General, Organic, & Biological Chemistry
3rd Edition
ISBN: 9780073511245
Author: Janice Gorzynski Smith Dr.
Publisher: McGraw-Hill Education
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Textbook Question
Chapter 4, Problem 4.88P
Answer the following question about the molecule OCS.
- How many valence electrons does OCS contain?
- Draw a valid Lewis structure.
- Label all polar bonds.
- What is the shape around the C atom?
- Is OCS a polar molecule ? Explain.
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Decide whether each molecule or polyatomic ion is polar or nonpolar.
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Decide whether these proposed Lewis structures are reasonable.
proposed Lewis structure
Is the proposed Lewis structure reasonable?
Yes.
No, it has the wrong number of valence electrons.
The correct number is:
No, it has the right number of valence electrons but doesn't satisfy the
octet rule.
The symbols of the problem atoms are: 0
Yes.
No, it has the wrong number of valence electrons.
a=ö:]
The correct number is:
No, it has the right number of valence electrons but doesn't satisfy the
octet rule.
The symbols of the problem atoms are: 0
Yes.
No, it has the wrong number of valence electrons.
:0:
The correct number is: 0
HIC-H
No, it has the right number of valence electrons but doesn't satisfy the
octet rule.
The symbols of the problem atoms are:"
* If two or more atoms of the same element don't satisfy the octet rule, just enter the chemical symbol as many
times as necessary. For example, if two oxygen atoms don't satisfy the octet rule, enter "O,0".
X 5 ?
: Z:
I
:Z:
Chapter 4 Solutions
General, Organic, & Biological Chemistry
Ch. 4.1 - Use electron-dot symbols to show how a hydrogen...Ch. 4.1 - Use electron-dot symbols to show how two chlorine...Ch. 4.1 - How many covalent bonds are predicted for each...Ch. 4.1 - Fill in the lone pairs on each atom to give every...Ch. 4.1 - Prob. 4.5PCh. 4.1 - Draw a Lewis structure for each covalent molecule....Ch. 4.1 - Draw a Lewis structure for dimethyl ether (C2H6O)...Ch. 4.2 - Prob. 4.8PCh. 4.2 - Prob. 4.9PCh. 4.2 - Prob. 4.10P
Ch. 4.3 - Prob. 4.11PCh. 4.3 - Prob. 4.12PCh. 4.4 - Prob. 4.13PCh. 4.4 - Draw resonance structures for each polyatomic...Ch. 4.4 - Nitrous oxide, N2O, is a sweet-smelling gas...Ch. 4.5 - Name each compound: (a) CS2; (b) SO2; (c) PCl5;...Ch. 4.5 - Prob. 4.17PCh. 4.5 - What is the shape around the indicated atom in...Ch. 4.6 - NaNH2, sodium amid, is a salt that contains a...Ch. 4.6 - Prob. 4.20PCh. 4.7 - Using the trends in the periodic table, rank the...Ch. 4.7 - Use electronegativity values to classify the...Ch. 4.7 - Prob. 4.23PCh. 4.8 - Prob. 4.24PCh. 4.9 - Prob. 4.25PCh. 4.9 - Prob. 4.26PCh. 4 - For each pair of compounds, classify the bonding...Ch. 4 - For each pair of compounds, classify the bonding...Ch. 4 - Prob. 4.29PCh. 4 - How many bonds and lone pairs are typically...Ch. 4 - Prob. 4.31PCh. 4 - Fill in the lone pairs needed to give the main...Ch. 4 - Prob. 4.33PCh. 4 - Convert the 3-D model of the general anesthetic...Ch. 4 - Draw a valid Lewis structure for each molecule. Hl...Ch. 4 - Draw a valid Lewis structure for each molecule....Ch. 4 - Prob. 4.37PCh. 4 - Prob. 4.38PCh. 4 - Draw a valid Lewis structure for...Ch. 4 - Draw a valid Lewis structure for phosgene, CCl2O ,...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Draw a valid Lewis structure for each ion: (a)...Ch. 4 - Keeping in mind that some elements violate the...Ch. 4 - Keeping in mind that some elements violate the...Ch. 4 - Prob. 4.45PCh. 4 - Prob. 4.46PCh. 4 - Prob. 4.47PCh. 4 - Prob. 4.48PCh. 4 - Prob. 4.49PCh. 4 - Label each pair of compounds are resonance...Ch. 4 - Prob. 4.51PCh. 4 - Draw three resonance structures for the nitrate...Ch. 4 - Name each covalent compound. PBr3 SO3 NCl3 P2S5Ch. 4 - Name each covalent compound. SF6 CBr4 N2O P4O10Ch. 4 - Prob. 4.55PCh. 4 - Prob. 4.56PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 4.59PCh. 4 - Match each compound with one of the molecular...Ch. 4 - Prob. 4.61PCh. 4 - Add lone pairs where needed to give octets and...Ch. 4 - Prob. 4.63PCh. 4 - Considering each of the given ball-and stick...Ch. 4 - Prob. 4.65PCh. 4 - Prob. 4.66PCh. 4 - Prob. 4.67PCh. 4 - Predict the bond angles around the indicated atoms...Ch. 4 - Prob. 4.69PCh. 4 - Prob. 4.70PCh. 4 - Rank the atoms in each group in order of...Ch. 4 - Prob. 4.72PCh. 4 - Prob. 4.73PCh. 4 - Using electronegativity values, classify the bond...Ch. 4 - Label the bond formed between carbon and each of...Ch. 4 - Label the bond formed between fluroine and each of...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Which bond in each pair is more polar-that is, has...Ch. 4 - Prob. 4.79PCh. 4 - Prob. 4.80PCh. 4 - Label the polar bonds and then decide if each...Ch. 4 - Label the polar bonds and then decide if each...Ch. 4 - Prob. 4.83PCh. 4 - Explain why H2O is a polar molecule but H2S is...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Convert each ball-and-stick model to a Lewis...Ch. 4 - Answer the following questions about the molecule...Ch. 4 - Answer the following question about the molecule...Ch. 4 - Prob. 4.89PCh. 4 - Lactic acid gives sour milk its distinctive taste....Ch. 4 - Prob. 4.91PCh. 4 - Prob. 4.92PCh. 4 - Prob. 4.93PCh. 4 - Prob. 4.94PCh. 4 - Isobutyl cyanoacrylate is used in medical glues to...Ch. 4 - Prob. 4.96PCh. 4 - Cyclopropane is a stable compound that contains...Ch. 4 - Prob. 4.98CPCh. 4 - Prob. 4.99CPCh. 4 - Prob. 4.100CP
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- Using the symbols and +, indicate the direction of polarity in each polar covalent bond. (a) CN (b) NO (c) CClarrow_forwardUse the Molecule Shape simulator (http://openstaxcollege.org/I/6MolecShape) to build a molecule. Starting with the central atom, click on the double bond to add one double bond. Then add one single bond and one lone pair. Rotate the molecule to observe the complete geometry. Name the electron group geometry and molecular structure and predict the bond angle. Then click the check boxes at the bottom and right of the simulator to check your answers.arrow_forwardSuccessive substitution of F atoms for H atoms in the molecule CH4 produces the molecules CH3F, CH2F2, CHF3, and CF4. a. Draw Lewis structures for each of the five molecules. b. Using VSEPR theory, predict the geometry of each of the five molecules. c. Specify the polarity (polar or nonpolar) for each of the five molecules.arrow_forward
- a. How many sticks did you need to make the skeleton structure?____________ b. How many sticks are left over? ____________ If your model is to obey the octet rule, each ball must have four sticks in it except for hydrogen atom balls, which need and can only have one. Each atom in an octet rule species is surrounded by four pairs of electrons. c. How many holes remain to be filled? ____________ Fill them with the remaining sticks, which represent nonbonding electron pairs. Draw the complete Lewis structure for NH2Cl using lines for bonds and pairs of dots for nonbonding electrons.arrow_forwardSuccessive substitution of F atoms for H atoms in the molecule NH3 produces the molecules NH2F, NHF2, and NF3. a. Draw Lewis structures for each of the four molecules. b. Using VSEPR theory, predict the geometry of each of the four molecules. c. Specify the polarity (polar or nonpolar) for each of the four molecules.arrow_forwardO ELECTRONIC STRUCTURE AND CHEMICAL BONDING Predicting whether molecules are polar or nonpolar Decide whether each molecule or polyatomic ion is polar or nonpolar. If the molecule or polyatomic ion is polar, write the chemical symbol of the atom closest to the negative side. For example, if the molecule were HCl and you decided the hydrogen atom was closest to the negative side of the molecule, you'd enter "H* in the last column of the table. molecule or polar or nonpolar? atom closest to polyatomic ion negative side O polar O nonpolar Cs2 попроlar O polar NH3 nonpolar polar HCl O nonpolar Explanation Check 02022 McGraw Hill LLC. AN Rights Reserved. Terms of Use I Privacy Center Accessibility F9 F10 F11 F12 Finder F4 F5 F6 F7 F8 DeX F2 APP2 F3 APP3 F1 Esc APP1- II ! @ # $ % & Bac %3D 4. 7 1arrow_forward
- * If two or more atoms have the wrong number of valence electrons around them, just enter the chemical symbol for the atom as many times as necessary. If two oxygen atoms have the wrong number of electrons around them, enter the symbol O twice.arrow_forwardPredicting the arrangement of electron groups around the central atom of a molecule.arrow_forwardFollowing is a molecule with polar bonds whose shape was obtained using the VSEPR theory. Specify the molecular shape of this molecule, and whether the molecule is polar or nonpolar. (Hint: In terms of polarity, see whether the dipoles in the molecule cancel or not. A molecule containing polar bonds can be nanpolar if the dipoles cancel each other. You can imagine the dipoles as ropes pulling on the central atom–If the pulls cancel each other, that is, the central atom cannot move, then the molecule is nonpolar. If on the other hand the opposite is true, then the molecule is polar.) O trigonal pyramidal shape, nonpolar O trigonal planar shape, nonpolar O tetrahedral shape, polar O trigonal pyramidal shape, polar O trigonal planar shape, polararrow_forward
- Decide whether these proposed Lewis structures are reasonable. proposed Lewis structure Is the proposed Lewis structure reasonable? O Yes. O No, it has the wrong number of valence electrons. はードー =N The correct number is:| No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* O Yes. No, it has the wrong number of valence electrons. The correct number is:| No, it has the right number of valence electrons but doesn't satisfy the octet rule. The symbols of the problem atoms are:* O Yes. O No, it has the wrong number of valence electrons. The correct number is: | No, it has the right number of valence electrons but doesn't satisfy the octet rule. : Cl C : The symbols of the problem atoms are: * If two or more atoms of the same element don't satisfy the octet rule, just enter the chemical symbol as many times as necessary. For example, if two oxygen atoms don't satisfy the octet rule, enter "0,0". O Oarrow_forwardWrite a Lewis structure for each of the following molecules. H2CO (carbon is central) Draw the molecule by placing atoms on the grid and connecting them with bonds. Include all lone pairs of electrons.arrow_forwardHelparrow_forward
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