General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 4, Problem 4.85P
Convert each ball-and-stick model to a Lewis structure and include all nondonded electron pairs. (b) Labell all polar bonds. (c) Is the molecule polar or nonpolar?
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Classify the bond formed between each pair of atoms as covalent, polar covalent, or ionic.(a) Sr and F (b) N and Cl (c) N and O
Answer true or false.
(a) An ionic bond is formed by the combination of positive and negative ions.
(b) An ionic bond between two atoms forms by the transfer of one or more valence electrons from the atom of higher electronegativity to the atom of lower electronegativity.
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Answer true or flase
(d) Both copper(II) oxide and cupric oxide are acceptable names for CuO.
(e) The systematic name for Fe2 O3 is iron(II) oxide.…
Answer each of the following questions for ClF3.
(a) total valence electron count.
(b) the Lewis structure.
(c) the arrangement (or shape) of the electron grouping (includes lone pairs).
(d) ideal bond angle.
(e) actual molecular geometry (may be the same or different than answer (c).
(f) actual bond angles (may use > or< symbols where appropriate).
Chapter 4 Solutions
General, Organic, & Biological Chemistry
Ch. 4.1 - Use electron-dot symbols to show how a hydrogen...Ch. 4.1 - Use electron-dot symbols to show how two chlorine...Ch. 4.1 - How many covalent bonds are predicted for each...Ch. 4.1 - Fill in the lone pairs on each atom to give every...Ch. 4.1 - Prob. 4.5PCh. 4.1 - Draw a Lewis structure for each covalent molecule....Ch. 4.1 - Draw a Lewis structure for dimethyl ether (C2H6O)...Ch. 4.2 - Prob. 4.8PCh. 4.2 - Prob. 4.9PCh. 4.2 - Prob. 4.10P
Ch. 4.3 - Prob. 4.11PCh. 4.3 - Prob. 4.12PCh. 4.4 - Prob. 4.13PCh. 4.4 - Draw resonance structures for each polyatomic...Ch. 4.4 - Nitrous oxide, N2O, is a sweet-smelling gas...Ch. 4.5 - Name each compound: (a) CS2; (b) SO2; (c) PCl5;...Ch. 4.5 - Prob. 4.17PCh. 4.5 - What is the shape around the indicated atom in...Ch. 4.6 - NaNH2, sodium amid, is a salt that contains a...Ch. 4.6 - Prob. 4.20PCh. 4.7 - Using the trends in the periodic table, rank the...Ch. 4.7 - Use electronegativity values to classify the...Ch. 4.7 - Prob. 4.23PCh. 4.8 - Prob. 4.24PCh. 4.9 - Prob. 4.25PCh. 4.9 - Prob. 4.26PCh. 4 - For each pair of compounds, classify the bonding...Ch. 4 - For each pair of compounds, classify the bonding...Ch. 4 - Prob. 4.29PCh. 4 - How many bonds and lone pairs are typically...Ch. 4 - Prob. 4.31PCh. 4 - Fill in the lone pairs needed to give the main...Ch. 4 - Prob. 4.33PCh. 4 - Convert the 3-D model of the general anesthetic...Ch. 4 - Draw a valid Lewis structure for each molecule. Hl...Ch. 4 - Draw a valid Lewis structure for each molecule....Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Draw a valid Lewis structure for...Ch. 4 - Draw a valid Lewis structure for phosgene, CCl2O ,...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Keeping in mind that some elements violate the...Ch. 4 - Keeping in mind that some elements violate the...Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - Prob. 4.47PCh. 4 - Prob. 4.48PCh. 4 - Prob. 4.49PCh. 4 - Label each pair of compounds are resonance...Ch. 4 - Prob. 4.51PCh. 4 - Draw three resonance structures for the nitrate...Ch. 4 - Name each covalent compound. PBr3 SO3 NCl3 P2S5Ch. 4 - Name each covalent compound. SF6 CBr4 N2O P4O10Ch. 4 - Prob. 4.55PCh. 4 - Prob. 4.56PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 4.59PCh. 4 - Match each compound with one of the molecular...Ch. 4 - Prob. 4.61PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 4.63PCh. 4 - Considering each of the given ball-and stick...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - Prob. 4.67PCh. 4 - Predict the bond angles around the indicated atoms...Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Rank the atoms in each group in order of...Ch. 4 - Prob. 4.72PCh. 4 - Prob. 4.73PCh. 4 - Using electronegativity values, classify the bond...Ch. 4 - Label the bond formed between carbon and each of...Ch. 4 - Label the bond formed between fluroine and each of...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Prob. 4.79PCh. 4 - Prob. 4.80PCh. 4 - Label the polar bonds and then decide if each...Ch. 4 - Label the polar bonds and then decide if each...Ch. 4 - Prob. 4.83PCh. 4 - Explain why H2O is a polar molecule but H2S is...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Answer the following questions about the molecule...Ch. 4 - Answer the following question about the molecule...Ch. 4 - Prob. 4.89PCh. 4 - Lactic acid gives sour milk its distinctive taste....Ch. 4 - Prob. 4.91PCh. 4 - Prob. 4.92PCh. 4 - Prob. 4.93PCh. 4 - Prob. 4.94PCh. 4 - Isobutyl cyanoacrylate is used in medical glues to...Ch. 4 - Prob. 4.96PCh. 4 - Cyclopropane is a stable compound that contains...Ch. 4 - Prob. 4.98CPCh. 4 - Prob. 4.99CPCh. 4 - Prob. 4.100CP
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- hat does it mean to say that a bond is polar? Give two examples of molecules with polar bonds. Indicate in your examples the direction of the polarity.arrow_forwardGive the polarity of the molecule of H2S and its bond angle.arrow_forwardFollowing is a molecule with polar bonds whose shape was obtained using the VSEPR theory. Specify the molecular shape of this molecule, and whether the molecule is polar or nonpolar. (Hint: In terms of polarity, see whether the dipoles in the molecule cancel or not. A molecule containing polar bonds can be nanpolar if the dipoles cancel each other. You can imagine the dipoles as ropes pulling on the central atom–If the pulls cancel each other, that is, the central atom cannot move, then the molecule is nonpolar. If on the other hand the opposite is true, then the molecule is polar.) O trigonal pyramidal shape, nonpolar O trigonal planar shape, nonpolar O tetrahedral shape, polar O trigonal pyramidal shape, polar O trigonal planar shape, polararrow_forward
- Which of the following statements are true regarding a covalent bond between nitrogen and oxygen atoms in a nitric oxide, NO, molecule? (a) Valence electrons are shared between nitrogen and oxygen atoms. (b) Bonding electrons are found only between the bonded atoms. (c) The bond length is greater than the sum of the two atomic radii. (d) Energy is required to break a covalent bond.arrow_forward(1) What is the total number of valence electrons in the Lewis structure of SF2? electrons (2) Draw a Lewis structure for SF2arrow_forwardWhich of the following compounds has both ionic and covalent bond? (a) H2O (b) NH4Cl (c) NaCl (d) HClarrow_forward
- For the polyatomic ion NO3-, answer the following: (a) total number of valence electrons in the ion (enter a number only) (b) identity of the central atom (element symbol) Now draw the Lewis Structure and answer the following questions: (c) number of electron groups on the central atom (enter a number only) (d) number of bonding groups on the central atom (enter a number only) (e) number of double bonds in the ion (enter a number only) (f) number of single bonds in the ionarrow_forwardWhich of the following statements are true regarding an ionic bond between cobalt and sulfur in a CoS formula unit? (a) Cobalt ions and sulfide ions bond by electrostatic attraction. (b) Cobalt atoms gain electrons and sulfur atoms lose electrons. (c) The ionic radius of a cobalt ion is greater than its atomic radius. (d) Breaking an ionic bond between cobalt and sulfur requires energy.arrow_forwardDetermine the shape around each central atom in acetone, (CH3)2CO.arrow_forward
- Draw the Lewis structure for the ionic compound thatforms from Mg and each atom.(a) F(b) O(c) Narrow_forward2. For the molecule SiBr2H2, answer the following: (a) number of valence electrons in the molecule (b) Identify of the central atom (c) Number of electron groups on the central atom (d) Number of bonding groups on the central atom (e) Number of single bonds in the molecule (f) Number of double bonds in the molecule (g) Number of unpaired electrons on the central atom (h) Shape of the molecule (j) Is the SiBr2H2 molecule polar?arrow_forwardWhich of these statements correctly describes the relationship between the displayed molecules? -Only one of these represents a valid Lewis Structure -They do not have the same molecular formula -They are isomers -They are the same moleculearrow_forward
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