanediol are to be compared with respect to the number of stereoisomers possible for each and chiral and achiral isomers are to be identified.

Concept Introduction:

An asymmetrical carbon atom attached to four different atoms or groups is called a chirality center.

A molecule having at least one chiral center is chiral molecule.

If a molecule having a chiral carbon atom contains a plane of symmetry or a center of symmetry, then it becomes achiral.

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6. Consider the following exothermic reaction below. 2Cu2+(aq) +41 (aq)2Cul(s) + 12(aq) a. If Cul is added, there will be a shift left/shift right/no shift (circle one). b. If Cu2+ is added, there will be a shift left/shift right/no shift (circle one). c. If a solution of AgNO3 is added, there will be a shift left/shift right/no shift (circle one). d. If the solvent hexane (C6H14) is added, there will be a shift left/shift right/no shift (circle one). Hint: one of the reaction species is more soluble in hexane than in water. e. If the reaction is cooled, there will be a shift left/shift right/no shift (circle one). f. Which of the changes above will change the equilibrium constant, K?

Chapter 4 Solutions

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