General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Question
Chapter 4, Problem 4.94P
Interpretation Introduction
Interpretation:
All the lone pairs and double bonds in the given molecule should be filled in order to give normal bonding pattern for every atom.
Concept introduction:
When drawing a molecule, number of valance electrons of each atom must be considered. The atom tries to attain stability by completing their octet. The octet can be completed either by sharing of electron(s) or by complete transfer of electron(s).
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Part 1 of 5
Draw the best Lewis structure of HC204. Include lone pair electrons and any formal charges.
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structure.
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5
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Fill in the lone pairs needed to give the main group elements (except hydrogen) an octet. Glycerol is a product of the metabolism of fats. Acrylamide is used to make polyacrylamide, which is used in some cosmetics and food packaging.
Chapter 4 Solutions
General, Organic, & Biological Chemistry
Ch. 4.1 - Use electron-dot symbols to show how a hydrogen...Ch. 4.1 - Use electron-dot symbols to show how two chlorine...Ch. 4.1 - How many covalent bonds are predicted for each...Ch. 4.1 - Fill in the lone pairs on each atom to give every...Ch. 4.1 - Prob. 4.5PCh. 4.1 - Draw a Lewis structure for each covalent molecule....Ch. 4.1 - Draw a Lewis structure for dimethyl ether (C2H6O)...Ch. 4.2 - Prob. 4.8PCh. 4.2 - Prob. 4.9PCh. 4.2 - Prob. 4.10P
Ch. 4.3 - Prob. 4.11PCh. 4.3 - Prob. 4.12PCh. 4.4 - Prob. 4.13PCh. 4.4 - Draw resonance structures for each polyatomic...Ch. 4.4 - Nitrous oxide, N2O, is a sweet-smelling gas...Ch. 4.5 - Name each compound: (a) CS2; (b) SO2; (c) PCl5;...Ch. 4.5 - Prob. 4.17PCh. 4.5 - What is the shape around the indicated atom in...Ch. 4.6 - NaNH2, sodium amid, is a salt that contains a...Ch. 4.6 - Prob. 4.20PCh. 4.7 - Using the trends in the periodic table, rank the...Ch. 4.7 - Use electronegativity values to classify the...Ch. 4.7 - Prob. 4.23PCh. 4.8 - Prob. 4.24PCh. 4.9 - Prob. 4.25PCh. 4.9 - Prob. 4.26PCh. 4 - For each pair of compounds, classify the bonding...Ch. 4 - For each pair of compounds, classify the bonding...Ch. 4 - Prob. 4.29PCh. 4 - How many bonds and lone pairs are typically...Ch. 4 - Prob. 4.31PCh. 4 - Fill in the lone pairs needed to give the main...Ch. 4 - Prob. 4.33PCh. 4 - Convert the 3-D model of the general anesthetic...Ch. 4 - Draw a valid Lewis structure for each molecule. Hl...Ch. 4 - Draw a valid Lewis structure for each molecule....Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Draw a valid Lewis structure for...Ch. 4 - Draw a valid Lewis structure for phosgene, CCl2O ,...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Keeping in mind that some elements violate the...Ch. 4 - Keeping in mind that some elements violate the...Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - Prob. 4.47PCh. 4 - Prob. 4.48PCh. 4 - Prob. 4.49PCh. 4 - Label each pair of compounds are resonance...Ch. 4 - Prob. 4.51PCh. 4 - Draw three resonance structures for the nitrate...Ch. 4 - Name each covalent compound. PBr3 SO3 NCl3 P2S5Ch. 4 - Name each covalent compound. SF6 CBr4 N2O P4O10Ch. 4 - Prob. 4.55PCh. 4 - Prob. 4.56PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 4.59PCh. 4 - Match each compound with one of the molecular...Ch. 4 - Prob. 4.61PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 4.63PCh. 4 - Considering each of the given ball-and stick...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - Prob. 4.67PCh. 4 - Predict the bond angles around the indicated atoms...Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Rank the atoms in each group in order of...Ch. 4 - Prob. 4.72PCh. 4 - Prob. 4.73PCh. 4 - Using electronegativity values, classify the bond...Ch. 4 - Label the bond formed between carbon and each of...Ch. 4 - Label the bond formed between fluroine and each of...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Prob. 4.79PCh. 4 - Prob. 4.80PCh. 4 - Label the polar bonds and then decide if each...Ch. 4 - Label the polar bonds and then decide if each...Ch. 4 - Prob. 4.83PCh. 4 - Explain why H2O is a polar molecule but H2S is...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Answer the following questions about the molecule...Ch. 4 - Answer the following question about the molecule...Ch. 4 - Prob. 4.89PCh. 4 - Lactic acid gives sour milk its distinctive taste....Ch. 4 - Prob. 4.91PCh. 4 - Prob. 4.92PCh. 4 - Prob. 4.93PCh. 4 - Prob. 4.94PCh. 4 - Isobutyl cyanoacrylate is used in medical glues to...Ch. 4 - Prob. 4.96PCh. 4 - Cyclopropane is a stable compound that contains...Ch. 4 - Prob. 4.98CPCh. 4 - Prob. 4.99CPCh. 4 - Prob. 4.100CP
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- Indicate which of the following molecules are polar. Draw the molecular structure of each polar molecule, including the arrows that indicate the bond dipoles and the molecular dipole moment. (a) HCN (b) I2 (c) NOarrow_forwardConsider the pyrosulfate ion, S2O72-. It has no sulfur–sulfur nor oxygen–oxygen bonds. (a) Write a Lewis structure for the pyrosulfate ion using only single bonds. (b) What is the formal charge on the sulfur atoms for the Lewis structure you drew in part (a)? (c) Write another Lewis structure using six bonds and two O—S bonds. (d) What is the formal charge on each atom for the structure you drew in part (c)?arrow_forwardSuccessive substitution of F atoms for H atoms in the molecule NH3 produces the molecules NH2F, NHF2, and NF3. a. Draw Lewis structures for each of the four molecules. b. Using VSEPR theory, predict the geometry of each of the four molecules. c. Specify the polarity (polar or nonpolar) for each of the four molecules.arrow_forward
- In addition to CO, CO2, and C3O2, there is another molecular oxide of carbon, pentacarbon dioxide, C5O2, a yellow solid. (a) What is the approximate C-to-C-to-O bond angle in pentacarbon dioxide? (b) What is the approximate C-to-C-to-C bond angle in this compound?arrow_forwardConsider the following compounds: CO2, SO2, KrF2, SO3, NF3, IF3, CF4, SF4, XeF4, PF5, IF5, and SCl6. These 12 compounds arc all examples of different molecular structures. Draw the Lewis structures for each and predict the molecular structure. Predict the bond angles and the polarity of each. (A polar molecule has a net dipole moment, while a nonpolar molecule docs not.) See Exercises 115 and 116 for the molecular structures based on the trigonal bipyramid and the octahedral geometries.arrow_forwardFormamide, HC(O)NH2, is prepared at high pressures from carbon monoxide and ammonia, and serves as an industrial solvent (the parentheses around the O indicate that it is bonded only to the carbon atom and that the carbon atom is also bonded to the H and the N atoms). Two resonance forms (one with formal charges) can be written for formamide. Write both resonance structures, and predict the bond angles about the carbon and nitrogen atoms for each resonance form. Are they the same? Describe how the experimental determination of the HNH bond angle could be used to indicate which resonance form is more important.arrow_forward
- Successive substitution of F atoms for H atoms in the molecule CH4 produces the molecules CH3F, CH2F2, CHF3, and CF4. a. Draw Lewis structures for each of the five molecules. b. Using VSEPR theory, predict the geometry of each of the five molecules. c. Specify the polarity (polar or nonpolar) for each of the five molecules.arrow_forwardDraw Lewis structures to illustrate the bonding in the following molecules. In each case, there will be at least one multiple bond present in a molecule. a. C3H4: A central carbon atom has two other carbon atoms bonded to it. Each of the noncentral carbon atoms also has two hydrogen atoms bonded to it. b. N2F2: The two nitrogen atoms are bonded to one another, and each nitrogen atom also has a fluorine atom bonded to it. c. C2H3N: The two carbon atoms are bonded to each other. One of the carbon atoms has a nitrogen atom bonded to it, and the other carbon atom has three hydrogen atoms bonded to it. d. C3H4: A central carbon atom has two other carbon atoms bonded to it. One of the noncentral carbon atoms also has one hydrogen atom bonded to it, and the other one has three hydrogen atoms bonded to it.arrow_forwardThe study of carbon-containing compounds and their properties is called organic chemistry. Besides carbon atoms, organic compounds also can contain hydrogen, oxygen, and nitrogen atoms (as well as other types of atoms). A common trait of simple organic compounds is to have Lewis structures where all atoms have a formal charge of zero. Consider the following incomplete Lewis structure for an organic compound called histidine (an amino acid), which is one of the building blocks of proteins found in our bodies: Draw a complete Lewis structure for histidine in which all atoms have a formal charge of zero.arrow_forward
- Indicate whether each of the following hypothetical triatomic molecules is polar or nonpolar. Assume that A, X, and Y have different electronegativities. a. a linear XAX molecule b. a linear XXA molecule c. an angular AXY molecule d. an angular XAY moleculearrow_forwardDraw Lewis structures showing all valence electrons for these molecules. (a) C2H6 (b) CS2 (c) HCNarrow_forwardConsider the following compounds: CO2, SO2, KrF2, SO3, NF3, IF3, CF4, SF4, XeF4, PF5, TF5, and SCl6. These 12 compounds are all examples of different molecular structures. Draw the Lewis structures for each and predict the molecular structures. Predict the bond angles and the polarity of each. (A polar molecule has a net dipole moment, while a nonpolar molecule does not.) See Exercises 25 and 26 for the molecular structures based on the trigonal bipyramid and the octahedral geometries.arrow_forward
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Types of bonds; Author: Edspira;https://www.youtube.com/watch?v=Jj0V01Arebk;License: Standard YouTube License, CC-BY